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History|-263757b8|entries.json
{"version":1,"resource":"file:///Users/Rob-TIF/Desktop/TIF%20Projects/baby_brezza/France/assets/pandectes-settings.json","entries":[{"id":"S8rC.json","timestamp":1654872463516},{"id":"Fuzs.json","timestamp":1654872500982},{"id":"wXAk.json","timestamp":1654872587981}]}
Raw
History|-263757b8|Fuzs.json
{
"store": {
"plan": "plus",
"theme": "LIVE THEME [don't switch out]",
"primaryLocale": "fr"
},
"tsPublished": 1654870844,
"declaration": {
"showPurpose": true,
"showProvider": true,
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},
"language": {
"languageMode": "Single",
"fallbackLanguage": "fr",
"languageDetection": "browser",
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},
"texts": {
"managed": {
"headerText": {
"fr": "Nous respectons votre vie privée"
},
"consentText": {
"fr": "Gérer mes cookies\n\nNotre site babybrezza.fr et nos partenaires utilisent des cookies pour vous proposer de la publicité personnalisée, de la publicité géolocalisée, ainsi que pour vous permettre de partager du contenu sur les réseaux sociaux. Nous conservons votre choix pendant 6 mois.\n\n

En cliquant sur \"Tout accepter\" vous consentez à l'utilisation de cookies pour l'ensemble des finalités ci-dessous."
},
"dismissButtonText": {
"fr": "D'accord"
},
"linkText": {
"fr": "Consulter la politique cookies"
},
"preferencesButtonText": {
"fr": "Personnaliser"
},
"allowButtonText": {
"fr": "Tout Accepter"
},
"denyButtonText": {
"fr": "Déclin"
},
"leaveSiteButtonText": {
"fr": "Quitter ce site"
},
"cookiePolicyText": {
"fr": "Politique de cookies"
},
"preferencesPopupTitleText": {
"fr": "Gérer les préférences de consentement"
},
"preferencesPopupIntroText": {
"fr": "Nous utilisons des cookies pour optimiser les fonctionnalités du site Web, analyser les performances et vous offrir une expérience personnalisée. Certains cookies sont indispensables au bon fonctionnement et au bon fonctionnement du site. Ces cookies ne peuvent pas être désactivés. Dans cette fenêtre, vous pouvez gérer votre préférence de cookies."
},
"preferencesPopupCloseButtonText": {
"fr": "proche"
},
"preferencesPopupAcceptAllButtonText": {
"fr": "Accepter tout"
},
"preferencesPopupRejectAllButtonText": {
"fr": "Tout rejeter"
},
"preferencesPopupSaveButtonText": {
"fr": "Enregistrer les préférences"
},
"accessSectionTitleText": {
"fr": "Portabilité des données"
},
"accessSectionParagraphText": {
"fr": "Vous avez le droit de pouvoir accéder à vos données à tout moment."
},
"rectificationSectionTitleText": {
"fr": "Rectification des données"
},
"rectificationSectionParagraphText": {
"fr": "Vous avez le droit de demander la mise à jour de vos données chaque fois que vous le jugez approprié."
},
"erasureSectionTitleText": {
"fr": "Droit à l'oubli"
},
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"fr": "Vous avez le droit de demander que toutes vos données soient effacées. Après cela, vous ne pourrez plus accéder à votre compte."
}
},
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"fr": "Cookies strictement nécessaires"
},
"functionalityCookiesTitleText": {
"fr": "Cookies fonctionnels"
},
"performanceCookiesTitleText": {
"fr": "Cookies de performances"
},
"targetingCookiesTitleText": {
"fr": "Ciblage des cookies"
},
"unclassifiedCookiesTitleText": {
"fr": "Cookies non classés"
},
"strictlyNecessaryCookiesDescriptionText": {
"fr": "Ces cookies sont essentiels pour vous permettre de vous déplacer sur le site Web et d'utiliser ses fonctionnalités, telles que l'accès aux zones sécurisées du site Web. Le site Web ne peut pas fonctionner correctement sans ces cookies."
},
"functionalityCookiesDescriptionText": {
"fr": "Ces cookies permettent au site de fournir des fonctionnalités et une personnalisation améliorées. Ils peuvent être définis par nous ou par des fournisseurs tiers dont nous avons ajouté les services à nos pages. Si vous n'autorisez pas ces cookies, certains ou tous ces services peuvent ne pas fonctionner correctement."
},
"performanceCookiesDescriptionText": {
"fr": "Ces cookies nous permettent de surveiller et d'améliorer les performances de notre site Web. Par exemple, ils nous permettent de compter les visites, d'identifier les sources de trafic et de voir quelles parties du site sont les plus populaires."
},
"targetingCookiesDescriptionText": {
"fr": "Ces cookies peuvent être installés via notre site par nos partenaires publicitaires. Ils peuvent être utilisés par ces sociétés pour établir un profil de vos intérêts et vous montrer des publicités pertinentes sur d'autres sites. Ils ne stockent pas directement d'informations personnelles, mais sont basés sur l'identification unique de votre navigateur et de votre appareil Internet. Si vous n'autorisez pas ces cookies, vous bénéficierez d'une publicité moins ciblée."
},
"unclassifiedCookiesDescriptionText": {
"fr": "Les cookies non classés sont des cookies que nous sommes en train de classer avec les fournisseurs de cookies individuels."
}
},
"auto": {
"declName": {
"fr": "Nom"
},
"declPath": {
"fr": "Chemin"
},
"declType": {
"fr": "Taper"
},
"declDomain": {
"fr": "Domaine"
},
"declPurpose": {
"fr": "But"
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"fr": "Fournisseur"
},
"declRetention": {
"fr": "Rétention"
},
"declFirstParty": {
"fr": "First-party"
},
"declThirdParty": {
"fr": "Tierce personne"
},
"cookiesDetailsText": {
"fr": "Détails des cookies"
},
"preferencesPopupAlwaysAllowedText": {
"fr": "Toujours permis"
},
"submitButton": {
"fr": "Soumettre"
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"fr": "Soumission..."
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"fr": "Annuler"
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},
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},
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"fr": "L'email n'est pas valide"
},
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"fr": "Merci pour votre requête"
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"guestsSupportEmailFailureTitle": {
"fr": "Un problème est survenu"
},
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"fr": "Si vous êtes inscrit en tant que client de ce magasin, vous recevrez bientôt un e-mail avec des instructions sur la marche à suivre."
},
"guestsSupportEmailFailureMessage": {
"fr": "Votre demande n'a pas été soumise. Veuillez réessayer et si le problème persiste, contactez le propriétaire du magasin pour obtenir de l'aide."
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"fr": "Un problème est survenu"
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},
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"fr": "Votre demande n'a pas été vérifiée. Veuillez réessayer et si le problème persiste, contactez le propriétaire du magasin pour obtenir de l'aide"
},
"consentSectionTitleText": {
"fr": "Consentement à la politique de cookies"
},
"consentSectionNoConsentText": {
"fr": "Vous n'avez pas consenti à la politique de cookies de ce site Web."
},
"consentSectionConsentedText": {
"fr": "Vous avez consenti à la politique de cookies de ce site Web sur"
},
"consentSectionChangeConsentActionText": {
"fr": "Révoquer le consentement"
},
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"fr": "Demandes des personnes concernées"
},
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"fr": "Données personnelles"
},
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"fr": "Ordres"
},
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"fr": "Tout télécharger"
},
"rectificationCommentPlaceholder": {
"fr": "Décrivez ce que vous souhaitez mettre à jour"
},
"rectificationCommentValidationError": {
"fr": "Un commentaire est requis"
},
"rectificationSectionEditAccountActionText": {
"fr": "Demander une mise à jour"
},
"erasureSectionRequestDeletionActionText": {
"fr": "Demander la suppression des données personnelles"
}
}
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"backgroundForCalculations": {
"a": 1,
"b": 255,
"g": 255,
"r": 255
},
"text": "#000000"
},
"button": {
"background": "#44989A",
"backgroundForCalculations": {
"a": 1,
"b": 154,
"g": 152,
"r": 68
},
"text": "#FFFFFF",
"textForCalculation": {
"a": 1,
"b": 255,
"g": 255,
"r": 255
},
"border": "transparent"
}
},
"content": {
"href": "https:\/\/babybrezzafrance.myshopify.com\/policies\/privacy-policy",
"close": "✕",
"target": "_blank",
"logo": "<img class=\"cc-banner-logo\" style=\"height: 49px;\" src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0560\/5126\/9839\/t\/5\/assets\/pandectes-logo.png?v=1654869306\" alt=\"Baby Brezza France\" \/>"
},
"window": "<div role=\"dialog\" aria-live=\"polite\" aria-label=\"cookieconsent\" aria-describedby=\"cookieconsent:desc\" id=\"pandectes-banner\" class=\"cc-window-wrapper cc-bottom-wrapper\"><div class=\"pd-cookie-banner-window cc-window {{classes}}\"><!--googleoff: all-->{{children}}<!--googleon: all--><\/div><\/div>",
"compliance": {
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},
"type": "custom",
"layouts": {
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"position": "bottom",
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"path": "\/",
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},
{
"name": "_shopify_tm",
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"path": "\/",
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},
{
"name": "cart_ver",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
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}
},
{
"name": "cart_sig",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
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"retention": "1 year(s)",
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},
{
"name": "cart_ts",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
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"fr": "Utilisé en relation avec le paiement."
}
},
{
"name": "cart",
"domain": "babybrezza.fr",
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"provider": "Shopify",
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"retention": "1 year(s)",
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"fr": "Nécessaire pour la fonctionnalité de panier d'achat sur le site Web."
}
},
{
"name": "secure_customer_sig",
"domain": "babybrezza.fr",
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"fr": "Utilisé en relation avec la connexion client."
}
},
{
"name": "_tracking_consent",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
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"fr": "Préférences de suivi."
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},
{
"name": "_shopify_tw",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
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}
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"1": [
{
"name": "_shopify_sa_t",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
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"purpose": {
"fr": "Analyses Shopify relatives au marketing et aux références."
}
},
{
"name": "_landing_page",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
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"retention": "Session",
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"fr": "Suit les pages de destination."
}
},
{
"name": "_shopify_s",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
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"fr": "Analyses Shopify."
}
},
{
"name": "_orig_referrer",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Suit les pages de destination."
}
},
{
"name": "_shopify_y",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
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"fr": "Analyses Shopify."
}
},
{
"name": "_s",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
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},
{
"name": "_y",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
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"path": "\/",
"provider": "Pandectes",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé pour la fonctionnalité de la bannière de consentement aux cookies."
}
},
{
"name": "_shopify_sa_p",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
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"purpose": {
"fr": "Analyses Shopify relatives au marketing et aux références."
}
},
{
"name": "_shopify_d",
"domain": ".babybrezza.fr",
"path": "\/",
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},
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}
},
{
"name": "_shopify_evids",
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}
}
],
"2": [
{
"name": "_ga",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Google",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Le cookie est défini par Google Analytics avec une fonctionnalité inconnue"
}
}
],
"4": [
],
"8": [
{
"name": "_ga_BHLT83V6M4",
"domain": ".babybrezza.fr",
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"provider": "Unknown",
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"fr": ""
}
},
{
"name": "localization",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Unknown",
"firstParty": true,
"retention": "1 year(s)",
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"fr": ""
}
}
]
},
"blocker": {
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"googleConsentMode": {
"id": "",
"analyticsId": "",
"isActive": false,
"dataLayerPropertyName": "dataLayer",
"adStorageCategory": 4,
"analyticsStorageCategory": 2,
"personalizationStorageCategory": 1,
"functionalityStorageCategory": 1,
"customEvent": true,
"securityStorageCategory": 0,
"redactData": true,
"urlPassthrough": false
},
"facebookPixel": {
"id": "",
"isActive": false,
"ldu": false
},
"rakuten": {
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"cmp": false,
"ccpa": false
},
"defaultBlocked": 0,
"patterns": {
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],
"blackList": {
"1": [
],
"2": [
],
"4": [
],
"8": [
]
}
}
}
}
Raw
History|-263757b8|S8rC.json
{
"store": {
"plan": "plus",
"theme": "LIVE THEME [don't switch out]",
"primaryLocale": "fr"
},
"tsPublished": 1654870844,
"declaration": {
"showPurpose": true,
"showProvider": true,
"showDateGenerated": false
},
"language": {
"languageMode": "Single",
"fallbackLanguage": "fr",
"languageDetection": "browser",
"languagesSupported": [
]
},
"texts": {
"managed": {
"headerText": {
"fr": "Nous respectons votre vie privée"
},
"consentText": {
"fr": "Gérer mes cookies\n\nNotre site babybrezza.fr et nos partenaires utilisent des cookies pour vous proposer de la publicité personnalisée, de la publicité géolocalisée, ainsi que pour vous permettre de partager du contenu sur les réseaux sociaux. Nous conservons votre choix pendant 6 mois.\n\n

En cliquant sur \"Tout accepter\" vous consentez à l'utilisation de cookies pour l'ensemble des finalités ci-dessous."
},
"dismissButtonText": {
"fr": "D'accord"
},
"linkText": {
"fr": "Consulter la politique cookies"
},
"preferencesButtonText": {
"fr": "Personnaliser"
},
"allowButtonText": {
"fr": "Tout Accepter"
},
"denyButtonText": {
"fr": "Déclin"
},
"leaveSiteButtonText": {
"fr": "Quitter ce site"
},
"cookiePolicyText": {
"fr": "Politique de cookies"
},
"preferencesPopupTitleText": {
"fr": "Gérer les préférences de consentement"
},
"preferencesPopupIntroText": {
"fr": "Nous utilisons des cookies pour optimiser les fonctionnalités du site Web, analyser les performances et vous offrir une expérience personnalisée. Certains cookies sont indispensables au bon fonctionnement et au bon fonctionnement du site. Ces cookies ne peuvent pas être désactivés. Dans cette fenêtre, vous pouvez gérer votre préférence de cookies."
},
"preferencesPopupCloseButtonText": {
"fr": "proche"
},
"preferencesPopupAcceptAllButtonText": {
"fr": "Accepter tout"
},
"preferencesPopupRejectAllButtonText": {
"fr": "Tout rejeter"
},
"preferencesPopupSaveButtonText": {
"fr": "Enregistrer les préférences"
},
"accessSectionTitleText": {
"fr": "Portabilité des données"
},
"accessSectionParagraphText": {
"fr": "Vous avez le droit de pouvoir accéder à vos données à tout moment."
},
"rectificationSectionTitleText": {
"fr": "Rectification des données"
},
"rectificationSectionParagraphText": {
"fr": "Vous avez le droit de demander la mise à jour de vos données chaque fois que vous le jugez approprié."
},
"erasureSectionTitleText": {
"fr": "Droit à l'oubli"
},
"erasureSectionParagraphText": {
"fr": "Vous avez le droit de demander que toutes vos données soient effacées. Après cela, vous ne pourrez plus accéder à votre compte."
}
},
"categories": {
"strictlyNecessaryCookiesTitleText": {
"fr": "Cookies strictement nécessaires"
},
"functionalityCookiesTitleText": {
"fr": "Cookies fonctionnels"
},
"performanceCookiesTitleText": {
"fr": "Cookies de performances"
},
"targetingCookiesTitleText": {
"fr": "Ciblage des cookies"
},
"unclassifiedCookiesTitleText": {
"fr": "Cookies non classés"
},
"strictlyNecessaryCookiesDescriptionText": {
"fr": "Ces cookies sont essentiels pour vous permettre de vous déplacer sur le site Web et d'utiliser ses fonctionnalités, telles que l'accès aux zones sécurisées du site Web. Le site Web ne peut pas fonctionner correctement sans ces cookies."
},
"functionalityCookiesDescriptionText": {
"fr": "Ces cookies permettent au site de fournir des fonctionnalités et une personnalisation améliorées. Ils peuvent être définis par nous ou par des fournisseurs tiers dont nous avons ajouté les services à nos pages. Si vous n'autorisez pas ces cookies, certains ou tous ces services peuvent ne pas fonctionner correctement."
},
"performanceCookiesDescriptionText": {
"fr": "Ces cookies nous permettent de surveiller et d'améliorer les performances de notre site Web. Par exemple, ils nous permettent de compter les visites, d'identifier les sources de trafic et de voir quelles parties du site sont les plus populaires."
},
"targetingCookiesDescriptionText": {
"fr": "Ces cookies peuvent être installés via notre site par nos partenaires publicitaires. Ils peuvent être utilisés par ces sociétés pour établir un profil de vos intérêts et vous montrer des publicités pertinentes sur d'autres sites. Ils ne stockent pas directement d'informations personnelles, mais sont basés sur l'identification unique de votre navigateur et de votre appareil Internet. Si vous n'autorisez pas ces cookies, vous bénéficierez d'une publicité moins ciblée."
},
"unclassifiedCookiesDescriptionText": {
"fr": "Les cookies non classés sont des cookies que nous sommes en train de classer avec les fournisseurs de cookies individuels."
}
},
"auto": {
"declName": {
"fr": "Nom"
},
"declPath": {
"fr": "Chemin"
},
"declType": {
"fr": "Taper"
},
"declDomain": {
"fr": "Domaine"
},
"declPurpose": {
"fr": "But"
},
"declProvider": {
"fr": "Fournisseur"
},
"declRetention": {
"fr": "Rétention"
},
"declFirstParty": {
"fr": "First-party"
},
"declThirdParty": {
"fr": "Tierce personne"
},
"cookiesDetailsText": {
"fr": "Détails des cookies"
},
"preferencesPopupAlwaysAllowedText": {
"fr": "Toujours permis"
},
"submitButton": {
"fr": "Soumettre"
},
"submittingButton": {
"fr": "Soumission..."
},
"cancelButton": {
"fr": "Annuler"
},
"guestsSupportInfoText": {
"fr": "Veuillez vous connecter avec votre compte client pour continuer."
},
"guestsSupportEmailPlaceholder": {
"fr": "Adresse e-mail"
},
"guestsSupportEmailValidationError": {
"fr": "L'email n'est pas valide"
},
"guestsSupportEmailSuccessTitle": {
"fr": "Merci pour votre requête"
},
"guestsSupportEmailFailureTitle": {
"fr": "Un problème est survenu"
},
"guestsSupportEmailSuccessMessage": {
"fr": "Si vous êtes inscrit en tant que client de ce magasin, vous recevrez bientôt un e-mail avec des instructions sur la marche à suivre."
},
"guestsSupportEmailFailureMessage": {
"fr": "Votre demande n'a pas été soumise. Veuillez réessayer et si le problème persiste, contactez le propriétaire du magasin pour obtenir de l'aide."
},
"confirmationSuccessTitle": {
"fr": "Votre demande est vérifiée"
},
"confirmationFailureTitle": {
"fr": "Un problème est survenu"
},
"confirmationSuccessMessage": {
"fr": "Nous reviendrons rapidement vers vous quant à votre demande."
},
"confirmationFailureMessage": {
"fr": "Votre demande n'a pas été vérifiée. Veuillez réessayer et si le problème persiste, contactez le propriétaire du magasin pour obtenir de l'aide"
},
"consentSectionTitleText": {
"fr": "Consentement à la politique de cookies"
},
"consentSectionNoConsentText": {
"fr": "Vous n'avez pas consenti à la politique de cookies de ce site Web."
