launch.json

{
    // Use IntelliSense to learn about possible attributes.
    // Hover to view descriptions of existing attributes.
    // For more information, visit: https://go.microsoft.com/fwlink/?linkid=830387
    "version": "0.2.0",
    "configurations": [
        {
            "name": "Listen for Xdebug",
            "type": "php",
            "request": "launch",
            "port": 9000,
            "pathMappings": {
                //"/var/www/html": "${workspaceFolder}"
                //nao consegui fazer funcionar acima
                "/var/www/html": "Code/php/"
            }
        },
        {
            "name": "Launch currently open script",
            "type": "php",
            "request": "launch",
            "program": "${file}",
            "cwd": "${fileDirname}",
            "port": 9000
        }
    ]
}

Testar "${workspaceRoot}" ao invés de ${workspaceFolder}?