Serving pre-gzipped assets from Apache

.htaccess

AddEncoding gzip .gz

RewriteEngine on
RewriteCond %{HTTP:Accept-encoding} gzip
RewriteCond %{HTTP_USER_AGENT} !Konqueror
RewriteCond %{REQUEST_FILENAME}.gz -f
RewriteRule ^(.*)\.css$ $1.css.gz [QSA,L]
RewriteRule ^(.*)\.js$ $1.js.gz [QSA,L]
RewriteRule ^(.*)\.html$ $1.html.gz [QSA,L]

Also you should add:
<Files *.css.gz>
ForceType text/css
</Files>
<Files *.js.gz>
ForceType application/javascript
</Files>
<Files *.html.gz>
ForceType text/html
</Files>

or browsers will not recognize css