},
"consentSectionConsentedText": {
"fr": "Vous avez consenti à la politique de cookies de ce site Web sur"
},
"consentSectionChangeConsentActionText": {
"fr": "Révoquer le consentement"
},
"accessSectionGDPRRequestsActionText": {
"fr": "Demandes des personnes concernées"
},
"accessSectionAccountInfoActionText": {
"fr": "Données personnelles"
},
"accessSectionOrdersRecordsActionText": {
"fr": "Ordres"
},
"accessSectionDownloadReportActionText": {
"fr": "Tout télécharger"
},
"rectificationCommentPlaceholder": {
"fr": "Décrivez ce que vous souhaitez mettre à jour"
},
"rectificationCommentValidationError": {
"fr": "Un commentaire est requis"
},
"rectificationSectionEditAccountActionText": {
"fr": "Demander une mise à jour"
},
"erasureSectionRequestDeletionActionText": {
"fr": "Demander la suppression des données personnelles"
}
}
},
"library": {
"previewMode": false,
"fadeInTimeout": 0,
"defaultBlocked": 0,
"showLink": true,
"enabled": true,
"cookie": {
"name": "_pandectes_gdpr",
"expiryDays": 365,
"secure": true
},
"dismissOnScroll": false,
"dismissOnWindowClick": true,
"dismissOnTimeout": false,
"palette": {
"popup": {
"background": "#FFFFFF",
"backgroundForCalculations": {
"a": 1,
"b": 255,
"g": 255,
"r": 255
},
"text": "#000000"
},
"button": {
"background": "#44989A",
"backgroundForCalculations": {
"a": 1,
"b": 154,
"g": 152,
"r": 68
},
"text": "#FFFFFF",
"textForCalculation": {
"a": 1,
"b": 255,
"g": 255,
"r": 255
},
"border": "transparent"
}
},
"content": {
"href": "https:\/\/babybrezzafrance.myshopify.com\/policies\/privacy-policy",
"close": "&#10005;",
"target": "_blank",
"logo": "<img class=\"cc-banner-logo\" style=\"height: 49px;\" src=\"https:\/\/cdn.shopify.com\/s\/files\/1\/0560\/5126\/9839\/t\/5\/assets\/pandectes-logo.png?v=1654869306\" alt=\"Baby Brezza France\" \/>"
},
"window": "<div role=\"dialog\" aria-live=\"polite\" aria-label=\"cookieconsent\" aria-describedby=\"cookieconsent:desc\" id=\"pandectes-banner\" class=\"cc-window-wrapper cc-bottom-wrapper\"><div class=\"pd-cookie-banner-window cc-window {{classes}}\"><!--googleoff: all-->{{children}}<!--googleon: all--><\/div><\/div>",
"compliance": {
"custom": "<div class=\"cc-compliance cc-highlight\">{{preferences}}{{allow}}<\/div>"
},
"type": "custom",
"layouts": {
"basic": "{{logo}}{{messagelink}}{{compliance}}"
},
"position": "bottom",
"theme": "classic",
"revokable": false,
"animateRevokable": false,
"static": false,
"autoAttach": true,
"hasTransition": true,
"blacklistPage": [
""
]
},
"geolocation": {
"brOnly": false,
"caOnly": false,
"euOnly": false
},
"dsr": {
"guestsSupport": false,
"accessSectionDownloadReportAuto": false
},
"banner": {
"resetTs": 1654200958,
"extraCss": " .cc-banner-logo {max-width: 24em!important;} @media(min-width: 768px) {.cc-window.cc-floating{max-width: 24em!important;width: 24em!important;}} .cc-message, .cc-header, .cc-logo {text-align: left} .cc-window-wrapper{z-index: 2147483647;} .cc-window{padding: 29px!important;z-index: 2147483647;font-size: 14px!important;font-family: inherit;} .cc-header{font-size: 14px!important;font-family: inherit;} .pd-cp-ui{font-family: inherit; background-color: #FFFFFF;color:#000000;} .pd-cp-btn{background-color:#44989A;color:#FFFFFF!important;} input + .pd-cp-preferences-slider{background-color: rgba(0, 0, 0, 0.3)} .pd-cp-scrolling-section::-webkit-scrollbar{background-color: rgba(0, 0, 0, 0.3)} input:checked + .pd-cp-preferences-slider{background-color: rgba(0, 0, 0, 1)} .pd-cp-scrolling-section::-webkit-scrollbar-thumb {background-color: rgba(0, 0, 0, 1)} .pd-cp-ui-close{color:#000000;} .pd-cp-preferences-slider:before{background-color: #FFFFFF} .pd-cp-title:before {border-color: #000000!important} .pd-cp-preferences-slider{background-color:#000000} .pd-cp-toggle{color:#000000!important} @media(max-width:699px) {.pd-cp-ui-close-top svg {fill: #000000}} .pd-cp-toggle:hover,.pd-cp-toggle:visited,.pd-cp-toggle:active{color:#000000!important} .pd-cookie-banner-window {box-shadow: 0 0 18px rgb(0 0 0 \/ 20%);} ",
"customJavascript": "function() {console.log('fooo')}",
"showPoweredBy": false,
"isActive": false,
"implicitSavePreferences": true,
"cookieIcon": false,
"blockBots": false,
"showCookiesDetails": true,
"cookiesBlockedByDefault": "0",
"hasTransition": true,
"blockingPage": false,
"showOnlyLandingPage": false,
"leaveSiteUrl": "https:\/\/www.google.com",
"linkRespectStoreLang": false
},
"cookies": {
"0": [
{
"name": "_shopify_m",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé pour gérer les paramètres de confidentialité des clients."
}
},
{
"name": "_shopify_tm",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé pour gérer les paramètres de confidentialité des clients."
}
},
{
"name": "cart_ver",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé en relation avec le panier d'achat."
}
},
{
"name": "cart_sig",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Analyses Shopify."
}
},
{
"name": "cart_ts",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé en relation avec le paiement."
}
},
{
"name": "cart",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Nécessaire pour la fonctionnalité de panier d'achat sur le site Web."
}
},
{
"name": "secure_customer_sig",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé en relation avec la connexion client."
}
},
{
"name": "_tracking_consent",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Préférences de suivi."
}
},
{
"name": "_shopify_tw",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé pour gérer les paramètres de confidentialité des clients."
}
}
],
"1": [
{
"name": "_shopify_sa_t",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify relatives au marketing et aux références."
}
},
{
"name": "_landing_page",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Suit les pages de destination."
}
},
{
"name": "_shopify_s",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify."
}
},
{
"name": "_orig_referrer",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Suit les pages de destination."
}
},
{
"name": "_shopify_y",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify."
}
},
{
"name": "_s",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify."
}
},
{
"name": "_y",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify."
}
},
{
"name": "_pandectes_gdpr",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Pandectes",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé pour la fonctionnalité de la bannière de consentement aux cookies."
}
},
{
"name": "_shopify_sa_p",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify relatives au marketing et aux références."
}
},
{
"name": "_shopify_d",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify."
}
},
{
"name": "_shopify_evids",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify."
}
},
{
"name": "_shopify_evids",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Analyses Shopify."
}
}
],
"2": [
{
"name": "_ga",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Google",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Le cookie est défini par Google Analytics avec une fonctionnalité inconnue"
}
}
],
"4": [
],
"8": [
{
"name": "_ga_BHLT83V6M4",
"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Unknown",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": ""
}
},
{
"name": "localization",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Unknown",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": ""
}
}
]
},
"blocker": {
"isActive": false,
"googleConsentMode": {
"id": "",
"analyticsId": "",
"isActive": false,
"dataLayerPropertyName": "dataLayer",
"adStorageCategory": 4,
"analyticsStorageCategory": 2,
"personalizationStorageCategory": 1,
"functionalityStorageCategory": 1,
"customEvent": true,
"securityStorageCategory": 0,
"redactData": true,
"urlPassthrough": false
},
"facebookPixel": {
"id": "",
"isActive": false,
"ldu": false
},
"rakuten": {
"isActive": false,
"cmp": false,
"ccpa": false
},
"defaultBlocked": 0,
"patterns": {
"whiteList": [
],
"blackList": {
"1": [
],
"2": [
],
"4": [
],
"8": [
]
}
}
}
}
Raw
History|-263757b8|wXAk.json
{
"store": {
"plan": "plus",
"theme": "LIVE THEME [don't switch out]",
"primaryLocale": "fr"
},
"tsPublished": 1654872166,
"declaration": {
"showPurpose": true,
"showProvider": true,
"showDateGenerated": false
},
"language": {
"languageMode": "Single",
"fallbackLanguage": "fr",
"languageDetection": "browser",
"languagesSupported": [
]
},
"texts": {
"managed": {
"headerText": {
"fr": "Nous respectons votre vie privée"
},
"consentText": {
"fr": "Notre site babybrezza.fr et nos partenaires utilisent des cookies pour vous proposer de la publicité personnalisée, de la publicité géolocalisée, ainsi que pour vous permettre de partager du contenu sur les réseaux sociaux. Nous conservons votre choix pendant 6 mois.\n\n

En cliquant sur \"Tout accepter\" vous consentez à l'utilisation de cookies pour l'ensemble des finalités ci-dessous."
},
"dismissButtonText": {
"fr": "D'accord"
},
"linkText": {
"fr": "Consulter la politique cookies"
},
"preferencesButtonText": {
"fr": "Personnaliser"
},
"allowButtonText": {
"fr": "Tout Accepter"
},
"denyButtonText": {
"fr": "Déclin"
},
"leaveSiteButtonText": {
"fr": "Quitter ce site"
},
"cookiePolicyText": {
"fr": "Politique de cookies"
},
"preferencesPopupTitleText": {
"fr": "Gérer les préférences de consentement"
},
"preferencesPopupIntroText": {
"fr": "Nous utilisons des cookies pour optimiser les fonctionnalités du site Web, analyser les performances et vous offrir une expérience personnalisée. Certains cookies sont indispensables au bon fonctionnement et au bon fonctionnement du site. Ces cookies ne peuvent pas être désactivés. Dans cette fenêtre, vous pouvez gérer votre préférence de cookies."
},
"preferencesPopupCloseButtonText": {
"fr": "proche"
},
"preferencesPopupAcceptAllButtonText": {
"fr": "Accepter tout"
},
"preferencesPopupRejectAllButtonText": {
"fr": "Tout rejeter"
},
"preferencesPopupSaveButtonText": {
"fr": "Enregistrer les préférences"
},
"accessSectionTitleText": {
"fr": "Portabilité des données"
},
"accessSectionParagraphText": {
"fr": "Vous avez le droit de pouvoir accéder à vos données à tout moment."
},
"rectificationSectionTitleText": {
"fr": "Rectification des données"
},
"rectificationSectionParagraphText": {
"fr": "Vous avez le droit de demander la mise à jour de vos données chaque fois que vous le jugez approprié."
},
"erasureSectionTitleText": {
"fr": "Droit à l'oubli"
},
"erasureSectionParagraphText": {
"fr": "Vous avez le droit de demander que toutes vos données soient effacées. Après cela, vous ne pourrez plus accéder à votre compte."
}
},
"categories": {
"strictlyNecessaryCookiesTitleText": {
"fr": "Cookies strictement nécessaires"
},
"functionalityCookiesTitleText": {
"fr": "Cookies fonctionnels"
},
"performanceCookiesTitleText": {
"fr": "Cookies de performances"
},
"targetingCookiesTitleText": {
"fr": "Ciblage des cookies"
},
"unclassifiedCookiesTitleText": {
"fr": "Cookies non classés"
},
"strictlyNecessaryCookiesDescriptionText": {
"fr": "Ces cookies sont essentiels pour vous permettre de vous déplacer sur le site Web et d'utiliser ses fonctionnalités, telles que l'accès aux zones sécurisées du site Web. Le site Web ne peut pas fonctionner correctement sans ces cookies."
},
"functionalityCookiesDescriptionText": {
"fr": "Ces cookies permettent au site de fournir des fonctionnalités et une personnalisation améliorées. Ils peuvent être définis par nous ou par des fournisseurs tiers dont nous avons ajouté les services à nos pages. Si vous n'autorisez pas ces cookies, certains ou tous ces services peuvent ne pas fonctionner correctement."
},
"performanceCookiesDescriptionText": {
"fr": "Ces cookies nous permettent de surveiller et d'améliorer les performances de notre site Web. Par exemple, ils nous permettent de compter les visites, d'identifier les sources de trafic et de voir quelles parties du site sont les plus populaires."
},
"targetingCookiesDescriptionText": {
"fr": "Ces cookies peuvent être installés via notre site par nos partenaires publicitaires. Ils peuvent être utilisés par ces sociétés pour établir un profil de vos intérêts et vous montrer des publicités pertinentes sur d'autres sites. Ils ne stockent pas directement d'informations personnelles, mais sont basés sur l'identification unique de votre navigateur et de votre appareil Internet. Si vous n'autorisez pas ces cookies, vous bénéficierez d'une publicité moins ciblée."
},
"unclassifiedCookiesDescriptionText": {
"fr": "Les cookies non classés sont des cookies que nous sommes en train de classer avec les fournisseurs de cookies individuels."
}
},
"auto": {
"declName": {
"fr": "Nom"
},
"declPath": {
"fr": "Chemin"
},
"declType": {
"fr": "Taper"
},
"declDomain": {
"fr": "Domaine"
},
"declPurpose": {
"fr": "But"
},
"declProvider": {
"fr": "Fournisseur"
},
"declRetention": {
"fr": "Rétention"
},
"declFirstParty": {
"fr": "First-party"
},
"declThirdParty": {
"fr": "Tierce personne"
},
"cookiesDetailsText": {
"fr": "Détails des cookies"
},
"preferencesPopupAlwaysAllowedText": {
"fr": "Toujours permis"
},
"submitButton": {
"fr": "Soumettre"
},
"submittingButton": {
"fr": "Soumission..."
},
"cancelButton": {
"fr": "Annuler"
},
"guestsSupportInfoText": {
"fr": "Veuillez vous connecter avec votre compte client pour continuer."
},
"guestsSupportEmailPlaceholder": {
"fr": "Adresse e-mail"
},
"guestsSupportEmailValidationError": {
"fr": "L'email n'est pas valide"
},
"guestsSupportEmailSuccessTitle": {
"fr": "Merci pour votre requête"
},
"guestsSupportEmailFailureTitle": {
"fr": "Un problème est survenu"
},
"guestsSupportEmailSuccessMessage": {
"fr": "Si vous êtes inscrit en tant que client de ce magasin, vous recevrez bientôt un e-mail avec des instructions sur la marche à suivre."
},
"guestsSupportEmailFailureMessage": {
"fr": "Votre demande n'a pas été soumise. Veuillez réessayer et si le problème persiste, contactez le propriétaire du magasin pour obtenir de l'aide."
},
"confirmationSuccessTitle": {
"fr": "Votre demande est vérifiée"
},
"confirmationFailureTitle": {
"fr": "Un problème est survenu"
},
"confirmationSuccessMessage": {
"fr": "Nous reviendrons rapidement vers vous quant à votre demande."
},
"confirmationFailureMessage": {
"fr": "Votre demande n'a pas été vérifiée. Veuillez réessayer et si le problème persiste, contactez le propriétaire du magasin pour obtenir de l'aide"
},
"consentSectionTitleText": {
"fr": "Consentement à la politique de cookies"
},
"consentSectionNoConsentText": {
"fr": "Vous n'avez pas consenti à la politique de cookies de ce site Web."
},
"consentSectionConsentedText": {
"fr": "Vous avez consenti à la politique de cookies de ce site Web sur"
},
"consentSectionChangeConsentActionText": {
"fr": "Révoquer le consentement"
},
"accessSectionGDPRRequestsActionText": {
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},
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},
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"fr": "Ordres"
},
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"fr": "Tout télécharger"
},
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},
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},
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"fr": "Demander une mise à jour"
},
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}
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""
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},
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"caOnly": false,
"euOnly": false
},
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"accessSectionDownloadReportAuto": false
},
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},
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"domain": ".babybrezza.fr",
"path": "\/",
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"retention": "1 year(s)",
"purpose": {
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}
},
{
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"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
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"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
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"retention": "1 year(s)",
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}
},
{
"name": "cart_sig",
"domain": "babybrezza.fr",
"path": "\/",
"provider": "Shopify",
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}
},
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"path": "\/",
"provider": "Shopify",
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},
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"domain": "babybrezza.fr",
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}
},
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"path": "\/",
"provider": "Shopify",
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}
},
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"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
"fr": "Utilisé pour gérer les paramètres de confidentialité des clients."
}
}
],
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"path": "\/",
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}
},
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"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
"purpose": {
"fr": "Suit les pages de destination."
