Initially, these four outcomes are equally probable:
older child younger child
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boy boy P = 1/4
boy girl P = 1/4
girl boy P = 1/4
girl girl P = 1/4
Now I tell you that one of the children is a boy:
older child younger child
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boy boy P = 1/3
boy girl P = 1/3
girl boy P = 1/3
Note that if I identify which child is a boy, the probability is 1/2. For instance, suppose I tell you that one of the children is a boy, and it's the older of the two children. Then:
older child younger child
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boy boy P = 1/2
boy girl P = 1/2