Redirect to post if a search only returns one post.. Just paste the following code snippet into your functions.php file:

wordpress-redirect-post-single-query.php

add_action('template_redirect', 'redirect_single_post');
function redirect_single_post() {
    if (is_search()) {
        global $wp_query;
        if ($wp_query->post_count == 1) {
            wp_redirect( get_permalink( $wp_query->posts['0']->ID ) );
        }
    }
}