}
},
{
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"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
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}
},
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"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Shopify",
"firstParty": true,
"retention": "Session",
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}
},
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"domain": ".babybrezza.fr",
"path": "\/",
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"firstParty": true,
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}
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}
},
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},
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"firstParty": true,
"retention": "1 year(s)",
"purpose": {
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}
},
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},
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},
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"domain": ".babybrezza.fr",
"path": "\/",
"provider": "Google",
"firstParty": true,
"retention": "1 year(s)",
"purpose": {
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}
}
],
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],
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}
},
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Raw
History|-2bd2cf58|BfTw.json
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"home_video_title": "Add a video here",
"home_video_description": "Add a video, a still image and custom text from your theme settings.",
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"asterick_text": "*Savings on your first order $75+. Not valid on spare parts, Formula Pro Advanced WiFi, Sterilizer Dryer Advanced, or 1 Step Sterilizer"
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"type": "subheadline",
"settings": {
"title": "Common Cleaning & Maintenance Questions for Baby Brezza Products",
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"67b12ff9-2bb5-4d28-beeb-f16d406fc9d5": {
"type": "question",
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"settings": {
"title": "How do I clean or descale the Baby Brezza One Step Sterilizer, Sterilizer Dryer or Sterilizer Dryer Advanced?",
"text": "<p>To remove mineral scale, we recommend using <a href=\"https:\/\/babybrezza.com\/products\/safe-effective-appliance-descaler-liquid-8oz\" target=\"_blank\" title=\"Open our Baby Brezza Descaler in a new window.\">Baby Brezza Descaler<\/a> to remove mineral scale from your sterilizer and extend its useful life. <\/p><p>To clean, you can hand wash the lid and accessory tree in hot soapy water. Do not place in the dishwasher. You can use a damp cloth to clean the base and control console.<\/p><p>To avoid mineral scale build up, wipe the heating plate with a soft moist cloth after each operation.<\/p>"
}
},
"003a2bea-2cff-4f88-9e93-24c619f62c13": {
"type": "question",
"settings": {
"title": "How do I clean or descale the Baby Brezza Formula Pro Advanced?",
"text": "<p>1. We recommend using <a href=\"https:\/\/babybrezza.com\/products\/safe-effective-appliance-descaler-liquid-8oz\" target=\"_blank\" title=\"Open our Baby Brezza Descaler in a new window.\">Baby Brezza Descaler<\/a> to remove mineral scale from your Formula Pro Advanced and extend the appliance’s useful life. To clean or descale, hand-wash all components with lukewarm water and mild soap.<\/p><p>2. Make sure all parts are dry and reassemble machine, leaving powder container completely empty.<\/p><p>3. Fill the water tank with 20oz Baby Brezza Distilled Water and run a 10oz cycle.<\/p><p>4. Add Baby Brezza Descaler Liquid, or a cup of distilled white vinegar inside the water tank with 12oz of water and run another 10oz cycle.<\/p><p>5. Discard remaining descaler liquid or vinegar\/water solution, and wash tank with mild soap and water, and refill with 20oz distilled water.<\/p><p>6. Run another 10oz cycle to rinse out internal tubes of any vinegar residue.<\/p><p>7. Repeat steps 4-6 if concerns persists.<\/p>"
}
},
"54c3c61c-4088-4af4-b85b-ab6c414f44fb": {
"type": "question",
"settings": {
"title": "How do I clean or descale the heating plate or steam tank Steam for my Baby Brezza Sterilizer or Food Maker (any model)?",
"text": "<p>We recommend using <a href=\"https:\/\/babybrezza.com\/products\/safe-effective-appliance-descaler-liquid-8oz\" target=\"_blank\" title=\"Open our Baby Brezza Descaler in a new window.\">Baby Brezza Descaler<\/a> to remove mineral scale from any of your Baby Brezza appliances which also extends your appliance's useful life. Mineral scale occurs when minerals in the water you're using are left behind after the water evaporates. These minerals discolor your heating plate and can affect its performance over time. Monthly descaling helps to prevent this. You can also use Distilled Water which is free of minerals. Try <a href=\"https:\/\/babybrezza.com\/products\/baby-brezza-distilled-water-1-gallon-3pk\" target=\"_blank\" title=\"https:\/\/babybrezza.com\/products\/baby-brezza-distilled-water-1-gallon-3pk\">Baby Brezza Distilled Water<\/a>. <\/p>"
}
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"title": "BABY BREZZA PRODUCTS",
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"1588191729227": {
"type": "subheadline",
"settings": {
"title": "Baby Brezza Formula Pro\/Formula Pro Advanced\/Formula Pro Advanced WiFi",
"align_text": "left"
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},
"834829eb-80f8-4d01-b31f-8d1e78e085d3": {
"type": "question",
"settings": {
"title": "What do I do if my Formula Pro has an E4 error code?",
"text": "<p>The E4 error code means your machine’s water temperature sensor is malfunctioning. You can try to resolve this by pressing the button on the far right of the Control Panel for 10 seconds to reset the sensor. Then make another bottle and see what happens. If the E4 error code doesn’t return, then the issue is resolved. If the E4 error code does return, unfortunately, then your Formula Pro has a more serious issue that will need to be addressed by our Customer Care Team. Please have your proof of purchase available when we contact you to expedite the resolution of your issue. You can contact our Customer Care team at <a href=\"https:\/\/babybrezza.com\/fpa\" target=\"_blank\" title=\"https:\/\/babybrezza.com\/fpa\">www.babybrezza.com\/fpa<\/a> or calling 888-396-6552 (M-F, 9am-5pm ET).<\/p>"
}
},
"faq-4": {
"type": "question",
"settings": {
"title": "How do I find the formula setting for my Formula Pro?",
"text": "<p>Use the formula settings finder which will help you find the setting for the formula you’re using. <a href=\"https:\/\/babybrezza.com\/pages\/formula-pro-global-settings-finder\" title=\"Open our Baby Brezza Global Settings Finder\"><span style=\"text-decoration:underline\"><strong>Click Here<\/strong><\/span><\/a> for Formula Pro Settings Finder. We have two Formula Pro models so please choose the one that you’re using. If you have any problems, you can contact <a href=\"https:\/\/babybrezza.com\/pages\/contact\" title=\"Open our Baby Brezza Customer Service.\"><span style=\"text-decoration:underline\"><strong>Baby Brezza Customer Service<\/strong><\/span><\/a> for assistance.<\/p>"
}
},
"d22e23c7-0cd0-4b4e-a780-9fb80113a85f": {
"type": "question",
"settings": {
"title": "How do you use Baby Brezza Formula Pro Advanced?",
"text": "<p>Visit the Baby Brezza Formula Pro Advanced Information Center to find out how to use this formula maker. It’s very easy to automatically make a warm formula bottle with this formula maker that most parents call a “game-changer”. Just pick your settings, press start and in seconds, the Formula Pro will dispense a perfectly mixed bottle. The Information Center includes videos that explain how to use the Formula Pro, how to set it up, and answers to commonly asked questions. <\/p>"
}
},
"f1330fb3-df12-4cdb-988a-4a7480141f0c": {
"type": "question",
"settings": {
"title": "What formula works with the Baby Brezza Formula Pro Advanced?",
"text": "<p>The Baby Brezza Formula Pro Advanced works with virtually all brands of formula including hypo-allergenic types such as Similac Alimentum. You can check the compatibility of your brand and type of formula at <a href=\"http:\/\/www.babybrezza.com\/fpa\">www.babybrezza.com\/fpa<\/a>.<\/p>"
}
},
"1588192528529": {
"type": "question",
"settings": {
"title": "How do I set up my Formula Pro powder container?",
"text": "<p>For a quick reference set up guide, <a href=\"https:\/\/babybrezza.com\/pages\/user-manuals-united-states\" title=\"Open our User Manuals.\">click here<\/a> for the user manual or <a href=\"https:\/\/babybrezza.com\/pages\/how-to-videos-demos\" title=\"Open our Video Demos.\">click here<\/a> for the setup video. We recommend following the complete instructions in the user manual.<\/p>"
}
},
"1588192532136": {
"type": "question",
"settings": {
"title": "How do I know which Measuring Insert or Measuring Wheel Setting to use?",
"text": "<p>For a complete list of US Formula Powders and their correct Measuring Inserts or Measuring Wheel Settings, <a href=\"\/pages\/user-manuals-united-states\">click here<\/a>. If your powder is not listed, please contact customer service at <a href=\"mailto:customerservice@babybrezza.com\" title=\"Send an e-mail to customerservice@babybrezza.com\">customerservice@babybrezza.com<\/a><\/p>"
}
},
"7efb0673-89e7-4fef-a268-1a8cda93f98b": {
"type": "question",
"settings": {
"title": "Does the Formula Pro dispense the correct amount of formula​? How can I test if the amount of formula dispensed is accurate? ​",
"text": "<p>The right amount of formula is critical for the health of the baby. The Formula Pro Advanced comes with settings for specific formula brands and types to accurately dispense the exact amount of formula. <a href=\"https:\/\/babybrezza.com\/pages\/fpa-information-center-formula-settings-accuracy\" target=\"_blank\" title=\"See the settings and how you can test for  yourself at home to see the results. \">See the settings and how you can test for  yourself at home to see the results. <\/a><\/p>"
}
},
"1588192534484": {
"type": "question",
"settings": {
"title": "My Baby Brezza Formula Pro is dispensing more formula than indicated on the ounce selector on the control panel. Why?",
"text": "<p>The ounce size on the Formula Pro control panel indicates water volume only. When powder is added to the water, the volume is increased, just like when you make a bottle by hand. The final volume of mixed formula is expected to be a little over the ounce amount indicated on the control panel. If the amount of formula is significantly higher than the ounces you are expecting, please contact us.<\/p>"
}
},
"1588192555295": {
"type": "question",
"settings": {
"title": "My Baby Brezza Formula Pro is dispensing less formula than indicated on the control panel. Why?",
"text": "<p>Clean the Funnel to make sure formula powder isn’t clogging the machine. Contact customer service if the problem persists.<\/p>"
}
},
"1588192557760": {
"type": "question",
"settings": {
"title": "How do I prevent mold from growing in the Baby Brezza Formula Pro?",
"text": "<p>As with any food preparation product or food storage container, proper maintenance and cleaning is required to make sure that your Baby Brezza Formula Pro stays clean. In addition to the regular cleaning recommended in the instruction manual, we recommend that care be taken when pouring formula powder into the powder container. After pouring powder into the container, check to make sure that no powder has spilled in the area next to the water tank, and clean any excess powder with a damp cloth. Also make sure that all parts of the powder container are completely dry before assembly. Mold should not grow in Formula Pro when properly cleaned and dried.<\/p>"
}
},
"1588192567917": {
"type": "question",
"settings": {
"title": "Monthly cleaning and preparation for long term storage - Baby Brezza Formula Pro Advanced",
"text": "<p><strong>Monthly Descaling Instructions<\/strong><\/p><p>You can leave the formula powder in the powder tank during the descaling process.<\/p><p><strong>To prevent mineral scale on the water heater inside your Baby Brezza Formula Pro® Advanced, follow these easy steps:<\/strong><\/p><p>1. Remove the water tank, empty it and fill it with 20oz\/600ml distilled vinegar & 20oz\/600ml of purified water.<\/p><p>2. Place the water tank on the base of the machine & place a cup larger than 10oz\/300ml under the funnel.<\/p><p>3. Select “10oz\/300ml” with the “oz\/ml” button, then press the “water only” button to dispense.<\/p><p>4. Empty the cup, place back under the funnel, then press the <strong>“water only”<\/strong> button again to dispense another 10oz\/300ml.<\/p><p>5. Now unplug the machine, remove the water tank, and empty it. <strong>Let the machine sit for 4 hours.<\/strong><\/p><p>6. Wash, rinse and fill the water tank to the max line with purified water, then place it back on the base.<\/p><p>7. Plug in the machine, place a cup to catch 10oz\/300ml water and use the “water only” button to run a 10oz\/300ml cycle. Dispose of the water dispensed in the cup and then repeat this step to run the entire tank of purified water through the machine. When the “Low Water” indicator turns on, you’re done rinsing.<\/p><p>8. Refill the water tank with purified water and return to normal use<\/p><p> <\/p><p><strong>Long Term Storage Instructions<\/strong><\/p><p><strong>It is extremely important to clean the machine and remove all formula powder residue before storage.<\/strong><\/p><p>If you’re going to store your Formula Pro® Advanced for later use, or will not use it for a while, please follow the instructions below:<\/p><p>1. Remove the powder container parts, funnel, funnel cover, drip tray and water tank from the base.<\/p><p>2. Wipe the base with a clean damp cloth and make sure to remove any and all formula residue. Dry the base well.<\/p><p>3. Empty the powder container, wash all powder container parts, dry thoroughly, reassemble, & reinstall on the base.<\/p><p>4. Follow the Monthly Descaling Instructions shown above, steps <strong>1-7 only.<\/strong> Do not remove or refill the water tank after step 7.<\/p><p>5. Now place a cup to catch 10oz\/300ml water under the funnel, then <strong>press & hold<\/strong> the “water only” button for 5 seconds. Water will dispense continuously until the machine is completely empty, then stop automatically.<\/p><p>6. Unplug the machine, remove the funnel, funnel cover and water tank, dry them both thoroughly and reinstall them on the machine.<\/p><p>7. Your machine is now ready for storage. Pack the machine in its box or enclose it in a bag to keep it dust free.<\/p>"
}
},
"1588192569819": {
"type": "question",
"settings": {
"title": "Monthly cleaning and preparation for long term storage - Formula Pro Original",
"text": "<p>1. Remove powder container from the Formula Pro base and set aside.<\/p><p>2. Make sure the funnel is properly connected to the base of the Formula Pro.<\/p><p>3. Place a container 20oz or larger under the funnel to catch water<\/p><p>4. Fill the formula pro water tank with 10oz of water and 10oz of vinegar<\/p><p>5. Plug in and turn on the Formula Pro.<\/p><p>6. Press and hold “ounce”, “stop” and “start” buttons simultaneously.<\/p><p>7. Continue to hold all 3 buttons until the entire solution of water and vinegar are flushed through the machine.<\/p><p>8. Rinse the water tank and refill with 20oz of purified water and hold “ounce”, “stop” and “start” buttons to rinse any remaining vinegar from the machine”.<\/p><p>9. Unplug the machine, remove the funnel, funnel cover and water tank, dry them thoroughly and reinstall them to the machine.<\/p><p>10. Your machine is now ready for storage. Pack the machine in its box, or enclose it in a bag and keep it dust free.<\/p>"
}
},
"1588192572766": {
"type": "question",
"settings": {
"title": "There is mineral build up in my Baby Brezza Formula Pro. How do I clean?",
"text": "<p>1. Please hand-wash all components with lukewarm water and mild soap.<\/p><p>2. Make sure all parts are dry and reassemble machine, leaving powder container completely empty.<\/p><p>3. Fill the water tank with 20oz distilled water and run a 10oz cycle.<\/p><p>4. Add a cup of distilled white vinegar inside the water tank with 12oz of water and run another 10oz cycle.<\/p><p>5. Discard remaining vinegar\/water solution, and wash tank with mild soap and water, and refill with 20oz distilled water.<\/p><p>6. Run another 10oz cycle to rinse out internal tubes of any vinegar residue.<\/p><p>7. Repeat steps 4-6 if concerns persists.<\/p>"
}
},
"1588192579833": {
"type": "question",
"settings": {
"title": "Do I need to clean the Baby Brezza Formula Pro\/Formula Pro Advanced after every 4th bottle?",
"text": "<p>Yes it’s very important to clean the machine after every 4th bottle or when the clean funnel indicator light turns on. Unfortunately, formula can build up on the funnel during mixing because formula by nature likes to clump with water. If the formula builds up too much, it can affect how much formula drops from the powder container into the mixing funnel, affecting the machine’s accuracy. By removing the funnel after every 4th bottle and wiping the underside of the formula container, you can clean any formula build-up and ensure the machine works accurately. One suggestion to make cleaning easier is to purchase a spare funnel. That way, after every 4th bottle, you can remove the funnel that needs to be cleaned and insert your spare funnel that’s clean. <a href=\"https:\/\/babybrezza.com\/collections\/spare-parts\/products\/formula-pro-advanced-funnel-and-funnel-cover\" title=\"Open our Formula Pro Advanced Funnel and Funnel cover page.\"><span style=\"text-decoration:underline\"><strong>Click here<\/strong><\/span><\/a> to shop for a spare funnel for the Baby Brezza Formula Pro Advanced and <a href=\"https:\/\/babybrezza.com\/collections\/spare-parts\/products\/formula-pro-funnel-and-funnel-cover\" title=\"Open our Formula Pro Advanced Funnel and Funnel cover page.\"><span style=\"text-decoration:underline\"><strong>Click Here<\/strong><\/span><\/a> to shop for a spare funnel for the Formula Pro.<\/p>"
}
},
"6514046b-fa73-49a4-8a0a-4280146f664d": {
"type": "question",
"settings": {
"title": "What type of router does the Formula Pro Advanced WiFi work with?",
"text": "<p>The Formula Pro Advanced WiFi works only with 2.4ghz routers. It is not compatible with 5ghz routers unfortunately.<\/p>"
}
},
"8502d657-6b4a-4e56-8790-e878e8fe4a3c": {
"type": "question",
"settings": {
"title": "Do you need to sterilize the Baby Brezza formula dispenser?",
"text": "<p>You do not need to sterilize the formula dispenser that comes with the Baby Brezza Formula Pro Advanced. We recommend hand washing it and making sure it completely dries before filling it with formula powder. <\/p>"
}
},
"b0f07eca-1061-4788-89c0-998825fc7c73": {
"type": "question",
"settings": {
"title": "Does the Baby Brezza Formula Pro sterilize the water?",
"text": "<p>No, the Baby Brezza Formula Pro doesn’t sterilize water. However, we recommend using distilled water which is 100% free of any bacteria, viruses, mold, minerals and other toxins. <\/p>"
}
},
"44f0dd27-545c-4f64-a83f-0fb8ca92c6de": {
"type": "question",
"settings": {
"title": "Can you use Baby Brezza Formula Pro for breast milk?",
"text": "<p>The Baby Brezza Formula Pro can’t be used for breast milk, only to make formula bottles. If you’d like to safely warm up breastmilk, we recommend the Baby Brezza Safe + Smart Bottle Warmer, which is the only bottle warmer with 2 unique warming settings – a Warm Water Bath to safely warm breastmilk that protects its vital nutrients (unlike traditional warmers that use steam heat which destroys these proteins) and Steam Heat to rapidly warm formula. Learn more at: <a href=\"https:\/\/babybrezza.com\/products\/safe-smart-bottle-warmer\">https:\/\/babybrezza.com\/products\/safe-smart-bottle-warmer<\/a><\/p>"
}
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"type": "subheadline",
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"title": "Baby Brezza One Step Baby Food Makers",
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"1588192582072": {
"type": "question",
"settings": {
"title": "Are the Baby Brezza One Step Baby Food Makers BPA and Phthalate Free?",
"text": "<p>Yes, the Baby Brezza One Step Baby Food Makers are BPA and Phthalate Free.<\/p>"
}
},
"1588192593182": {
"type": "question",
"settings": {
"title": "Are the Baby Brezza One Step Baby Food Makers dishwasher safe?",
"text": "<p>The bowl and blade are top rack dishwasher safe. The drive shaft should always be removed before washing.<\/p>"
}
},
"1588192908206": {
"type": "question",
"settings": {
"title": "How do I clean the Steam Tank for my Baby Brezza One Step Baby Food Makers?",
"text": "<p>We recommend regular cleaning of the Steam Tank to prevent damage to the machine from mineral deposits. The frequency of cleaning will depend on the type of water you are using and how much mineral deposit build up forms. Always unplug before cleaning. Put 1\/3 cup white vinegar and 1\/3 cup distilled water in machine and let sit overnight. Pour out vinegar and water solution (refer to user manual for proper emptying instructions). Refill Steam Tank with purified water, plug in machine and run “Steam” cycle for 10 minutes. Let Steam Tank cool and scrub with a cleaning brush if necessary. Rinse with purified water to eliminate any remaining vinegar taste. Empty tank and fill with clean water before cooking<\/p>"
