ShellReadFileExtendedProperties.cs

public static void Main(string[] args)
{
    List<string> arrHeaders = new List<string>();

    Shell32.Shell shell = new Shell32.Shell();
    Shell32.Folder objFolder;

    objFolder = shell.NameSpace(@"C:\temp\testprop");

    for( int i = 0; i < short.MaxValue; i++ )
    {
        string header = objFolder.GetDetailsOf(null, i);
        if (String.IsNullOrEmpty(header))
            break;
        arrHeaders.Add(header);
    }

    foreach(Shell32.FolderItem2 item in objFolder.Items())
    {
        for (int i = 0; i < arrHeaders.Count; i++)
        {
            Console.WriteLine("{0}\t{1}: {2}", i, arrHeaders[i], objFolder.GetDetailsOf(item, i));
        }
    }
}

Add a reference to Microsoft Shell Controls and Automation from the COM tab of the References dialog.