This instructions will guide you on how to use Pupil VR Add-on with 3rd party content in Steam VR. Such as playing a game, for which you won't have access to the camera feed and properties.
To capture the scene camera feed without having to develop anything, there are 3rd party plugins for OBS, like this one or this, that allows you to capture your VR content through the OpenVR API.
Please note that there is no OpenXR solution yet.
You will need to record the data without calibration using Pupil Capture.