}
},
"38772156-9cc9-4462-be10-cad9b6472474": {
"type": "question",
"settings": {
"title": "Why Is My Baby Brezza food maker beeping when I press start?",
"text": "<p>Your Baby Brezza Food Maker is beeping because there isn’t enough water in the water tank to steam the food. It’s very easy to resolve by filling up the water tank. <\/p>"
}
},
"1588192934635": {
"type": "question",
"settings": {
"title": "What are the capacities of the Baby Brezza One Step Baby Food Makers?",
"text": "<p>The bowl of The Baby Brezza One Step Baby Food Maker Deluxe holds 3 ½ cups, and the Glass Food Maker holds 4 cups.<\/p>"
}
},
"1588192971634": {
"type": "question",
"settings": {
"title": "Do I need to peel fruits and vegetables before using in the Baby Brezza One Step Baby Food Makers?",
"text": "<p>We recommend peeling fruits and vegetables for young babies. We recommend checking with your pediatrician before offering any new foods, including fruit and vegetable peels and skins, to your child.<\/p>"
}
},
"1b88cd39-3bd1-4e4a-8f10-8506ae399ffc": {
"type": "question",
"settings": {
"title": "Are baby food makers worth it?",
"text": "<p>Yes using a baby food maker is worth it because it greatly simplifies the process of cooking homemade baby food. With a Food Maker like the Baby Brezza, you just push a button and the machine automatically steams & blends homemade baby food in minutes. Just put vegetables, fruits, meat or fish in the cooking bowl, press a button and the machine will make a delicious and healthy puree or mash for your little one. Plus, making your own homemade baby food will save you up to $500 versus buying the equivalent amount of store-bought baby food. <\/p>"
}
},
"2b7c2817-3a4f-42f7-9288-98e67fabc91c": {
"type": "question",
"settings": {
"title": "Which baby food maker is best?",
"text": "<p>The Baby Brezza Baby Food Makers are the best food makers because they are the easiest way to make homemade baby food. They are the only food makers that automatically steam & blend homemade baby food in 1 easy step. Other baby food makers require multiple steps and transferring food between the cook and blend phase. With the Baby Brezza Food Makers, you put your food in the bowl, press a button to select your setting, and then let the machine do the rest. In as little as 10 minutes, you’ll have a delicious and healthy baby food puree or mash for your little one! <\/p>"
}
},
"6589fc7f-3787-42a4-9178-8717aabec7f8": {
"type": "question",
"settings": {
"title": "What is the Baby Brezza food maker?",
"text": "<p>The Baby Brezza Food Maker is the only food maker that automatically steams & blends homemade baby food in 1 easy step. It takes all of the effort out of making homemade baby food. Just put vegetables, fruits, meat or fish in the cooking bowl, press a button and the machine will automatically make a delicious and healthy puree or mash for your little one. It's that easy! It comes in two styles: Deluxe (which includes a 3.5 cup plastic bowl with 3 reusable food pouches) and Glass (which includes a 4 cup glass bowl).<\/p>"
}
},
"1588192984993": {
"type": "subheadline",
"settings": {
"title": "Baby Brezza One Step Sterilizer and One Step Sterilizer-Dryers",
"align_text": "left"
}
},
"744e1030-53e4-4496-8d92-b2c50aeb57d6": {
"type": "question",
"settings": {
"title": "What does a red screen mean on my Sterilizer?",
"text": "<p>The red screen means that there isn’t enough water on your Sterilizer's heater plate for the appliance to run properly. This can occur if you didn’t add enough water to begin the sterilization process or the appliance used up all of the water before the 8 minute sterilization cycle finished. To address, please let the Sterilizer Dryer fully cool, then add 4 ounces of water to the heater plate. Then try the appliance again. <\/p><p>If the Sterilizer Dryer begins working, then the issue is resolved. If it doesn’t, then your Sterilizer Dryer has a more serious issue that will need to be addressed by our Customer Care Team. You can contact our Customer Care team by <a href=\"https:\/\/babybrezza.com\/pages\/contact\" title=\"https:\/\/babybrezza.com\/pages\/contact\">clicking here.<\/a><\/p>"
}
},
"1588193010898": {
"type": "question",
"settings": {
"title": "Does the Baby Brezza Sterilizer-Dryer also wash bottles and accessories?",
"text": "<p>The Baby Brezza Sterilizer-Dryer sterilizes and dries baby products, but it does not wash them. <\/p>"
}
},
"1588193031524": {
"type": "question",
"settings": {
"title": "Should I rinse\/clean products before sterilizing?",
"text": "<p>Yes, you should always rinse and clean all products before sterilizing to ensure they are properly sterilized.<\/p>"
}
},
"1588193044440": {
"type": "question",
"settings": {
"title": "What happens if I put unwashed bottles with milk residue in the Sterilizer-Dryer?",
"text": "<p>If you put unwashed bottles with milk residue in the sterilizer, these bottles will not be washed and properly sterilized. Also the milk inside the bottle will drip out and burn the heating plate, resulting in brown staining that is very difficult to clean.  <\/p>"
}
},
"1588193067545": {
"type": "question",
"settings": {
"title": "What temperature does the water reach during sterilization?",
"text": "<p>The Baby Brezza sterilizer boils water to produce steam (212°F \/ 100°C) to naturally sterilize your baby products. <\/p>"
}
},
"1588193082710": {
"type": "question",
"settings": {
"title": "What type of water is recommended for use?",
"text": "<p>We recommend using distilled water to avoid any mineral scale build-up. You can use tap water or spring water, but more frequent cleaning of the heating plate will be required. <\/p>"
}
},
"1588193103860": {
"type": "question",
"settings": {
"title": "How often does the water need to be changed?",
"text": "<p>Because the Baby Brezza Sterilizer-Dryer dries contents with each cycle, you will need to add ½ cups or 120ml of water before each use. <\/p>"
}
},
"1588193128129": {
"type": "question",
"settings": {
"title": "How do I clean the Baby Brezza Sterilizer and what components are dishwasher-safe?",
"text": "<p>Please do not dishwash any of the sterilizer components. Please clean the lid and accessory tree in hot soapy water. You can use a damp cloth to clean the base and control console. To avoid mineral scale build up, wipe the heating plate with a soft moist cloth after each operation. <\/p>"
}
},
"1588193162904": {
"type": "question",
"settings": {
"title": "How many volts is the Baby Brezza Sterilizer-Dryer? Can this appliance be used outside the US?",
"text": "<p>The Baby Brezza Sterilizer-Dryer is 120 volts and comes with a standard North American electric plug. Using the Baby Brezza Sterilizer Dryer with voltage any higher than 120V will permanently damage the unit. We do not recommend using the North American version outside of the US and Canada. Baby Brezza sells appliances globally through a network of distributors. To find a distributor in your country, please contact <a href=\"https:\/\/babybrezza.com\/pages\/contact\" title=\"https:\/\/babybrezza.com\/pages\/contact\">Baby Brezza Customer Service<\/a>.<\/p>"
}
},
"1588193178157": {
"type": "question",
"disabled": true,
"settings": {
"title": "How long is the warranty period and what does it cover?",
"text": "<p>The Baby Brezza Sterilizer-Dryer comes with a 1 year limited warranty. Please click here to read the details in the <a href=\"https:\/\/cdn.shopify.com\/s\/files\/1\/1465\/2384\/files\/STERILIZER-DRYER-INSTRUCTIONS.pdf?1544638409974322460\" title=\"https:\/\/cdn.shopify.com\/s\/files\/1\/1465\/2384\/files\/STERILIZER-DRYER-INSTRUCTIONS.pdf?1544638409974322460\">instruction manual<\/a>.<\/p>"
}
},
"1598539178517": {
"type": "question",
"settings": {
"title": "How hot is the air that dries the bottles?",
"text": "<p>Approximately 130°F\/55°C<\/p>"
}
},
"1588193199231": {
"type": "subheadline",
"settings": {
"title": "Baby Brezza Safe + Smart Bottle Warmer",
"align_text": "left"
}
},
"1588193214993": {
"type": "question",
"settings": {
"title": "Can I use the Baby Brezza Bottle Warmer without the orange insert?",
"text": "<p>The warmer should not be used without the orange holder.<\/p>"
}
},
"1588193233143": {
"type": "question",
"settings": {
"title": "How much water do I need to use?",
"text": "<p>It is important to fill the warmer with water to the correct level indicated on the warmer. For reference, please see instruction manual <a href=\"https:\/\/cdn.shopify.com\/s\/files\/1\/1465\/2384\/files\/Bottle-Warmer-Instructions.pdf?1544638409974322460\"><strong><span style=\"text-decoration:underline\">here<\/span><\/strong><\/a>.<\/p>"
}
},
"1588193251161": {
"type": "question",
"settings": {
"title": "Can I defrost my milk storage bags?",
"text": "<p>Yes, it is important to note that milk storage bags will defrost faster than a glass or plastic bottle. Please reach out to our Customer Service Team if you need assistance. <\/p>"
}
},
"1588193266950": {
"type": "question",
"settings": {
"title": "How do I defrost my bottle?",
"text": "<p>The instructions for using the &quot;steady warm&quot; function should be followed when defrosting, and lasts about 10-minutes. When the defrost setting is used, the result is usually room temp milk, depending on the volume being defrosted and the vessel it&#x27;s stored in. <\/p><p>Please reach out to our Customer Service Team who will be more than happy to assist if needed. <\/p>"
}
},
"1588191422979": {
"type": "subheadline",
"disabled": true,
"settings": {
"title": "Baby Brezza 2-Part Bottle",
"align_text": "left"
}
},
"faq-1": {
"type": "question",
"disabled": true,
"settings": {
"title": "Can I sterilize the bottle?",
"text": "<p>The Baby Brezza 2-part bottle is both top-rack dishwasher and electric steam sterilizer safe. The nipples are not microwave sterilizer safe. <\/p>"
}
},
"1588193280213": {
"type": "subheadline",
"disabled": true,
"settings": {
"title": "Bottle Washer",
"align_text": "left"
}
},
"1588193285776": {
"type": "question",
"disabled": true,
"settings": {
"title": "Does Baby Brezza sell a bottle washer?",
"text": "<p>Baby Brezza no longer sells a Bottle Washer. This item was discontinued several years ago… but check babybrezza.com for updates on new bottle cleaning products coming soon.  <\/p>"
}
},
"1588193321358": {
"type": "rich-text",
"settings": {
"title": "General Information",
"text": "",
"align_text": "left"
}
},
"1588193335729": {
"type": "subheadline",
"settings": {
"title": "General Questions",
"align_text": "left"
}
},
"70494a64-d2ad-432b-b507-f0c20bcc2cd4": {
"type": "question",
"settings": {
"title": "What are the exclusions for the Welcome15 and Mobile15 promotional codes?",
"text": "<p>The Welcome15 and Mobile15 promotional codes offer 15% off your first order $75+ but these discounts are not valid on the Formula Pro Advanced WiFi, Sterilizer Dryer Advanced, Descaler, Distilled Water and spare parts. <\/p>"
}
},
"1588193342035": {
"type": "question",
"disabled": true,
"settings": {
"title": "I am a retailer and would like to carry Baby Brezza in my store",
"text": "<p>Contact <a href=\"mailto:%20customerservice@babybrezza.com\">customerservice@babybrezza.com<\/a> and your inquiry will be forwarded to our sales department.<\/p>"
}
},
"1588193357371": {
"type": "question",
"settings": {
"title": "Do Baby Brezza products come with a warranty?",
"text": "<p>Yes, you can view our warranty <a href=\"https:\/\/babybrezza.com\/pages\/warranty\">here<\/a><\/p>"
}
},
"1588193373527": {
"type": "question",
"settings": {
"title": "Can you describe the types of spare parts that Baby Brezza sells?",
"text": "<p>Baby Brezza’s spare parts are 100% new and perform exactly like the same part that is included with your original purchase. However, if you are purchasing a spare part to help address a specific troubleshooting issue, there’s no assurance that this spare part will resolve the issue.<\/p>"
}
},
"1588193392360": {
"type": "subheadline",
"settings": {
"title": "Online Orders",
"align_text": "left"
}
},
"1588193399168": {
"type": "question",
"settings": {
"title": "How much will it cost to ship my order?",
"text": "<p>Shipping costs can be found <a href=\"https:\/\/babybrezza.com\/pages\/shipping-returns\">here<\/a>.<\/p>"
}
},
"1588193406089": {
"type": "question",
"settings": {
"title": "What is your return policy?",
"text": "<p>Please review our return policy <a href=\"\/pages\/shipping-returns\">here<\/a><\/p>"
}
},
"1588193408634": {
"type": "question",
"disabled": true,
"settings": {
"title": "Do you offer gift wrapping?",
"text": "<p>At this time, we do not offer gift wrapping<\/p>"
}
},
"1588193411456": {
"type": "question",
"disabled": true,
"settings": {
"title": "What is the Policy on Promotional Offers?",
"text": "<p>Promotional offers cannot be combined with any other offer, coupon or discount. No cash value. No cash back. Not applicable to prior purchases, shipping fees or taxes. <strong><em>*All promotions exclude spare parts, 1-Step Sterilizer, 1-Step Sterilizer\/Dryer Advanced  and Formula Pro Advanced WiFi<\/em><\/strong><\/p>"
}
},
"1588193413808": {
"type": "question",
"settings": {
"title": "Can I buy two products with two different discounts in the same order?",
"text": "<p>Unfortunately you can’t due a limitation with our ecommerce provider Shopify. If you’d like to purchase two products that have two different discount codes, please order each in a separate transaction. Sorry for this inconvenience but we’re unable to offer this feature.<\/p>"
}
},
"1588193422557": {
"type": "question",
"settings": {
"title": "Does Baby Brezza ship to international addresses?",
"text": "<p>Baby Brezza doesn&#x27;t ship to international addresses. The reasons may include: electrical, regulatory and other requirements which may be different in countries outside the US, therefore the products we sell in the US may not work well internationally.<\/p>"
}
},
"1588193424457": {
"type": "question",
"settings": {
"title": "Does Baby Brezza accept an international address for a billing address?",
"text": "<p>We are unable to ship products to US mailing addresses with international billing addresses because we have found in our experience that these products are being diverted to other countries, bypassing our rules against shipping internationally.<\/p>"
}
},
"1588193545787": {
"type": "subheadline",
"disabled": true,
"settings": {
"title": "Contact Us",
"align_text": "left"
}
},
"1588193552962": {
"type": "question",
"disabled": true,
"settings": {
"title": "By Phone",
"text": "<p>Our Customer Service team is available to assist you Monday through Friday, 9am to 10pm EST.  The phone number is 888-396-6552.<\/p>"
}
},
"1588193567967": {
"type": "question",
"disabled": true,
"settings": {
"title": "By Email",
"text": "<p>All emails will be answered as quickly as possible, 3 business days (though usually sooner) <a href=\"mailto:cs@babybrezza.com\" title=\"mailto:cs@babybrezza.com\">cs@babybrezza.com<\/a><\/p>"
}
},
"1588193582164": {
"type": "question",
"disabled": true,
"settings": {
"title": "By Mail",
"text": "<p>We recommend calling or emailing us before returning product back to us. Our mailing address is:  Baby Brezza Customer Service, 250 Passaic Street, Newark NJ 07104<\/p>"
}
},
"c3efc414-4d13-4d65-acdf-2e7dfaa5e23c": {
"type": "rich-text",
"settings": {
"title": "Sleep & Soothing",
"text": "",
"align_text": "left"
}
},
"c03f0619-16b3-4666-9561-bfd161e9167b": {
"type": "subheadline",
"settings": {
"title": "Smart Soothing Mat",
"align_text": "left"
}
},
"97482a80-0a92-4b04-b157-44c9aa6ccdbf": {
"type": "question",
"settings": {
"title": "When do I use the Smart Soothing Mat?",
"text": "<p>The Smart Soothing Mat can be used anytime, anywhere! The mat is easy to use during naps or bedtime, as well as mid-day meltdowns, and is especially good for colicky babies or those suffering from excessive gas.<\/p>"
}
},
"a3ea381f-f80a-4edc-90fc-24c0df69f158": {
"type": "question",
"settings": {
"title": "How do I turn the mat on\/off and activate the vibration and heartbeat modes?",
"text": "<p>It’s really easy. First, make sure working batteries are installed properly. You can turn the mat on and cycle through the 8 different settings either using the FREE app or using the buttons on the mat. To turn on using the buttons, just press and hold the on-off button on the mat for 3 seconds. To change settings, press the mode button.<br\/><br\/>To switch between settings, press the Mode button to cycle through the 8 different settings and find which one works best for your baby:<br\/>Extra Low Vibration (mat turns on and starts from Extra Low)<br\/>Low Vibration<br\/>Medium Vibration<br\/>High Vibration<br\/>Heartbeat Extra Slow<br\/>Heartbeat Slow<br\/>Heartbeat Fast<\/p>"
}
},
"422664ff-1874-4523-9342-50745426af4c": {
"type": "question",
"disabled": true,
"settings": {
"title": "Should I use the Smart Soothing Mat along with other soothing techniques?",
"text": "<p>While many parents find that the Smart Soothing Mat works well alone, others may find that their little ones need a combination of techniques, such as:<br\/><br\/>using in combination with a swaddle blanket or pacifier<br\/>using the Mat in a swing<br\/>while holding their baby or baby wearing<br\/>with additional white or pink noise<\/p>"
}
},
"3e3e4aa1-ef54-4249-b98c-1671b61217f4": {
"type": "question",
"settings": {
"title": "What are the most common ways and places to use the Smart Soothing Mat?",
"text": "<p>Smart Soothing Mat can be folded or rolled for easy transportation to wherever you and baby are going! Most parents use it in their baby’s crib or bassinet either under or over the sheet. But you can also use it in a pack and play, on an activity mat, on the floor, or even in your baby’s car seat (on top of the straps\/baby only) or stroller (on top of your baby’s legs). Be sure to follow all safety instructions for the Smart Soothing Mat and any other infant support device you may be using.<\/p>"
}
},
"e66ea264-df10-40a5-a908-bfcb38cc107d": {
"type": "question",
"settings": {
"title": "When should I start using the Smart Soothing Mat?",
"text": "<p>Unless your newborn is a preemie (less than 37 weeks), you can start using the Mat with your baby as soon as it is delivered! The product works best for younger babies 0-4 months or during the “4th trimester” as Dr. Harvey Karp calls it. Of course, as babies age, they learn more self-soothing techniques and cry more often for specific reasons (dirty diaper, hungry, teething, etc). Fortunately, the Smart Soothing Mat can still be helpful helping older babies learn to sleep alone in their cribs or while traveling away from home.<\/p>"
}
},
"c57ff352-0a36-4996-b548-a003ffc39201": {
"type": "question",
"settings": {
"title": "Are Smart Soothing Mats safe for babies?",
"text": "<p>All Smart Soothing Mats meet or exceed Children&#x27;s Product Certificate Standards per the CPSC as well as all other applicable USA and Canadian safety laws based on testing with a third party laboratory. All contact areas are phthalate-free, BPA-free, and lead-free. Common sense safety considerations are included in our labeling and use instructions.<br\/><br\/>The Smart Soothing Mat’s vibrations and white noise are also safe for baby.  There is currently no clinical data regarding vibrations being harmful to babies and similar vibrating products have been on the market and in use for 10 years or longer without any known ill effects. The Smart Soothing Mat features a range of vibration\/sound levels from 40 to 65 decibels. Babies are exposed to decibel levels up to 80-90 decibels in the womb and babies cries can be up to 130 decibel levels, which are higher than the maximum settings on the Smart Soothing Mat.<br\/><br\/>The Smart Soothing Mat doesn’t contain a heating element so there is no risk of overheating when the product is used properly and according to manufacturer’s guidelines.<\/p>"
}
},
"31ff47ab-a656-4f5e-9185-9d356f6a1e42": {
"type": "question",
"disabled": true,
"settings": {
"title": "How long does the Smart Soothing Mat take to work?",
"text": "<p>Every baby reacts differently. Many find it instantly soothing, calming in just seconds. Some babies, however, may need an adjustment period to get used to the mat. If your baby does not immediately respond or becomes more upset with the mat’s use, it could be they require a different setting (see above for how to change modes) or it could simply be because they’re in pain, hungry, or need a diaper change. In rare cases, we recommend that you try out the mat while holding your baby when he or she is content and happy. For these more sensitive babies, a gradual introduction can help them adjust to the Smart Soothing Mat. Over time, the child associates the product with the comfort of mom and dad’s embrace and is more responsive to the mat&#x27;s soothing when upset.<\/p>"
}
},
"831410cd-9a39-4141-8ebd-a9c24d60561d": {
"type": "question",
"settings": {
"title": "Can I leave my baby alone with Smart Soothing Mat on?",
"text": "<p>The Smart Soothing Mat was designed to be a safe and portable baby-soothing option, not an overnight white noise machine. In addition, the mat adds extra material to cribs so we wouldn’t advise leaving your baby alone with the mat for an extended period of time. If you wish to use the mat to help baby sleep we recommend opting for the 15, 30, 45 or 60-minute shut-off function. After reading all of the instructions and warnings and accepting full responsibility for how you choose to use the product, you are free to make any decision that works best for your child and family.<\/p>"
