pchome.py

 #!/usr/bin/python
# -*- coding: utf-8 -*-

import sys  
import requests 

headers = {
    'User-Agent': 'Mozilla/5.0 (Macintosh; Intel Mac OS X 10_9_1) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/32.0.1700.107 Safari/537.36',
}

cookies = {
    '_ts_id':  '999999999999999999', 
}
  
reload(sys)  
sys.setdefaultencoding('utf8')  

h = requests.get('http://class.ruten.com.tw/user/index00.php?s=nevereverfor', headers=headers, cookies=cookies)

#print h.text # 亂碼
#b = h.text.encode('latin-1').decode('big5') # UnicodeDecodeError: 'big5'

b = h.text.encode('latin-1').decode('utf-8')
print(b)