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Ensure the game is closed.
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Navigate to your Steam directory.
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Navigate to the xml. Risk of Rain 2 is game id 632360. The path should look something like this:
Steam\userdata\<userid>\632360\remote\UserProfiles\<hash>.xml
Update coins field to however many lunar coins you want.
<coins>63</coins>
Replace your achievementsList field with the following:
<achievementsList>KillEliteMonster CompleteTeleporter CompleteThreeStages FailShrineChance LoopOnce StayAlive1 Discover10UniqueTier1 CompleteUnknownEnding RepeatedlyDuplicateItems Discover5Equipment TotalMoneyCollected Die5Times RepeatFirstTeleporter KillBossQuick Complete30StagesCareer AttackSpeed MaxHealingShrine FindTimedChest TotalDronesRepaired KillTotalEnemies MoveSpeed HardHitter CompleteTeleporterWithoutInjury MajorMultikill KillElementalLemurians CompleteMultiBossShrine LogCollector ChargeTeleporterWhileNearDeath FreeMage CompletePrismaticTrial FindDevilAltar CompleteThreeStagesWithoutHealing CarryLunarItems Complete20Stages FindUniqueNewtStatues SuicideHermitCrabs HardEliteBossKill</achievementsList>