}
},
"db6b8c41-a148-46ba-84c8-67af49173594": {
"type": "question",
"settings": {
"title": "Does the Smart Soothing Mat have an age limit or weight limit?",
"text": "<p>There is no age or weight limit with the Smart Soothing Mat. In fact, many older children and adults have admitted that they also find the Smart Soothing Mat’s sounds and motions soothing, so don’t be surprised to find yourself curling up with your baby’s vibrating mat someday! The amount of weight on top of the mat may affect the strength of the vibrations or the battery life. With more weight on the mat, the motors have to work a bit harder and thus vibrations may be slightly dampened and battery life reduced.<\/p>"
}
},
"5211e56c-f92f-4a74-80fb-3a865f3712ca": {
"type": "question",
"settings": {
"title": "How long do the batteries last using the Smart Soothing Mat?",
"text": "<p>The way you use your Smart Soothing Mat will affect how long the batteries will last including the vibration level\/heartbeat setting you choose and whether you run continuously or use one of the timer settings. The app includes a battery life remaining indicator to help you gauge remaining battery life.<br\/><br\/>Based on our testing using standard AA batteries and typical use, you should expect at least 30-50 hours of battery life before the batteries start to lose power and the vibration or heartbeat levels diminish. NOTE: if the vibration level immediately stops after turning the mat on, then this is a sign that the batteries need to be immediately changed. We recommend using rechargeable AA batteries to use with your Smart Soothing Mat, especially if you are concerned about how long the batteries will last.<\/p>"
}
},
"e147acb0-d8b3-412b-8ca8-ccc0c956f4f5": {
"type": "question",
"settings": {
"title": "Is the Smart Soothing Mat washable?",
"text": "<p>The soft cotton\/spandex cover is removable and is machine washable. The water-resistant inner lining can be wiped down with a cloth. Do not submerge any part of the mat in liquids—this could damage the mat’s electronic components.<\/p>"
}
},
"bf1fe225-bab5-4385-9378-b70c7abb8edc": {
"type": "question",
"settings": {
"title": "What are Smart Soothing Mat’s vibration and heartbeat levels?",
"text": "<p>The Smart Soothing Mat comes with four different vibration levels—extra low, low, medium, and high—and four heartbeat settings – extra slow, slow, medium, fast – to help parents customize the vibrations and white noise to match their baby’s needs and mimic the sounds and motions of the womb that comforted your baby in utero. Some babies only need a little extra soothing so using Extra Low vibrations or heartbeats might work well. Other babies need more soothing power so using High might be best for them.<\/p>"
}
},
"9c4c92cf-8c6d-4213-b089-2aa3202b8723": {
"type": "question",
"settings": {
"title": "Is there an automatic shut-off function for the Smart Soothing Mat?",
"text": "<p>Yes! There are 4 timer settings with auto shut-off in the app (15, 30, 45 and 60 minutes). Of you can activate the 60 minute auto-shut-off using the buttons. To do this, first turn the mat on by pressing and holding the power button for three seconds, then after the vibrations turn on continue to hold the power button for an additional three seconds to activate the 60-minute auto off.<\/p>"
}
},
"90e1c170-dc09-4ff1-8ce6-2b5a271bb3ef": {
"type": "question",
"settings": {
"title": "Is the Smart Soothing Mat right for daycare centers?",
"text": "<p>Yes the Smart Soothing Mat is safe for in a daycare setting. First, the Smart Soothing Mat has been tested by a third party laboratory in the U.S. We have carefully sought out, tested, and selected only phthalate-free, BPA-free, and lead-free components including all components encased in the waterproof barrier. Common sense safety considerations are included in our labeling and use instructions.<br\/><br\/>Second, the Smart Soothing  Mat’s vibration and white noise levels are safe for babies. There is currently no clinical data regarding vibrations being harmful to babies and similar vibrating products have been on the market and in use for 10 years or longer without any known ill effects. The Smart Soothing Mat features a range of vibration\/sound levels from 40 to 63 decibels. Babies are exposed to decibel levels up to 80-90 decibels in the womb which is significantly higher than the maximum setting on the Smart Soothing Mat.<br\/><br\/>If your daycare facility follows the Hospital Standard for white noise machines (which is 50 decibels), you can use the Smart Soothing Mat on the Low and Medium vibration levels since these decibel levels are below 50. The Medium High and High vibration levels have decibel levels between 55-62, respectively, and the low and high heartbeat settings have decibel levels between average 55-60 and 60-63, respectively.<br\/><br\/>Lastly, the Smart Soothing Mat also doesn’t contain any heating element so there is no risk of a baby overheating when the product is used properly and according to manufacture guidelines.<\/p>"
}
},
"4d64d883-0ce6-4c8c-80b8-53db37f92be4": {
"type": "subheadline",
"settings": {
"title": "Baby Soothe Massager",
"align_text": "left"
}
},
"4396fed6-f889-42d9-9074-add801129dfb": {
"type": "question",
"settings": {
"title": "What is the Baby Soothe?",
"text": "<p>Baby Soothe is the first-ever baby massager that naturally calms your baby by mimicking mom’s gentle fingertip massage. It has 3 massagers that gentle rotate which activates your baby’s natural calming response. To learn more about how Baby Soothe works, click on: <a href=\"https:\/\/nam02.safelinks.protection.outlook.com\/?url=https%3A%2F%2Fwww.youtube.com%2Fwatch%3Fv%3DxFtFZuJod4Q&amp;data=04%7C01%7CDContract%40BeteshGroup.com%7C1924cb704c50461f862108d8d37b878e%7C2e90c06dde6c4e10833ed761f6e889d7%7C0%7C0%7C637491874799689521%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C1000&amp;sdata=Pyrvk5CpsJs2RSfEXVwA0n1kfJJqTBjLAPdePP1fq4k%3D&amp;reserved=0\" target=\"_blank\">https:\/\/www.youtube.com\/watch?v=xFtFZuJod4Q<\/a><\/p>"
}
},
"6e6df049-7adc-457b-841c-fa711bc7fcf2": {
"type": "question",
"settings": {
"title": "Is the Baby Soothe safe for my baby?",
"text": "<p>Yes, the Baby Soothe is safe to use on your baby. Massage has been used on babies for centuries and is a natural way to calm a baby. The Baby Soothe massager meets or exceeds all applicable USA and Canadian safety laws. All contact areas are phthalate-free, BPA-free, and lead-free. Common sense safety considerations are included in our labeling and use instructions.<\/p>"
}
},
"1731ceb6-f4d2-4348-8056-0f86957ad6b3": {
"type": "question",
"settings": {
"title": "How do I turn the Baby Soothe on and off?",
"text": "<p>It’s really easy to use Baby Soothe. To turn on, just press the large button. To turn off, just press the large button. The Baby Soothe comes with an automatic 10 minute shut-off.<\/p>"
}
},
"66d6a0cd-1197-459f-8c9c-657362979de8": {
"type": "question",
"settings": {
"title": "How long does the Baby Soothe work?",
"text": "<p>The Baby Soothe comes with an automatic 10 minute shut-off.<\/p>"
}
},
"3f0380ec-a4ca-4396-b03a-9ac70951ee11": {
"type": "question",
"settings": {
"title": "Do I have to use the belly band? How do I use the belly band?",
"text": "<p>You can use the Baby Soothe in two different ways. You can use the massager directly on your baby. Or you can wrap the belly band around your baby using the Velcro flaps and then place the Baby Soothe in the large pocket on the front. Either way, the Baby Soothe will work and naturally calm your baby.<\/p>"
}
},
"9747d91d-8421-4f0c-a2ed-ad5dbbfb9ee7": {
"type": "question",
"settings": {
"title": "Can I leave my baby alone with the Baby Soothe?",
"text": "<p>Baby Soothe was designed to be safely used on your baby either with or without adult supervision. Baby Brezza recommends using Baby Soothe with adult supervision.<\/p>"
}
},
"33c54789-056a-437c-9441-691288ccd3dc": {
"type": "question",
"settings": {
"title": "How long do the batteries last?",
"text": "<p>Based on our testing, the batteries should last at least approximately 50 hours of continuous use. Note the Baby Soothe comes with an automatic 10 minute shut-off so one set of batteries should last for months. If you’re concerned about battery life, we recommend using rechargeable batteries.<\/p>"
}
},
"a995b422-f16a-4d81-b632-cf0e93fdeda2": {
"type": "question",
"settings": {
"title": "How much does the Baby Soothe massager weigh?",
"text": "<p>The Baby Soothe massager with batteries and the belly band weigh 10 ounces.<\/p>"
}
},
"0e323c28-23c4-4fbb-b14e-9d6065d676b1": {
"type": "question",
"settings": {
"title": "How do I take care of the Baby Soothe?",
"text": "<p>It’s easy to care of the Baby Soothe massager and band. To clean the massager, wipe it with a soft, damp cloth. Do not immerse in liquid. NOTE: if water accidentally gets inside the massager, remove the batteries, allow the unit to dry completely, then wipe with a dry cloth before next use. To clean the band, you can either hand or machine wash using cold water. Air dry only. Do not dry clean, bleach or tumble dry the band.<\/p>"
}
},
"6be220a6-feb2-44e8-8dff-cf953c2465c7": {
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{
"article_title": "Silicone Elastomers with Intrinsic Control of Surface Hydrophilicity",
"year": "2013",
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"link": "http://biomaterials-org.securec7.ezhostingserver.com/abstracts/data/papers/2013/0243-000796.pdf",
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"abstract": "Addition-cure, platinum catalyzed silicone RTVs undergo a crosslinking reaction yielding silicone elastomers.1 Silicone elastomers have myriad uses in medical applications due to their biocompatiblity. The hydrophobic surface of silicone elastomers is a well documented disadvantage in many applications. Longterm surface modification of silicones to improve wettability and reduce protein adsorption is desirable. Oxidative surface treatment of silicone elastomers to improve surface wettability has been reported, however, the surface recovers hydrophobic character over time.2 As a result, oxidative surface treatments need to be continually reapplied to the silicone elastomer to retain hydrophilic surface performance. Addition of a hydrophilic additive such as polyethylene glycol (PEG) to silicone RTV formulations is another approach to modifying the surface of silicone elastomers. These unbound hydrophilic additives in silicone elastomers lead to loss of optical clarity, increased presence of undesirable extractables and degradation of mechanical properties. This paper reports the development of silicone elastomer comonomers containing surface active pendants with discrete discrete polyether or tetrahydrofurfuryl (THF) substitution and a central vinyl functionality that can react into RTV formulations. Copolymerization leads to optically clear silicone elastomers with good mechanical properties and no increase in extractables. The pendant hydrophilic groups orient on the surface of the bulk silicone elastomer, providing long-term improvement of surface wettability and reduced protein adsorption."
},
{
"article_title": "Quaternary functional silsesquioxanes for use in personal care: polysilsesquioxane steardimonium chloride",
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"abstract": "Quaternary amine functional silsesquioxane particles are a universal conditioning and anti-static additive for personal care and cosmetics formulations. This solid powder can be dispersed easily into water based formulations, dry powders or plastic packaging. The highly charged surface provides beneficial effects at low loading levels. The particles are non-toxic, non-leaching, non-irritating, biocompatible, environmentally friendly and thermally stable"
},
{
"article_title": "Cyclic azasilanes: Volatile coupling agents for nanotechnology",
"year": "2004",
"date": "1072933200",
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"article_title": "Migratory Internal Lubrication of Thermoplastic Resins",
"year": "1973",
"date": "94712400",
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"article_title": "Tailoring surfaces with silanes",
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"date": "220942800",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37375696/Arkles__B.__Tailoring_Surfaces_with_Silanes__Chemtech__7__766-778__1977-with-cover-page-v2.pdf?Expires=1634063497&Signature=CXTSM-b~rDJqAmzeLCWOHgbGJ-cUMaRglMl1CMuHGd7LAiHbc1Dwq8ujjD5YjiipDMuNLgbBZywiVX4Lx53IS3qCihZW~uXR4k9DAXzceOzEdH3VI-5N1ISqtJH5yWdzkx~vRN1QVHfeO9BC~6ROlDGe59H6SfuV9s1B1~V0PVPTpCWvwHLLr~Fz1-HQbFptdgSbl9UnsULaDre58BxwfzWV5LmGN~H-s3gQzy1HyRxSIX81INxGOr~PyLWCRud-6wmDJDmInaEaKdj5K-JF-kgZMfA7EZ62MhsdsfPX29gaorLPa9qBtvHHG4w2I9cZDN-O~koATz4A0XbWuit7ow__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
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"article_title": "Look what you can make out of silicones (Biomedical applications of silicones)",
"year": "1983",
"date": "410245200",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37376162/Look_what_you_can_make_out_of_silicones.pdf?1429627172=&response-content-disposition=inline%3B+filename%3DLook_what_you_can_make_out_of_silicones.pdf&Expires=1634059656&Signature=FzIPg3lHj89qRmnX-Gn83UcPhgd9vzSQKiH7kb7mNUpYM6UiU4e5BrvGZbcx9EC7xPrlX-CDdDN4QK5ygFonRuAL5GeqtGFiGGvnLYlDa1Xlwm0odBCFEEBsyPf-zV-~hXWQ468HIgO-BKIo5a50zkqUbKDytN3T22NkgpDXAlSZD9w~R3-OOWuilrIsynE3XKyPJP8if-3InF~21gsGiSdw~kpFBy4Z-He5mjMfQmPOPUQ0ipYc~AO~Arp9eh2bq9C-CuLAMKioAudV3v0pXVA3pwcrEwK-b89-MobvpoC7dbkSQevoWGBJex3oFHyBUtIN7nXxbzbSCqgttO69Wg__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
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"article_title": "Polysiloxane-thermoplastic interpenetrating polymer networks",
"year": "1990",
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"link": "https://d1wqtxts1xzle7.cloudfront.net/37383062/Polysiloxane-Thermoplastic_Interpenetrating_Polymer_Networks.pdf?1429665559=&response-content-disposition=inline%3B+filename%3DPolysiloxane_Thermoplastic_Interpenetrat.pdf&Expires=1634056569&Signature=Npn2MP~65Upuij7y9ADi1VwgqXZHuFncOYSH-WnTkUCPmdeGTBByuuEOjuUDgan5Q-ikRY69jfAeQiVTPlbS34jBI76yK6SXNdcvx35y~oKGcRglrSrrvFiPzje7~JZmxynBPMf55-~FjbbwAUen5At-9pJlgd-ygH5vLCdikRqcI5ZDYdtXm8EIFRmd~idQhVnymgswqnOAATBgpgg4MTccQp0VgACTDOBeD6eIHagKys4yYmC8N6ngkGBJciE84HBbag~DskTikLT7D-wmn8EGHTrf8CWmKnFe64WwYxGh7FEaJnJqtig8t3XldGPhz-CQIMKkqVPYTu2V9a4tXA__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
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"article_title": "Polymeric Silane Coupling Agents Enhance Strength of Composites",
"year": "1987",
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{
"article_title": "The effect of silanes on adhesion of size-free glass fibers in thermoplastic composites",
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"link": "https://d1wqtxts1xzle7.cloudfront.net/38801757/The_Effect_of_Silanes_on_Adhesion_of_Size_Free_Glass_Fibers_in_Thermoplastic_Composites.pdf?1442506325=&response-content-disposition=inline%3B+filename%3DThe_Effect_of_Silanes_on_Adhesion_of_Siz.pdf&Expires=1634062870&Signature=JvBWTXoXMVglm2fJtse49dgKRjKYhUo5FvVckKSQXRgRcxXjDyc0b0p08jnzTXrBSHo2tAcwqQK4dTJjr96dZIJJO7Bubu-2-CqRq~guoXIy4HVUepqqXrsoLcraGjgYIVvxfCuoErGmv-lPzMMfB~AiagjIZRIDsJu-J8nFr8rA5mTLzqKAUHsWujV9261wwh3Uu18fcoofCfjnciIZ21pySkze35MIqBz~CU0uSP0YQpKat4Jf8AqFzONsCYRrMz3yRPzEwT7mpIjZPlTBn59dR2aV30JSZk55xIXisGWRx9cH9AgKeuoVgI5X8u2GLcL-ulDT5P5F1Pu4FZvddw__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
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{
"article_title": "Ultra-High Elongation Silicone Elastomers",
"year": "2016",
"date": "1451624400",
"link": "https://d1wqtxts1xzle7.cloudfront.net/46582485/Ultra-high_Elongation_Silicone_Elastomers-with-cover-page-v2.pdf?Expires=1633988094&Signature=H795V8OdSlTmtlCJLmZZR7tISLfWgyEF3jQYyV31BaGBj0Rsz0PrkISZIL7zzpOZGKLS0bQEtXyLB9hMUdnz8nLjfcc0xnk501bb4tX~8vED~hK0esLq-NbW4CVKOLvMwp1WVWLbYOivcwKqSXhQYWqS1D1lK4FjlSsfr~ANDCEEY-Q3CXjx6zksfk~SXYWr7-LPmPxxQL1fYWj4tUkwAXdBgPRbu3sX3Oi8GQx4EdMvDjvtM4yE2zi9YWDWQGdD5OhDMEiEqit9gcexKcZ0dk7kuGcpVn7Kmj8tDuwar4cywLpXBq2LFCS5At9tEq81V2JZ5FQw0PjU4-gKQP7g0A__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
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"author_ids": [3, 1, 2, 16],
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"abstract": ""
},
{
"article_title": "Sivate enhanced aminofunctional silane",
"year": "2018",
"date": "1514782800",
"link": "https://d1wqtxts1xzle7.cloudfront.net/56420499/Sivate_enhanced_amino_functional_silane.pdf?1524703920=&response-content-disposition=inline%3B+filename%3DSivate_enhanced_amino_functional_silane.pdf&Expires=1633987817&Signature=cZFoAv9tH0aNVl-yQny9wCYtwanbBfmLytJ6lqVZgpazPx170X654B3vR~FO1Hwmlqki-nCSZhTqsUkGrCRSiJNBYFLMbiU7PH9NiFbbfDDPw3pFsgAghLrw4KrsBfZ4aDm-NfvOxdp8~CIyvRT2y-NKnlokGYts6kxsP9Hhguc5UyDqy6Ew-B6h7FGitZ4UZTmVNAQgfCcC9~Duim0LKmp1UIebouvd~F1QzdS8u98Phb5qHeEN~-VyyE0Rgxjj4e-IXdytwM~SLW1rEmKwh9aKAbTzcadi7I2gq2VxcHHQzZNF1sZDXzJ2yGjWvSgA~pB4cw7vyyogZ0x9rq2kcw__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "208",
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"journal_id": 12,
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"abstract": ""
},
{
"article_title": "Commercial Hybrid Organic‐Inorganic Polymers",
"year": "2000",
"date": "946702800",
"link": "https://doi.org/10.1002/9783527620777.ch100c",
"volume": "1",
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"abstract": ""
},
{
"article_title": "Thermally Induced Silane Dehydrocoupling on Silicon Nanostructures",
"year": "2016",
"date": "1451624400",
"link": "https://doi.org/10.1002/anie.201601010",
"volume": "55 ",
"pages": " 6533-6537",
"is_gelest": false,
"journal_id": 22,
"author_ids": [22, 28, 9, 29, 30, 31, 3, 27],
"category_ids": [1],
"abstract": "Organic trihydridosilanes can be grafted to hydrogen-terminated porous Si nanostructures with no catalyst. The reaction proceeds efficiently at 80 °C, and it shows little sensitivity to air or water impurities. The modified surfaces are stable to corrosive aqueous solutions and common organic solvents. Octadecylsilane H3Si(CH2)17CH3, and functional silanes H3Si(CH2)11Br, H3Si(CH2)9CH=CH2, and H3Si(CH2)2(CF2)5CF3 are readily grafted. When performed on a mesoporous Si wafer, the perfluoro reagent yields a superhydrophobic surface (contact angle 151°). The bromo-derivative is converted to azide, amine, or alkyne functional surfaces via standard transformations, and the utility of the method is demonstrated by loading of the antibiotic ciprofloxaxin (35 % by mass). When intrinsically photoluminescent porous Si films or nanoparticles are used, photoluminescence is retained in the grafted products, indicating that the chemistry does not introduce substantial nonradiative surface traps."
},
{
"article_title": "Surface Triggered Tandem Coupling Reactions of Cyclic Azasilanes",
"year": "2017",
"date": "1483246800",
"link": "https://doi.org/10.1002/asia.201700137",
"volume": "12 ",
"pages": " 1198-1203",
"is_gelest": false,
"journal_id": 18,
"author_ids": [9, 20, 10, 21, 1, 3],
"category_ids": [1],
"abstract": "Cyclic azasilanes have been synthesized for the purpose of developing coupling agents appropriate for a variety of nanotechnologies including surface modification of nanoparticles, nanocrystals, mesoporous materials and substrates. N-Methyl-aza-2,2,4-trimethylsilacyclopentane is representative of this class of compounds. Preliminary data for the treatment of inorganic surfaces, including nanoparticles and oxidized silicon wafers, with cyclic azasilanes suggest high-density monolayer deposition by a ring-opening reaction. Cyclic azasilanes contain a cryptic amine functionality that can perform a subsequent tandem coupling reaction with functional molecules after the surface-triggered ring-opening reaction, allowing for a one-pot self-assembly route on nanostructures. Tandem coupling reactions are demonstrated via addition reactions of the cryptic amine with epoxy and acrylate systems."
},
{
"article_title": "Enhanced Hydrolytic Stability of Siliceous Surfaces Modified with Pendant Dipodal Silanes",
"year": "2014",
"date": "1388552400",
"link": "https://doi.org/10.1002/chem.201402757",
"volume": "20 ",
"pages": " 9442-9450",
"is_gelest": true,
"journal_id": 34,
"author_ids": [3, 9, 33, 35],
"category_ids": [1],
"abstract": "Dipodal silanes possess two silicon atoms that can covalently bond to a surface. They offer a distinct advantage over conventional silanes commonly used for surface modification in terms of maintaining the integrity of surface coatings, adhesive primers, and composites in aqueous environments. New nonfunctional and functional dipodal silanes with structures containing “pendant” rather than “bridged” organofunctionality are introduced. The stability of surfaces in aqueous environments prepared from dipodal silanes with hydrophobic alkyl functionality is compared to the stability of similar surfaces prepared from the conventional silanes. In strongly acidic and brine environments, surfaces modified with dipodal silanes demonstrate markedly improved resistance to hydrolysis compared to surfaces prepared from conventional silanes. Pendant dipodal silanes exhibit greater stability than bridged dipodal silanes. The apparent equilibrium constant for the formation of silanol species by the hydrolysis of a disiloxane bond was determined as Kc=[SiOH]2/[Si-O-Si][H2O]=6±1×10−5 and is helpful in understanding the enhanced hydrolytic stability of surfaces modified with dipodal silanes."
