You don't need to memorise ASCII as there is a handy chart available by typing man ascii
in a Terminal.
However, you may find it useful to remember some fun facts about ASCII.
Blocks of 32 are useful. 32 is 2⁵ (2 raised to the power 5) and a block of 32 is enough to represent all 26 common english letters plus some extra stuff.
ASCII is a coding for the first 128 numbers. 0 to 127.