This is a sample XML file that Microsoft makes available.

books.xml

<?xml version="1.0"?>
<catalog>
   <book id="bk101">
      <author>Gambardella, Matthew</author>
      <title>XML Developer's Guide</title>
      <genre>Computer</genre>
      <price>44.95</price>
      <publish_date>2000-10-01</publish_date>
      <description>An in-depth look at creating applications 
      with XML.</description>
   </book>
   <book id="bk102">
      <author>Ralls, Kim</author>
      <title>Midnight Rain</title>
      <genre>Fantasy</genre>
      <price>5.95</price>
      <publish_date>2000-12-16</publish_date>
      <description>A former architect battles corporate zombies, 
      an evil sorceress, and her own childhood to become queen 
      of the world.</description>
   </book>
   <book id="bk103">
      <author>Corets, Eva</author>
      <title>Maeve Ascendant</title>
      <genre>Fantasy</genre>
      <price>5.95</price>
      <publish_date>2000-11-17</publish_date>
      <description>After the collapse of a nanotechnology 
      society in England, the young survivors lay the 
      foundation for a new society.</description>
   </book>
   <book id="bk104">
      <author>Corets, Eva</author>
      <title>Oberon's Legacy</title>
      <genre>Fantasy</genre>
      <price>5.95</price>
      <publish_date>2001-03-10</publish_date>
      <description>In post-apocalypse England, the mysterious 
      agent known only as Oberon helps to create a new life 
      for the inhabitants of London. Sequel to Maeve 
      Ascendant.</description>
   </book>
   <book id="bk105">
      <author>Corets, Eva</author>
      <title>The Sundered Grail</title>
      <genre>Fantasy</genre>
      <price>5.95</price>
      <publish_date>2001-09-10</publish_date>
      <description>The two daughters of Maeve, half-sisters, 
      battle one another for control of England. Sequel to 
      Oberon's Legacy.</description>
   </book>
   <book id="bk106">
      <author>Randall, Cynthia</author>
      <title>Lover Birds</title>
      <genre>Romance</genre>
      <price>4.95</price>
      <publish_date>2000-09-02</publish_date>
      <description>When Carla meets Paul at an ornithology 
      conference, tempers fly as feathers get ruffled.</description>
   </book>
   <book id="bk107">
      <author>Thurman, Paula</author>
      <title>Splish Splash</title>
      <genre>Romance</genre>
      <price>4.95</price>
      <publish_date>2000-11-02</publish_date>
      <description>A deep sea diver finds true love twenty 
      thousand leagues beneath the sea.</description>
   </book>
   <book id="bk108">
      <author>Knorr, Stefan</author>
      <title>Creepy Crawlies</title>
      <genre>Horror</genre>
      <price>4.95</price>
      <publish_date>2000-12-06</publish_date>
      <description>An anthology of horror stories about roaches,
      centipedes, scorpions  and other insects.</description>
   </book>
   <book id="bk109">
      <author>Kress, Peter</author>
      <title>Paradox Lost</title>
      <genre>Science Fiction</genre>
      <price>6.95</price>
      <publish_date>2000-11-02</publish_date>
      <description>After an inadvertant trip through a Heisenberg
      Uncertainty Device, James Salway discovers the problems 
      of being quantum.</description>
   </book>
   <book id="bk110">
      <author>O'Brien, Tim</author>
      <title>Microsoft .NET: The Programming Bible</title>
      <genre>Computer</genre>
      <price>36.95</price>
      <publish_date>2000-12-09</publish_date>
      <description>Microsoft's .NET initiative is explored in 
      detail in this deep programmer's reference.</description>
   </book>
   <book id="bk111">
      <author>O'Brien, Tim</author>
      <title>MSXML3: A Comprehensive Guide</title>
      <genre>Computer</genre>   
      <price>36.95</price>
      <publish_date>2000-12-01</publish_date>
      <description>The Microsoft MSXML3 parser is covered in 
      detail, with attention to XML DOM interfaces, XSLT processing, 
      SAX and more.</description>
   </book>
   <book id="bk112">
      <author>Galos, Mike</author>
      <title>Visual Studio 7: A Comprehensive Guide</title>
      <genre>Computer</genre>
      <price>49.95</price>
      <publish_date>2001-04-16</publish_date>
      <description>Microsoft Visual Studio 7 is explored in depth,
      looking at how Visual Basic, Visual C++, C#, and ASP+ are 
      integrated into a comprehensive development 
      environment.</description>
   </book>
</catalog>

recursiveXMLParser.R

rm(list=ls())
library(XML)
# @ramnarasimhan

# for additional help please refer to :
# http://statistics.berkeley.edu/classes/s133/XML-a.html


#Recursive Function to visit the XML tree (depth first)
visitNode <- function(node) {
  if (is.null(node)) {
    #leaf node reached. Turn back
    return()
  }
  print(paste("Node: ", xmlName(node)))
  num.children = xmlSize(node)  
  if(num.children == 0 ) {
    # Add your code to process the leaf node here
    
    print( paste("   ", xmlValue(node)))
  }
  #Go one level deeper
  for (i in 1 : num.children) {
    visitNode(node[[i]]) #the i-th child of node
  }
}

xmlfile <- "books.xml"

#read the XML tree into memory
xtree <- xmlInternalTreeParse(xmlfile)
root <- xmlRoot(xtree)
visitNode(root)

Hi Ram,
I have tried your code but was given an error message:
Error in [[.XMLInternalElementNode(node, i) :
cannot index an internal node with a negative number -1

Could you help please?
Tilly

Tilly - wrap the "one level deeper" statement in a conditional:

if (num.children > 0) { 
  for (i in 1 : num.children) { 
    visitNode(node[[i]]) #the i-th child of node 
  } 
}