},
{
"article_title": "Recycling Poly(Tetragluoroethylene)",
"year": "1973",
"date": "94712400",
"link": "https://doi.org/10.1007/978-1-4684-0871-3_8",
"volume": "1",
"pages": "121-137",
"is_gelest": true,
"journal_id": 142,
"author_ids": [3],
"category_ids": [1],
"abstract": "Poly(tetrafluoroethylene) (PTFE) is unique among polymers in its ecological position. Although there has been considerable discussion on recycling waste polymers such as poly(ethylene) (PE), poly(styrene) (PS), and poly(vinyl chloride) (PVC), only poly(tetrafluoroethylene) has been recycled in quantities significant compared to production. Over fifty times more PE is consumed in the form of trash bags for waste disposal than PTFE manufactured. Further, the growth rate of PE, PVC, and PS is continuing at 5–10%o per year while PTFE growth has plateaued. On a tonnage basis, then, the recycling of PTFE appears anomalous. The discrepancy disappears when the economic reward of reprocessing a $2.75/1b material is contrasted with that of a $0.14/1b material. The high scrap value of PTFE provides an incentive for both fabricators and end-users to accumulate waste in reasonably concentrated bulk. Further, freight cost to reprocessing installations is not a significant portion of the polymer cost. Due to the economic incentive a wide variety of methods for up-grading waste PTFE to reprocessable grades have been evaluated. The techniques employed may be transferable to other polymers of greater ecological impact."
},
{
"article_title": "Staged development of modified silicon dioxide films",
"year": "1997",
"date": "852094800",
"link": "https://doi.org/10.1007/BF02436883",
"volume": "8 ",
"pages": " 465-469",
"is_gelest": false,
"journal_id": 77,
"author_ids": [3, 62, 89, 68, 127, 128, 94],
"category_ids": [1],
"abstract": "The hydrolytic generation of SiO2 films from chlorosilanes or alkoxysilanes is interrupted by incorporating labile organic groups which stop SiO2 formation at a processable prepolymer stage. The monomers for the prepolymer have electron withdrawing substituents in the β-position. The organic groups are removed from the prepolymer at low temperature, extruding ethylene. The formation of SiO2 proceeds by intramolecular condensation of the electronegative substituents which are now in a hydrolytically unstable bond with silicon and hydroxyl groups or ambient moisture. Films of the prepolymer spun onto silicon wafers are converted into uniform SiO2-rich films at temperatures between 150–400°C."
},
{
"article_title": "Hydroxymethylsilanetriol – a simple analog of silicic acid",
"year": "2013",
"date": "1357016400",
"link": "https://doi.org/10.1007/s12633-013-9146-2",
"volume": "5 ",
"pages": " 187-197",
"is_gelest": false,
"journal_id": 37,
"author_ids": [3, 40, 41],
"category_ids": [1],
"abstract": "Hydroxymethyltriethoxysilane and hydroxymethyltrimethoxysilane, precursors by hydrolysis to a simple analog of silicic acid, hydroxymethylsilanetriol, were prepared. Hydroxymethyltrialkoxysilanes undergo condensation to form silmethyleneoxide oligomers and dimeric 2,2,5,5-tetraalkoxy-2,5-disila-1,4-dioxanes. Hydroxymethylsilanetriol undergoes condensation reactions similar to silicic acid and readily forms organosilicate structures by sol–gel processing techniques which may be converted at relatively low temperatures to silicon dioxide. Hydroxmethylsilanetriol derived gels were subject to less stress-cracking during drying than conventional tetraethoxysilane derived gels, suggesting that Si-O-C bond equilibration during drying provides a mechanism for stress-relief. In screening experiments, hydroxymethylsilanetriol appears to be a competitive inhibitor of the growth of the diatom C. fusiformis, a silicate dependent species, which produces silicate structures."
},
{
"article_title": "The molecular weight of PTFE wear debris",
"year": "1976",
"date": "189320400",
"link": "https://doi.org/10.1016/0043-1648(76)90235-0",
"volume": "39 ",
"pages": " 177-180",
"is_gelest": true,
"journal_id": 120,
"author_ids": [3, 169],
"category_ids": [1],
"abstract": "A preliminary investigation of the molecular weight of polytetrafluoroethylene (PTFE) wear debris was undertaken. It was found that the molecular weight of PTFE wear debris generated from thrust washers was drastically reduced compared with that of the thrust washer. A consistent difference in the molecular weight of the wear debris was observed in samples obtained at high and at low pressure velocities. A fluorocarbon composite material yielded wear debris of molecular weight even lower than that of unfilled PTFE wearing below its limiting pressure-velocity."
},
{
"article_title": "Functional properties of rat liver mitochondria immobilized on an alkylsilylated surface",
"year": "1979",
"date": "284014800",
"link": "https://doi.org/10.1016/0076-6879(79)56053-4",
"volume": "56",
"pages": " 550-557",
"is_gelest": false,
"journal_id": 116,
"author_ids": [158, 3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Concerning the relative non-toxicity of silacrown ionophores",
"year": "1985",
"date": "473403600",
"link": "https://doi.org/10.1016/0091-3057(84)90167-9",
"volume": "21 ",
"pages": " 77-80",
"is_gelest": true,
"journal_id": 98,
"author_ids": [152, 160, 153, 3],
"category_ids": [1],
"abstract": "Silacrowns, ionophoric materials in which an ethylene bridge of a normal crown ether has been replaced by a R2Si group, facilitate ion transport across liquid membranes. A major aspect of their properties is their nontoxicity when compared to these crown ethers. This is probably due to their ready hydrolysis to the corresponding polyethylene glycols. The glycols also exhibit ion transport properties, even with an efficiency close to the silacrowns but the silacrowns stay intact long enough to partition into the hydrophobic phase of a liquid membrane whereas their hydrolysis products preferentially partition into the aqueous phases. Ready removal from the hydrophobic phase of a membrane will reduce the long term transporting effectiveness of the glycols. Thus, in vivo hydrolysis of the silacrowns will result in the loss of transmembrane carriers. Similar removal will not occur for normal crown ionophores which are both hydrolytically stable and partition into the hydrophobic phase, and remain there for long time periods."
},
{
"article_title": "The Low-Temperature Remote-Plasma-Activated Pulsed Chemical Vapor Deposition Route to SiNx from 1,3,5-tri(isopropyl)cyclotrisilazane",
"year": "2020",
"date": "1577854800",
"link": "https://doi.org/10.1016/j.tsf.2020.138299",
"volume": "711",
"pages": " 138299",
"is_gelest": true,
"journal_id": 4,
"author_ids": [3, 7, 1, 8],
"category_ids": [1],
"abstract": "High-quality silicon nitride (SiNx) thin films were grown by remote-plasma-activated pulsed chemical vapor deposition (P-CVD) from the source precursor 1,3,5-tri(isopropyl)cyclotrisilazane (TICZ, C9H27N3Si3) and remote ammonia (NH3) plasma on silicon oxide (SiO2) substrates within an optimized substrate temperature window ranging from 200 to 350 °C. TICZ was selected because of its chemical stability, non-pyrophoric nature, good vapor pressure (~127 Pa at 70 °C), and its chemical structure that incorporates alkyl groups with three C atoms on each N atom, which provides a clean elimination mechanism for low temperature SiNx deposition. P-CVD consisted of a four-step process: TICZ pulse with no plasma, N2 purge, NH3 plasma pulse, and N2 purge. The as-deposited films were analyzed using spectroscopic ellipsometry and x-ray photoelectron spectroscopy (XPS). Wet etch rates were determined using a standard solution consisting of 0.5% hydrofluoric acid in deionized water. XPS analysis revealed a Si:N ratio of ~1:1 within the entire substrate temperature range and validated the formation of the SiNx phase. In situ, real-time ellipsometry measurements confirmed that SiNx growth exhibited a non-self-limiting P-CVD behavior. They also yielded an as-grown SiNx average refractive index of ~1.8 for the films grown at substrate temperatures above 200 °C."
},
{
"article_title": "Respiratory properties of rat liver mitochondria immobilized on an alkylsilylated glass surface",
"year": "1975",
"date": "157784400",
"link": "https://doi.org/10.1016/S0021-9258(19)40752-7",
"volume": "250 ",
"pages": " 8856-8862",
"is_gelest": true,
"journal_id": 127,
"author_ids": [3, 158],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Reaction of Trimethylsilyl Azide with Bridged Bicyclic Olefins",
"year": "1976",
"date": "189320400",
"link": "https://doi.org/10.1016/S0022-328X(00)85082-2",
"volume": "121 ",
"pages": " 285-291",
"is_gelest": false,
"journal_id": 125,
"author_ids": [163, 3, 173],
"category_ids": [1],
"abstract": "Bridged bicyclic olefins were found to undergo facile 1,3-cycloaddition reaction with trimethylsilyl azide. Norbornene produced cis,exo-1-trimethylsilyl-4,7-methano-3a,4,5,6,7,7a-hexahydrobenzotriazole, while norbornadiene formed a diadduct with cis,exo-stereochemistry, together with 2-trimethylsilyl-1,2,3-triazole produced by a retro-Diels—Alder reaction of an intermediate mono-adduct. Dicyclopentadiene reacted only at the norbornene position while α-pinene did not react with trimethylsilyl azide. In contrast to aryl- and sulfonyl-azide adducts of norbornene derivatives, which decompose upon heating the present adducts were recovered unchanged after prolonged treatment at 205°C."
},
{
"article_title": "Spin-on-glass thin films prepared from a novel polysilsesquioxane by thermal and ultraviolet-irradiation methods",
"year": "1999",
"date": "915166800",
"link": "https://doi.org/10.1016/S0040-6090(98)01740-4",
"volume": "345 ",
"pages": " 244-254",
"is_gelest": true,
"journal_id": 4,
"author_ids": [92, 93, 68, 94, 3, 89, 62],
"category_ids": [1],
"abstract": "New dielectric films are prepared by both pyrolytic and photolytic conversion of β-chloroethyl-silsesquioxane (BCESSQ). Film thickness, refractive index, composition, density and morphology are characterized using a palette of techniques including ellipsometry, Rutherford backscattering and forward recoil spectrometry, X-ray reflectivity, and atomic force and electron microscopies. After annealing at 350°C, BCESSQ films, initially 200 nm thick reach about 55% of their original thickness after 20 min. For films heated in air for 4 h, the atom fractions of carbon and hydrogen monotonically decrease to 10 and 30%, respectively, as annealing temperature increases from 225 to 450°C. The BCESSQ reactivity is reflected in the loss of chlorine at 400°C. At 450°C, the film density is 1.88 g/cm3, or 84% of thermally-grown silicon oxide. Upon exposure to ultraviolet ozone radiation, films ranging from ca. 200 to 700 nm are found to convert to ormosil films within 30 min. Surprisingly, the chlorine concentration is found to decrease more quickly than the hydrogen and carbon concentrations, suggesting that the ormosil film evolves HCl leaving a vinyl group of SiCHCH2. This reaction pathway differs from the thermal case. For films prepared by pyrolytic and photolytic methods, atomic force and electron microscopy studies show that the surface is smooth and featureless, the bulk is void free when view at a magnification of 50 000×, and the ormosil/substrate interface is continuous."
},
{
"article_title": "Silacrown ionophores",
"year": "1987",
"date": "536475600",
"link": "https://doi.org/10.1016/S0376-7388(00)81576-8",
"volume": "32 ",
"pages": " 83-92",
"is_gelest": true,
"journal_id": 93,
"author_ids": [152, 153, 154, 155, 156, 3],
"category_ids": [1],
"abstract": "A study is reported on the metal ion transport efficiency of various silacrown ether ionophores and their ethyleneoxy glycol hydrolysis products. The silacrowns are modified crown ethers in which an ethylene bridge has been replaced by a difunctional silyl group, e.g. dimethylsilyl. We have studied the relative transport efficiencies of the silacrowns with 4, 5, 6 and 7 oxygen atoms in the macrocycle for the alkali metals ions Li+, Na+, K+, Rb+, and Cs+. We have also performed experiments which illustrate that the silacrowns behave as short-term ion transporters. They will slowly hydrolyse in hydrophobic environments in contact with water to yield ethyleneoxy glycols which partition out of the hydrophobic phase into the hydrophilic phase, This terminates significant transport since the glycols are relatively inefficient ionophores. The potential of such shortterm ionophores is discussed."
},
{
"article_title": "Synthesis and Exploratory Deposition Studies of Isotetrasilane and Reactive Intermediates for Epitaxial Silicon",
"year": "2019",
"date": "1546318800",
"link": "https://doi.org/10.1021/acs.inorgchem.8b",
"volume": "58 ",
"pages": " 3050-3057",
"is_gelest": false,
"journal_id": 9,
"author_ids": [3, 9, 12, 1, 8],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Single Molecule Orthogonal Double-Click Chemistry–Inorganic to Organic Nanostructure Transition",
"year": "2020",
"date": "1577854800",
"link": "https://doi.org/10.1021/acsami.0c04018",
"volume": "12 ",
"pages": " 27737-27744",
"is_gelest": true,
"journal_id": 6,
"author_ids": [3, 1, 10, 9, 11, 5, 7],
"category_ids": [1],
"abstract": "Thiasilacyclopentane (TSCP) and azasilacyclopentane (ASCP) heteroatom cyclics have proven capable of rapidly converting hydroxylated surfaces to functionalized surfaces in inorganic click reactions. In this work, we demonstrate that the use of these reagents can be extended to “simultaneous double-clicking” when both inorganic and organic substrates are present at the onset of the reaction. The simultaneous double-click depends on a first ring-opening click with an inorganic substrate that is complete in ∼1 s at 30 °C and results in the reveal of a cryptic mercaptan or secondary amine group, which can then participate in a second click with an organic substrate. TSCPs and ASCPs can take part in tandem double-click reactions in which the organic substrate is added to the reaction mixture after the initial inorganic click reaction is completed. Additionally, ASCPs with exocyclic functionality, specifically N-alkenyl-, N-aminoalkyl, and N-alkynyl-ASCPs, are shown to be options for tandem double-clicking in which functionalization proceeds in two independent steps and the sequence of the double-click reaction can be reversed."
},
{
"article_title": "Carbon fiber reinforced thermoplastics",
"year": "1976",
"date": "189320400",
"link": "https://doi.org/10.1021/i360058a003",
"volume": "15 ",
"pages": " 100-114",
"is_gelest": true,
"journal_id": 121,
"author_ids": [166, 3, 170],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Silacrowns: Phase-Transfer Catalysts",
"year": "1983",
"date": "410245200",
"link": "https://doi.org/10.1021/om00075a018",
"volume": "2 ",
"pages": " 454-457",
"is_gelest": false,
"journal_id": 105,
"author_ids": [3, 40, 162, 163],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Conformational molecular switches for post-CMOS nanoelectronics",
"year": "2007",
"date": "1167627600",
"link": "https://doi.org/10.1109/TCSI.2007.907827",
"volume": "54 ",
"pages": " 2345-2352",
"is_gelest": true,
"journal_id": 50,
"author_ids": [8, 52, 3, 53, 54, 55, 56, 57, 58],
"category_ids": [1],
"abstract": "Theoretical treatments forecast that bistable CMOS devices using electronic charge as a state variable will operate at their maximum thermal dissipation limit possibly as early as 2012. The problem is further compounded by increasing manufacturing challenges associated with the ever decreasing logic switch dimensions. These challenges require the development of new fabrication strategies that replace or complement current top-down lithography with bottom-up protocols using controlled self-assembly of nanomaterial building blocks. To answer some of these issues, this paper focuses on a new device paradigm consisting of an arene-metal-arene conformational switch, addressable through capacitive, inductive, or resonant-tunneling field coupling. The operating principle is based on voltage-tunable modulation in quantum electron transmission. The switch is open (off) when the metal ion is displaced to a position at a C-H bond on the arene ring due to an externally applied bias. Conversely, when the external bias is removed, the metal ion moves to an axis- symmetric position on the arene ring, and the switch is closed (on). The paper presents a summary of the architecture, operating principle, and advantages of the conformational switch, along with associated findings from proof-of-concept theoretical and experimental studies of its target specifications and performance. The paper also discusses opportunities and challenges related to the integration of conformational switches into hybrid CMOS-molecular and monolithic (all molecular) circuits."
},
{
"article_title": "Low temperature inorganic chemical vapor deposition of Ti–Si–N diffusion barrier liners for gigascale copper interconnect applications",
"year": "2000",
"date": "946702800",
"link": "https://doi.org/10.1116/1.1306304",
"volume": "18 ",
"pages": " 2011-2015",
"is_gelest": true,
"journal_id": 61,
"author_ids": [47, 77, 78, 79, 80, 81, 82, 83, 8, 3, 73],
"category_ids": [1],
"abstract": "A new low temperature inorganic thermal chemical vapor deposition process has been developed for the growth of titanium–silicon–nitride (Ti–Si–N) liners for diffusion barrier applications in ultralarge scale integration copper interconnect schemes. This process employs the thermal reaction of tetraiodotitanium (TiI4), tetraiodosilane (SiI4), and ammonia (NH3) as, respectively, the individual Ti, Si, and N sources. Ti–Si–N films were successfully grown over a broad range of deposition conditions, including wafer temperature, process pressure, and TiI4, SiI4, and NH3 flows ranging, respectively, from 350 to 430°C, 0.1–1 Torr, and 2.5–8.0, 2.5–12.5, and 100–250 sccm. Film stoichiometry was tightly tailored through independent control of the Ti, Si, and N source flows. Film properties were characterized by x-ray photoelectron spectroscopy, Rutherford backscattering spectrometry, transmission electron microscopy, scanning electron microscopy, x-ray diffraction, and four-point resistivity probe. Resulting findings indicated that the texture and resistivity of the Ti–Si–N system were dependent on composition. In particular, films with a Ti33Si15N51 stoichiometry exhibited a nanocrystalline TiN phase within an amorphous SiN matrix, highly dense morphology, resistivity of ∼800μΩcm for 25 nm thick films, and step coverage of ∼50% in 130 nm wide, 10:1 aspect ratio trenches. Oxygen and iodine contaminant levels were below, respectively, 3 and 1.4 at. % each. Preliminary copper diffusion-barrier studies indicated that barrier failure for 25 nm thick Ti34Si23N43 films did not occur until after annealing for 30 min at 700°C."
},
{
"article_title": "Chemical vapor deposition of copper from Cu (I) hexafluoroacetylacetonate trimethylvinylsilane for ultralarge scale integration applications",
"year": "1996",
"date": "820472400",
"link": "https://doi.org/10.1116/1.588563",
"volume": "14 ",
"pages": " 1828-1836",
"is_gelest": false,
"journal_id": 79,
"author_ids": [129, 124, 130, 95, 8, 131, 132, 133, 73, 3],
"category_ids": [1],
"abstract": "In this article, the authors report the results of a study aimed at optimizing a manufacturable thermal copper‐chemical vapor deposition process, using (tmvs) CuI (hfac) as the source, where tmvs=trimethylvinylsilane and hfac=hexafluoroacetylacetonate, and establishing associated material and process characteristics and performance. This study employed a two‐stage design of experiments approach in conjunction with actual deposition runs on unpatterned silicon (Si) and titanium nitride (TiN) surfaces, as well as SEMATECH patterned TiN structures with feature sizes as small as 0.30 μm with aspect ratio 6:1. All samples were analyzed by Auger electron spectroscopy, Rutherford backscattering, four‐point resistivity probe, and cross‐section scanning electron microscopy. The results of these analyses showed that precursor concentration, substrate temperature, and in situ predeposition substrate surface plasma treatment play a key role in achieving good conformality and complete filling at high growth rates in aggressive via and trench structures. Based on these findings, an optimum process window was identified and employed to demonstrate complete high growth rate (∼2000 Å/min) filling of 0.3 μm, 6:1 aspect ratio, devices structures with pure copper at as‐deposited resistivities of 1.8 μΩ cm."
