SendToAll.py

from telegram import ParseMode
from telegram.ext import Updater
import time

updater = Updater('BOT-TOKEN-ID')

chatIds = ["109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039",
           "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039",
           "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039",
           "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039",
           "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039", "109416039"]


notSendIds = []

for chat_id in chatIds:
    try:
        updater.bot.send_message(chat_id=chat_id,
                                 text='*Your Desire Only Text*',
                                 parse_mode=ParseMode.MARKDOWN)
        updater.bot.sendPhoto(chat_id=chat_id,
                              photo='https://telegram.org/img/t_logo.png',
                              caption="Image with Caption!")
    except:
        notSendIds.append(chat_id)
    time.sleep(5)

print("\nYour message was not send to these users:\n")
for id in notSendIds:
    print(id)
print("\nTotal: " + str(len(notSendIds)) + "/" + str(len(chatIds)))