[Select CPU core]

affinity

start /affinity 1 program.exe

this will run program.exe on the first CPU as "1" is the hex value of the affinity mask

CPU3 CPU2 CPU1 CPU0  Bin  Hex
---- ---- ---- ----  ---  ---
OFF  OFF  OFF  ON  = 0001 = 1
OFF  OFF  ON   OFF = 0010 = 2
OFF  OFF  ON   ON  = 0011 = 3
OFF  ON   OFF  OFF = 0100 = 4
OFF  ON   OFF  ON  = 0101 = 5 
OFF  ON   ON   OFF = 0110 = 6
OFF  ON   ON   ON  = 0111 = 7
ON   OFF  OFF  OFF = 1000 = 8
ON   OFF  OFF  ON  = 1001 = 9
ON   OFF  ON   OFF = 1010 = A 
ON   OFF  ON   ON  = 1011 = B
ON   ON   OFF  OFF = 1100 = C
ON   ON   OFF  ON  = 1101 = D
ON   ON   ON   OFF = 1110 = E 
ON   ON   ON   ON  = 1111 = F