},
{
"article_title": "Low temperature plasma-promoted chemical vapor deposition of tantalum from tantalum pentabromide for copper metallization",
"year": "1998",
"date": "883630800",
"link": "https://doi.org/10.1116/1.590288",
"volume": "16",
"pages": " 2887",
"is_gelest": true,
"journal_id": 73,
"author_ids": [87, 96, 8, 3],
"category_ids": [1],
"abstract": "A low temperature plasma-promoted chemical vapor deposition (PPCVD) process has been developed for the growth of tantalum (Ta) from the halide source tantalum pentabromide (TaBr5), using hydrogen as reducing agent, for incorporation in emerging integrated circuitry (IC) copper metallization schemes. Ta films were produced at substrate temperatures of 400–450 °C, reactor working pressures of 0.6–0.7 Torr, hydrogen carrier flow rate of 50 sccm, hydrogen reactant flow rates between 200 and 1200 sccm, and plasma power ranging from 20 to 100 W, corresponding to a power density of 0.11–0.55 W/cm2. The films were subsequently characterized by Auger electron spectroscopy (AES), Rutherford backscattering (RBS), x-ray diffraction (XRD), atomic force microscopy (AFM), four-point resistivity probe, scanning electron microscopy (SEM), and cross-section SEM. These studies indicated that the Ta films thus produced were carbon and oxygen free, contained bromine concentration below 2.5 at. %, and exhibited better than 75% step coverage in nominally 0.6 μm, 2.5:1 aspect ratio, trench structures."
},
{
"article_title": "Low temperature plasma-assisted chemical vapor deposition of tantalum nitride from tantalum pentabromide for copper metallization",
"year": "1999",
"date": "915166800",
"link": "https://doi.org/10.1116/1.590533",
"volume": "17 ",
"pages": " 182-185",
"is_gelest": true,
"journal_id": 71,
"author_ids": [87, 96, 8, 3, 73],
"category_ids": [1],
"abstract": "In this article, the authors report the development of a new low temperature plasma-assisted chemical vapor deposition (PACVD) process for the growth of low resistivity, cubic tantalum nitride (TaN𝑥) for incorporation as a diffusion barrier/adhesion promoter in emerging ultralarge-scale integrated (ULSI) multilevel metallization (MLM) schemes. TaN𝑥 films were produced in a low density plasma using tantalum pentabromide, hydrogen, and nitrogen as coreactants. The films were grown at substrate temperatures of 350–450 °C, reactor working pressures of 0.9–1.6 Torr, hydrogen flow rates between 250 and 1500 sccm, nitrogen flow rates of 100–600 sccm, and plasma power ranging from 10 to 60 W, corresponding to a power density of 0.06–0.33W/cm2. The films were subsequently characterized by Auger electron spectroscopy, Rutherford backscattering spectrometry, x-ray diffraction, atomic force microscopy, four-point resistivity probe, and cross-sectional scanning electron microscopy. These studies indicated that the TaN𝑥 films produced were stoichiometric and carbon and oxygen free, contained bromine concentrations below 3 at. %, and exhibited resistivities as low as 150 μΩ cm. The conformality was higher than 95% in the nominally 0.3 μm, 4.5:1 aspect ratio structures. These results indicate that in the case of halide-based Ta chemistries, PACVD in a (N2+H2) plasma might be more viable than thermal CVD in a NH3 atmosphere for the deposition of TaN𝑥 for ULSI MLM applications."
},
{
"article_title": "Low temperature metal-organic chemical vapor deposition of tungsten nitride as diffusion barrier for copper metallization",
"year": "1999",
"date": "915166800",
"link": "https://doi.org/10.1116/1.590703",
"volume": "17 ",
"pages": " 1101-1104",
"is_gelest": true,
"journal_id": 70,
"author_ids": [106, 71, 70, 72, 8, 3],
"category_ids": [1],
"abstract": "A metal-organic chemical vapor deposition process has been developed for the growth of amorphous tungsten nitride thin films for barrier layer applications in ultralarge scale integration copper interconnect schemes. The process employs tungsten hexacarbonyl, [W(CO)6] and ammonia (NH3) as, respectively, the tungsten and nitrogen sources. Tungsten nitride films were produced within a wide process window, including a substrate temperature of 200–350 °C, W(CO)6 flow rate of 1–20 sccm, reactor pressure of 0.2–0.5 Torr, and NH3 flow rates of 100–500 sccm. The films were analyzed by x-ray photoelectron spectroscopy, cross-section scanning electron microscopy, x-ray diffraction, transmission electron microscopy, four-point resistivity probe, and Rutherford backscattering spectrometry. These studies indicated that the films consisted predominantly of a W2N phase. Films were grown with carbon and oxygen concentrations ⩽5 at. %, even at the lowest processing temperature investigated, where precursor dissociation would be expected to be the least efficient given the reduced thermal budget available to the decomposition reaction. Films deposited below 275 °C were amorphous, while those deposited between 275 and 350 °C were polycrystalline. Resistivities as low as 123 μΩ cm were achieved for 50-nm-thick films, with corresponding step coverage better than 90% in nominal 0.25 μm trench structures with aspect ratio of 4:1."
},
{
"article_title": "Thin-film Deposition of Silicon Nitrides and Oxides from Trihydridosilanes",
"year": "2015",
"date": "1420088400",
"link": "https://doi.org/10.1149/06409.0243ecst",
"volume": "64 ",
"pages": " 243-249",
"is_gelest": true,
"journal_id": 31,
"author_ids": [3, 9, 8],
"category_ids": [1],
"abstract": "Trihydridosilanes can provide a route for generating self-assembled monolayers on metal substrates. Under mild conditions, these precursors interact with a variety of clean, hydrogenated and fresh metal and metalloid surfaces, including titanium, silicon and gold. All classes of hydridosilanes have minimal interaction with anhydrous oxide surfaces. After initial deposition, SAMs formed from 2-chloroethyltrihydridosilanes may be converted to silicon nitride by pulsing with ammonia or silicon dioxide by pulsing water or oxygen. A proposed mechanism for the initial steps of deposition involves the dissociative adsorption of the silanes with the formation of hydrogen, followed by topmost atom layer insertion and concomitant surface reconstruction"
},
{
"article_title": "Near-Room-Temperature Soft Plasma Pulsed Deposition of SiCxNy from 1,3,5-tri(isopropyl)cyclotrisilazane",
"year": "2020",
"date": "1577854800",
"link": "https://doi.org/10.1149/09803.0121ecst",
"volume": "98 ",
"pages": " 121-135",
"is_gelest": false,
"journal_id": 3,
"author_ids": [1, 7, 3, 8],
"category_ids": [1],
"abstract": "Results are presented from an exploratory study of near-room-temperature pulsed deposition of SiCxNy thin films using 1,3,5-tri(isopropyl)cyclotrisilazane (TICZ, C9H27N3Si3) and soft remote ammonia (NH3) plasma co-reactants. The process involved four pulses: thermal adsorption of TICZ to the substrate at very low temperature, nitrogen (N2) purge, soft NH3 remote plasma step, and N2 purge. These steps were repeated until the desired film thickness was reached. The ratio of C to N in the films was modulated by controlling the substrate temperature in the range of 30 to 200oC. In-situ analysis of the deposition process was carried-out using spectroscopic ellipsometry, and the films were analyzed by x-ray photoelectron spectroscopy (XPS). The findings of this study indicate that the combination of reduced substrate thermal budget and soft remote plasma provides an optimum low energy environment for the controlled deposition of SiCxNy protective coatings on thermally fragile, chemically sensitive substrates, including plastics and polymers."
},
{
"article_title": "The effects of processing parameters in the chemical vapor deposition of cobalt from cobalt tricarbonyl nitrosyl",
"year": "1999",
"date": "915166800",
"link": "https://doi.org/10.1149/1.1391904",
"volume": "146 ",
"pages": " 2139",
"is_gelest": true,
"journal_id": 59,
"author_ids": [91, 70, 87, 71, 8, 3, 73],
"category_ids": [1],
"abstract": "This paper reports the development of a thermal chemical vapor deposition process for pure cobalt from the source precursor cobalt tricarbonyl nitrosyl for incorporation in integrated circuit silicide applications. Studies were carried out to examine the underlying mechanisms that control Co nucleation and growth kinetics, including the effects of key process parameters on film purity, texture, morphology, and electrical properties. For this purpose, systematic variations were implemented for substrate temperature, precursor flow, hydrogen reactant flow, and deposition time (thickness). Resulting films were analyzed by Rutherford backscattering spectrometry, X‐ray photoelectron spectroscopy, X‐ray diffraction, four‐point resistivity probe, scanning electron microscopy, and atomic force microscopy. These investigations identified an optimized process window for the growth of pure Co with resistivity of 9 ± 2 μΩ cm, smooth surface morphology, and root‐mean‐square surface roughness at or below 10% of film thickness. © 1999 The Electrochemical Society. All rights reserved."
},
{
"article_title": "Silicon Nitride and Silicon Nitride-Rich Thin Film Technologies: Trends in Deposition Techniques and Related Applications",
"year": "2017",
"date": "1483246800",
"link": "https://doi.org/10.1149/2.0011710jss",
"volume": "6 ",
"pages": " 691-714",
"is_gelest": true,
"journal_id": 16,
"author_ids": [8, 19, 1, 3],
"category_ids": [1],
"abstract": "This article provides an overview of the state-of-the-art chemistry and processing technologies for silicon nitride and silicon nitride-rich films, i.e., silicon nitride with C inclusion, both in hydrogenated (SiNx:H and SiNx:H(C)) and non-hydrogenated (SiNx and SiNx(C)) forms. The emphasis is on emerging trends and innovations in these SiNx material system technologies, with focus on Si and N source chemistries and thin film growth processes, including their primary effects on resulting film properties. It also illustrates that SiNx and its SiNx(C) derivative are the focus of an ever-growing research and manufacturing interest and that their potential usages are expanding into new technological areas."
},
{
"article_title": "Cobalt Thin Films: Trends in Processing Technologies and Emerging Applications",
"year": "2019",
"date": "1546318800",
"link": "https://doi.org/10.1149/2.0051902jss",
"volume": "8 ",
"pages": " P119-P152",
"is_gelest": false,
"journal_id": 5,
"author_ids": [8, 9, 1, 3],
"category_ids": [1],
"abstract": "Cobalt metallic films are the subject of an ever-expanding academic and industrial interest for incorporation into a multitude of new technological applications. This report reviews the state-of-the art chemistry and deposition techniques for cobalt thin films, highlighting innovations in cobalt metal-organic chemical vapor deposition (MOCVD), plasma and thermal atomic layer deposition (ALD), as well as pulsed MOCVD technologies, and focusing on cobalt source precursors, thin and ultrathin film growth processes, and the resulting effects on film composition, resistivity and other pertinent properties."
},
{
"article_title": "Emerging Molecular and Atomic Level Techniques for Nanoscale Applications",
"year": "2018",
"date": "1514782800",
"link": "https://doi.org/10.1149/2.F07184if",
"volume": "27 ",
"pages": " 61-65",
"is_gelest": false,
"journal_id": 10,
"author_ids": [8, 1, 3],
"category_ids": [1],
"abstract": "This overview provides an introduction and comparison of emerging processing technologies that represent the best contenders to satisfy future demands for ultrathin film applications. In particular, ALD, MLD, SAM, and CCD are newer techniques for ultrathin or near-zero-thickness film fabrication. These techniques are now entering early stages of commercialization, especially in biosensors, semiconductors and hetero-devices. This article introduces these techniques with emphasis on process descriptions and definitions in order to provide clarification and is illustrated with application examples. Sufficient citations are provided to allow the interested reader to pursue the subjects in more depth, but are not intended to be comprehensive."
},
{
"article_title": "Silicon Nitride and Silicon Nitride-Rich Thin Film Technologies: State-of-the-Art Processing Technologies, Properties, and Applications",
"year": "2020",
"date": "1577854800",
"link": "https://doi.org/10.1149/2162-8777/aba447",
"volume": "9 ",
"pages": " 063006",
"is_gelest": false,
"journal_id": 5,
"author_ids": [8, 9, 1, 3],
"category_ids": [1],
"abstract": "Accelerating interest in silicon nitride thin film material system continues in both academic and industrial communities due to its highly desirable physical, chemical, and electrical properties and the potential to enable new device technologies. As considered here, the silicon nitride material system encompasses both non-hydrogenated (SiNx) and hydrogenated (SiNx:H) silicon nitride, as well as silicon nitride-rich films, defined as SiNx with C inclusion, in both non-hydrogenated (SiNx(C)) and hydrogenated (SiNx:H(C)) forms. Due to the extremely high level of interest in these materials, this article is intended as a follow-up to the authors' earlier publication [A. E. Kaloyeros, F. A. Jové, J. Goff, B. Arkles, Silicon nitride and silicon nitride-rich thin film technologies: trends in deposition techniques and related applications, ECS J. Solid State Sci. Technol., 6, 691 (2017)] that summarized silicon nitride research and development (R&D) trends through the end of 2016. In this survey, emphasis is placed on cutting-edge achievements and innovations from 2017 through 2019 in Si and N source chemistries, vapor phase growth processes, film properties, and emerging applications, particularly in heterodevice areas including sensors, biointerfaces and photonics."
},
{
"article_title": "Factors contributing to the stability of alkoxysilanes in aqueous solution",
"year": "1992",
"date": "694242000",
"link": "https://doi.org/10.1163/156856192X00133",
"volume": "6 ",
"pages": " 193-206",
"is_gelest": true,
"journal_id": 45,
"author_ids": [3, 147, 36, 61],
"category_ids": [1],
"abstract": "Parameters controlling intrinsic stability and reactivity of organosilanols generated from alkoxysilanes in aqueous environments have been elucidated in several experiments. Data involving kinetics, equilibrium, phase separation, and bonding studies of alkyl and organofunctional alkoxysilanes are presented. The studies indicate that the rates of hydrolysis of alkoxysilanes are generally related to their steric bulk, but demonstrate that after rate-limiting hydrolysis of the first alkoxy group steric effects are much less important. Aqueous hydrolysis of alkylalkoxysilanes was studied to determine equilibrium constants and the extent of oligomerization up to phase separation. In the case of propyltrialkoxysilane, phase separation is coincident with the formation of tetramer. The equilibrium constant for esterification of silanols is Also, the performance properties of new water-borne silanes were evaluated and in most cases, their performance equalled or exceeded their traditional silane counterparts."
},
{
"article_title": "Pendant Dipodal Alkysilane Bonded Phases for Low pH HPLC",
"year": "2009",
"date": "1230786000",
"link": "https://doi.org/10.13140/RG.2.2.27713.81764",
"volume": "1",
"pages": "1",
"is_gelest": true,
"journal_id": 48,
"author_ids": [3, 33, 9, 48],
"category_ids": [1],
"abstract": "While octadecylsilanes remain the dominant materials for preparation of bonded phases utilized in preparative chromatography, their stability is not robust in low pH phosphate buffer systems utilized for many biological separations. 1,2-bis(trichlorosilyl)octadecane, the first example of a pendant disposal silane has been evaluated in bonded phases at pH extremes. Keywords: Chromatography, Bonded Phases, Organosilicon"
},
{
"article_title": "Low-temperature chemical vapor deposition of tantalum nitride from tantalum pentabromide for integrated circuitry copper metallization applications",
"year": "1999",
"date": "915166800",
"link": "https://doi.org/10.1557/JMR.1999.0276",
"volume": "14 ",
"pages": " 2043-2052",
"is_gelest": true,
"journal_id": 65,
"author_ids": [87, 95, 71, 70, 96, 8, 3, 73],
"category_ids": [1],
"abstract": "A low-temperature (>450 °C) thermal chemical vapor deposition (CVD) process was developed for the growth of TaNx from the reaction of tantalum pentabromide, ammonia, and hydrogen. Studies of process reaction kinetics yielded two sequential rate-controlling steps, with an activation energy of 0.45 eV for the kinetically limited reaction regime. Additionally, a systematic design of experiments approach examined the effects of key process parameters, namely, substrate temperature, source temperature, and hydrogen and ammonia flows, on film properties. A wide CVD process window was established for nitrogen-rich amorphous TaNx with contamination below 1 at.%. Film conformality was higher than 95% in nominally 0.30 μm, 4.5: 1 aspect ratio, trench structures."
},
{
"article_title": "Tantalum diffusion barrier grown by inorganic plasma-promoted chemical vapor deposition: Performance in copper metallization",
"year": "2000",
"date": "946702800",
"link": "https://doi.org/10.1557/JMR.2000.0400",
"volume": "15 ",
"pages": " 2800-2810",
"is_gelest": true,
"journal_id": 65,
"author_ids": [8, 87, 81, 88, 3],
"category_ids": [1],
"abstract": "As-deposited and annealed tantalum films, grown by plasma-promoted chemical vapor deposition (PPCVD) using pentabromotantalum and hydrogen as coreactants, were evaluated as diffusion barriers in copper metallization. Stacks consisting of 500-nm-thick sputtered Cu/55-nm-thick untreated PPCVD Ta/Si were annealed in argon in the range 450 to 650 °C, in 50 °C intervals, along with sputtered Cu/preannealed PPCVD Ta/Si and sputtered Cu/sputtered Ta/Si stacks of identical thickness. Pre- and postannealed stacks were characterized by x-ray photoelectron spectroscopy, Auger electron spectroscopy, Rutherford backscattering spectrometry, hydrogen profiling, x-ray diffraction, atomic force microscopy, sheet resistance measurements, and Secco chemical treatment and etch-pit observation by scanning electron microscopy. The sputtered and preannealed PPCVD Ta films acted as viable diffusion barriers up to 550 °C, while the as-deposited PPCVD Ta films failed above 500 °C. In all cases, breakdown occurred through the migration of Cu into Si, rather than an interfacial reaction between Ta and Si, in agreement with previously reported results for sputtered Ta films. The accelerated barrier failure for as-deposited PPCVD Ta might have been caused by the presence of approximately 20 at.% hydrogen in the as-deposited PPCVD Ta, an observation which was supported by the enhanced performance of the same PPCVD Ta films after annealing-induced hydrogen removal."
},
{
"article_title": "Commercial applications of sol-gel-derived hybrid materials",
"year": "2001",
"date": "978325200",
"link": "https://doi.org/10.1557/mrs2001.94",
"volume": "26 ",
"pages": " 402-408",
"is_gelest": false,
"journal_id": 58,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Dipodal Silanes: Important Tool for Surface Modification to Improve Durability",
"year": "2014",
"date": "1388552400",
"link": "https://doi.org/10.1557/opl.2014.257",
"volume": "1",
"pages": "1648",
"is_gelest": true,
"journal_id": 36,
"author_ids": [35, 39, 34, 9, 36, 3],
"category_ids": [1],
"abstract": "Dipodal silanes possess two silicon atoms that can covalently bond to a surface. They offer a distinctive advantage over conventional silanes in terms of maintaining the integrity of surface coatings, adhesive primers and composites in aqueous and aggressive environments. The improved durability of such dipodal silanes is associated with an increased crosslink density of the interphase and the inherent resistance to hydrolysis, as they can form six, rather than three, Si-O bonds to the substrate. This study examines dipodal silanes with hydrophobic alkyl functionality and compares them with similar functionality on conventional silane coupling agents. It also introduces new structural dipodal silanes containing “pendant” and “bridged” functionality and then examines their stability in aqueous environments. In strongly acidic and brine environments, dipodal silanes clearly demonstrate improved resistance to hydrolysis compared to conventional silane coupling agents."
},
{
"article_title": "Single Molecular Layer Adaption of Interfacial Surfaces by Cyclic Azasilane \"Click-Chemistry\"",
"year": "2015",
"date": "1420088400",
"link": "https://doi.org/10.1557/opl.2015.655",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 30,
"author_ids": [20, 34, 35, 36, 3],
"category_ids": [1],
"abstract": "The surfaces of inorganic substrates containing hydroxyl groups can be adapted to a variety of physical and chemical requirements by reaction with cyclic azasilanes. The moderately-strained ring structure of cyclic azasilanes containing adjacent Si and N atoms, along with the high oxophilicity of silicon, enables the high reactivity towards available hydroxyl groups on all siliceous surfaces investigated, including amorphous silica and borosilicate glass. The reaction occurs quantitatively at room temperature, requires no catalyst and has no byproducts. This investigation looks specifically at the reaction kinetics by means of DRIFT spectroscopy and quantifies extent of reaction by TGA. The less sterically-hindered the Si–N bond, the faster the reaction occurs. In all cases, the reaction is essentially complete in less than one minute. This study provides the first confirmation that the rate and extent of reaction without catalysis or byproducts of cyclic azasilanes conforms to the Sharpless requirements for “click chemistry” and can be deemed “click chemistry for surfaces.”"
},
{
"article_title": "Silicon Nitride Films Deposited by Atmospheric Pressure Chemical Vapor Deposition",
"year": "1998",
"date": "883630800",
"link": "https://doi.org/10.1557/PROC-495-107",
"volume": "495",
"pages": " 107-112",
"is_gelest": false,
"journal_id": 75,
"author_ids": [118, 119, 87, 8, 3],
"category_ids": [1],
"abstract": "Films of silicon nitride are widely used in semiconductor technologies for very large scale integration (VLSI), thin film transistor (TFT), and solar cell applications. Current production technologies for silicon nitride use low pressure chemical vapor deposition (LPCVD) at temperatures > 700 °C or plasma enhanced chemical vapor deposition (PECVD) at temperatures below 450 °C. In this report, successful deposition of silicon nitride films by the low temperature thermal atmospheric pressure chemical vapor deposition (APCVD) method is described. Using a novel precursor tetraiodosilane (SiI4), deposition of silicon nitride has been achieved at temperature as low as 400 °C. Data pertaining to the dependence of film properties on deposition temperature are presented, along with a evaluation of the deposition rate, composition, chemical structure, and conformality of the resulting films."
},
{
"article_title": "Low Temperature CVD Route to Binary and Ternary Diffusion Barrier Nitrides for Cu Metallization",
"year": "1998",
"date": "883630800",
"link": "https://doi.org/10.1557/PROC-514-499",
"volume": "514",
"pages": " 499",
"is_gelest": true,
"journal_id": 74,
"author_ids": [8, 97, 71, 82, 87, 116, 105, 3, 117, 73],
"category_ids": [1],
"abstract": "The identification of viable diffusion barrier/adhesion promoter material and associated deposition processes is a critical factor in the successful development of structurally and electrically reliable copper based metallization schemes. As feature sizes continue shrinking, such materials are expected to delivery enhanced performance at increasingly thinner layers to allow maximum space utilization by the actual conductor. In this respect, Ta and W based binary and ternary nitrides present promising solutions in view of their hardness, chemical inertness, and thermal stability to high temperatures. Additionally, their availability in amorphous form provides the added benefit of inherent absence of grain boundaries, which usually serve as a primary diffusion path. This paper presents finds from the development of low0temperature (,350°C) CVD processes for the growth of ultrathin Ta, W, Ta-Si, and WSinitride layers for sub−0.18 micron device structures. These processes employ novel inorganic and metal-organic source precursors which allow for the in-situ, one-step, growth of binary and ternary nitrides from appropriate mixtures of the corresponding source precursors. Results will also be discussed from diffusion barrier studies which established performance metris for the applicability of such materials in copper interconnect technologies."
},
{
"article_title": "Integration of PECVD tungsten nitride as a barrier layer for copper metallization",
"year": "1999",
"date": "915166800",
"link": "https://doi.org/10.1557/PROC-564-321",
"volume": "1",
"pages": "564",
"is_gelest": false,
"journal_id": 69,
"author_ids": [91, 101, 102, 103, 104, 105, 8],
"category_ids": [1],
"abstract": "Amorphous tungsten nitride (WNx) is a promising diffusion barrier for extending Cu metallization beyond 0.18 μm. This study evaluates the barrier performance, adhesion, and step coverage of PECVD WN0.5 integrated with a CVD Cu seed layer. The WN0.5 films exhibit amorphous structure with 33% bottom and side-wall step coverage in 0.14 μm wide structures with 9:1 aspect ratio. The potential of 50 Å WN0.5 as an effective Cu barrier is shown by the absence of Secco etch-pits in the Si substrate after a 30 min anneal at 500°C. When deposited on PECVD WN0.5 the CVD Cu films exhibit uniform nucleation, and as deposited resistivity of 2.5 μΩ-cm. Step coverage of the CVD Cu is better than 95% in 0.14 μm structures. Adhesion exceeding epoxy strength of the CVD Cu seed layer even to air-exposed WN0.5 is demonstrated using stud-pull adhesion tests."
},
{
"article_title": "β-Acetoxyethyl Silsesquioxanes: Chloride-Free Precursors for SiO2 Films via Staged Hydrolysis",
"year": "2000",
"date": "946702800",
"link": "https://doi.org/10.1557/PROC-606-251",
"volume": "606",
"pages": " 251-256",
"is_gelest": false,
"journal_id": 64,
"author_ids": [67, 3, 85, 86],
"category_ids": [1],
"abstract": "Silsesquioxanes containing β-acetoxyethyl (BAE) groups are processible resins that can be employed as spin-on-glass precursors to dielectric silica films. Thermal treatment >250 °C results in extrusion of ethylene from the CH2CH2OCOCH3 moiety with formation of Si- OCOCH3 groups, which undergo facile hydrolysis to a silica network. A minor pathway involving extrusion of acetic acid leaves some silicon vinyl groups, leading to residual organic carbon in the material. However, addition of a fluoride ion catalyst greatly accelerates the major reaction, resulting in lower conversion temperatures (<200 °C), quantitative extrusion of ethylene, and essentially pure silica. Alternatively, BAESSQs can be processed photochemically (λ <200 nm) to cleanly yield silica at ambient temperature."
},
{
"article_title": "Applications of Hybrid Polymers Generated from Living Anionic Ring Opening Polymerization",
"year": "2021",
"date": "1609477200",
"link": "https://doi.org/10.3390/molecules26092755",
"volume": "26 ",
"pages": " 2755",
"is_gelest": false,
"journal_id": 1,
"author_ids": [1, 2, 3],
"category_ids": [1],
"abstract": "Increasingly precise control of polymer architectures generated by “Living” Anionic Ring-Opening Polymerization (Living AROP) is leading to a broad range of commercial advanced material applications, particularly in the area of siloxane macromers. While academic reports on such materials remain sparse, a significant portion of the global population interacts with them on a daily basis—in applications including medical devices, microelectronics, food packaging, synthetic leather, release coatings, and pigment dispersions. The primary driver of this increased utilization of siloxane macromers is their ability to incorporate the properties of silicones into organic structures in a balanced manner. Compared to organic polymers, the differentiating properties of silicones—low Tg, hydrophobicity, low surface energy, and high free molal space—logically lend themselves to applications in which low modulus, release, permeability to oxygen and moisture, and tactile interaction are desired. However, their mechanical, structural and processing properties have until recently precluded practical applications. This review presents applications of “Living” AROP derived polymers from the perspective of historical technology development. Applications in which products are produced on a commercial scale—defined as not only offered for sale, but sold on a recurrent basis—are emphasized. Hybrid polymers with intriguing nanoscale morphology and potential applications in photoresist, microcontact printing, biomimetic soft materials, and liquid crystals are also discussed. Previously unreported work by the authors is provided in the context of this review."
},
{
"article_title": "Hydridosilane Modification of Metals: An Exploratory Study",
"year": "2012",
"date": "1325394000",
"link": "https://doi.org/10.4028/www.scientific.net/AMR.254.111",
"volume": "26 ",
"pages": " 41-54",
"is_gelest": false,
"journal_id": 45,
"author_ids": [3, 9, 48, 47, 49, 8],
"category_ids": [1],
"abstract": "Under mild conditions, trihydridosilanes interact with a variety of clean, hydrogenated and fresh metal and metalloid surfaces, including titanium, silicon and gold. In contrast, monohydridosilanes appear to have minimal interaction. All classes of hydridosilanes have minimal interaction with anhydrous oxide surfaces. Preliminary results suggest that surface modification with trihydridosilanes may provide a route for generating self-assembled monolayers on metal substrates. The synthesis of new trihydridosilanes is described. Contact angle, FTIR and XPS data for modified surfaces are provided."
},
{
"article_title": "Long-Chain Organofunctional Silanes: Synthesis and Surface Derivatization",
"year": "2012",
"date": "1325394000",
"link": "https://doi.org/10.4028/www.scientific.net/AMR.415-417.1829",
"volume": "415",
"pages": " 1829-1836",
"is_gelest": false,
"journal_id": 40,
"author_ids": [9, 3, 47, 8],
"category_ids": [1],
"abstract": "A series of organofunctional long-chain alkylfunctional silanes have been synthesized for the purpose of derivatization of micro- and nanoparticles and generation of molecular monolayers and films on the substrates. 11-bromoundecylsilane and 1, 10-disiladecane are evaluated to interact with a variety of clean hydrogenated metal and metalloid including titanium, silicon and silicon dioxide. The surface of those treated substrates has been analyzed by X-ray photoelectron spectroscopy (XPS) and reflection-absorption infrared spectroscopy (RAIRS). Our preliminary results indicate that self-assembled monolayer has been well formed on titanium metal and silicon wafer, minimally on silicon-dioxide. The discussion of experimental results is also provided."
},
{
"article_title": "Skin adhesion sebum-resistant formulations",
"year": "2020",
"date": "1577854800",
"link": "https://fr.zone-secure.net/48287/1261175/#page=329",
"volume": "Pi",
"pages": " 329-334",
"is_gelest": false,
"journal_id": 7,
"author_ids": [4, 5, 1],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Interlayer mediated epitaxy of cobalt silicide on silicon (100) from low temperature chemical vapor deposition of cobalt formation mechanisms and associated properties",
"year": "2001",
"date": "978325200",
"link": "https://iopscience.iop.org/article/10.1149/1.1344535/meta",
"volume": "148 ",
"pages": " C21",
"is_gelest": true,
"journal_id": 59,
"author_ids": [69, 70, 71, 72, 8, 3, 73],
"category_ids": [1],
"abstract": "This paper reports the development of a methodology for the growth of epitaxial that uses Co films deposited by low temperature (390°C) chemical vapor deposition (CVD) from cobalt tricarbonyl nitrosyl as source precursor. This CVD process exploits the reaction kinetics associated with the adsorption and decomposition of on Si surfaces to ensure the in situ, sequential growth of an ultrathin interfacial oxide layer followed by a Co thin film in a single deposition step. It is demonstrated that this interlayer, consisting of a Si-O or a Co-Si-O phase, inhibits silicidation for uncapped CVD Co regardless of annealing times and temperatures. Instead, Co agglomeration is observed, with the degree of agglomeration being proportional to the annealing temperature. The agglomeration is due to a reduction in the overall energy of the system through decrease of the Co/substrate interfacial area. Alternatively, for Ti/TiN capped CVD Co samples, the interfacial layer appears to play a role similar to that observed for similar layers in interlayer mediated epitaxy (IME). This assessment is supported by the observation of epitaxial for capped CVD Co samples after a single-step anneal at 725°C for 30 s. In contrast, Ti/TiN capped PVD Co samples annealed under identical processing conditions exhibited a polycrystalline phase with a strong (200) texture. As such, the methodology presented herein represents a modified IME technique for the growth of high quality, epitaxial films for applications in emerging microelectronics device technologies. © 2000 The Electrochemical Society. All rights reserved."
},
{
"article_title": "Tantalum nitride films grown by inorganic low temperature thermal chemical vapor deposition diffusion barrier properties in copper metallization",
"year": "1999",
"date": "915166800",
"link": "https://iopscience.iop.org/article/10.1149/1.1391582/meta",
"volume": "146 ",
"pages": " 170-176",
"is_gelest": true,
"journal_id": 59,
"author_ids": [8, 87, 107, 105, 108, 95, 96, 3, 73],
"category_ids": [1],
"abstract": "Key findings are presented from a systematic study which evaluated the performance of chemical vapor deposited (CVD) nitrogenrich tantalum nitride films as a diffusion barrier in copper (Cu) based metallization schemes. For this purpose, 3800 Å thick Cu films were grown by physical vapor deposition (PVD) on 550 Å thick films which were deposited by low temperature (<425°C) thermal CVD (TCVD) using tantalum pentabromide , ammonia, and hydrogen as coreactants. The resulting stacks were annealed in argon ambient at 450, 500, 550, and 650°C for 30 min each, along with similar PVD Cu/PVD bilayers of identical thickness. Both types of pre‐ and postannealed stacks were characterized by X‐ray photoelectron spectroscopy, Auger electron spectroscopy, Rutherford backscattering spectrometry, nuclear reaction analysis for hydrogen profiling, X‐ray diffraction, stack sheet resistance measurements, and Secco chemical treatment and etch‐pit observation by scanning electron microscopy. The resulting findings showed that the PVD films provided an excellent barrier against Cu diffusion throughout the annealing window investigated. Alternatively, the TCVD films exhibited similar stability up to 550°C. Barrier failure occurred, however, at temperatures between 550 and 600°C, as revealed by the formation of etch pits after Secco etch treatment. The failure of the TCVD films could not be attributed to bromine incorporation, given that residual bromine (∼0.5 atom %) in the TCVD films was highly stable against thermal diffusion in the temperature window investigated. Instead, the higher thermal stability of the PVD was attributed to differences in film microstructure and crystalline phase, or the location of excess nitrogen within the film matrix. © 1999 The Electrochemical Society. All rights reserved."
},
{
"article_title": "Barrier properties of titanium nitride films grown by low temperature chemical vapor deposition from titanium tetraiodide",
"year": "1997",
"date": "852094800",
"link": "https://iopscience.iop.org/article/10.1149/1.1837520/pdf",
"volume": "144 ",
"pages": " 1002-1008",
"is_gelest": true,
"journal_id": 1,
"author_ids": [123, 71, 110, 77, 124, 72, 125, 8, 3, 126],
"category_ids": [1],
"abstract": "Results are presented from a systematic study of the composition, texture, and electrical properties of titanium nitride (TiN) films and their performance as diffusion barrier in multilevel interconnect schemes of ultralarge scale integration (ULSI) computer chip device structures. The films were grown by low temperature (<450°C) inorganic chemical vapor deposition using titanium tetraiodide as source precursor and ammonia and hydrogen as co‐reactants. The TiN films were nitrogen‐rich., with iodine concentrations below 2 atom percent, displayed resistivities in the range 100 to 150 μΩ cm depending on thickness, and exhibited excellent step coverage with better than 90% conformality in both nominal 0.45 μm, 3:1 aspect ratio and 0.25 μm, 4:1 aspect ratio contact structures. A comparison of the properties of chemical vapor deposited (CVD) TiN with equivalent physical vapor deposited (PVD) TiN showed that reactivity with Al‐0.5 a/o Cu alloys was equivalent in both cases. In particular, a 10% increase in the Al‐Cu/TiN stack sheet resistance was observed for both types of TiN after a 450°C, 30 min sinter. Similarly, the characteristics of CVD tungsten and reflow plug fills were identical on both types of TiN films. However, barrier performance for CVD TiN in aluminum and tungsten plug technologies was superior to that of PVD TiN, as evidenced by lower contact diode leakage for CVD TiN in comparison with PVD TiN films of equal thickness. This improved barrier performance could be attributed to a combination of factors, which include the nitrogen‐rich composition, higher density, and enhanced conformality of the CVD TiN phase in comparison with the PVD TiN. In view of the superior step coverage and diffusion barrier characteristics, the low temperature inorganic CVD route to TiN seems to provide an adequate replacement for conventional PVD TiN in emerging ULSI metallization interconnect schemes."
},
{
"article_title": "The Effects of Processing Parameters in the Low‐Temperature Chemical Vapor Deposition of Titanium Nitride from Tetraiodotitanium",
"year": "1998",
"date": "883630800",
"link": "https://iopscience.iop.org/article/10.1149/1.1838322/meta",
"volume": "145 ",
"pages": " 676",
"is_gelest": false,
"journal_id": 1,
"author_ids": [109, 71, 110, 77, 111, 112, 72, 8, 3],
"category_ids": [1],
"abstract": "Key findings are presented from a systematic study aimed at establishing a fundamental understanding of precursor decomposition pathways and resulting film nucleation and growth kinetics in the chemical vapor deposition of titanium nitride from tetraiodotitanium. As part of the study, key process parameters were varied systematically in order to determine process activation energy and establish corresponding functionality curves for film purity, growth rate, structure, and morphology. The key process parameters studied were substrate temperature, source temperature, hydrogen carrier gas flow, and reactor pressure. Corresponding findings indicated that all four parameters showed a direct and significant effect on film quality. Additionally, a thorough evaluation of resulting film composition, texture, and electrical properties led to the identification of a wide process window for the growth of TiN films with optimized characteristics and performance. In this process window, the TiN films were nitrogen‐rich, with iodine concentrations below 2 atom %, displayed resistivities in the range 100 to 150 μΩ cm, depending on thickness, and exhibited excellent step coverage, better than 90% conformality in both nominal 0.45 μm, 3:1 aspect ratio and 0.25 μm, 4:1 aspect ratio contact structures."
},
{
"article_title": "Dual functional silicones as building blocks for higher order silicones",
"year": "2012",
"date": "1325394000",
"link": "https://moam.info/dual-functional-silicones-as-building-blocks-for-_5bb7059a097c4745448b463c.html",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 44,
"author_ids": [3, 1, 45, 42, 33, 46],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Hybrid polymers in the marketplace",
"year": "1999",
"date": "915166800",
"link": "https://onlinelibrary.wiley.com/doi/10.1002/chin.200007284",
"volume": "29 ",
"pages": " 7-16",
"is_gelest": false,
"journal_id": 66,
"author_ids": [3],
"category_ids": [1],
"abstract": "ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option."
},
{
"article_title": "Polysiloxane—Thermoplastic Interpenetrating Polymer Networks",
"year": "1989",
"date": "599634000",
"link": "https://pubs.acs.org/doi/10.1021/ba-1990-0224.ch010",
"volume": "224 ",
"pages": " 181-199",
"is_gelest": false,
"journal_id": 90,
"author_ids": [3, 149],
"category_ids": [1],
"abstract": "Polysiloxane-thermoplastic interpenetrating polymer networks (IPNs) are a unique class of polymer-polymer composites that significantly extend the process and mechanical property range of silicone elastomers and allow modification of the behavior of thermoplastics. The materials are characterized by reactive processing consistent with traditional thermoplastic technology and the development of physical properties consistent with semi-IPNs generated from polysiloxanes cross-linked in a variety of thermoplastic matrices, including polyurethanes, polyamides, and polyolefins. The semi-IPNs are prepared by melt-mixing hydride- and vinyl-functionalized polysiloxanes with thermoplastics and inducing cross-linking with a platinum catalyst in a second melt-process step. Polysiloxane composition, cross-link density, and total content affect the process and mechanical behavior of the semi-IPNs. Polysiloxane-thermoplastic IPNs may be used in biomedical materials, gears and bearings, and applications in which the dimensional stability of crystalline resins must be enhanced."
},
{
"article_title": "Silacrowns, a New Class of Immobilizable Phase Transfer Catalysts",
"year": "1982",
"date": "378709200",
"link": "https://pubs.acs.org/doi/abs/10.1021/bk-1982-0192.ch017",
"volume": "192",
"pages": " 281-292",
"is_gelest": true,
"journal_id": 109,
"author_ids": [3, 163, 40],
"category_ids": [1],
"abstract": "Immobilized phase transfer catalysts can be expected to demonstrate the same advantages as other immobilized catalysts. The reactions are clean, the products are uncontaminated by catalysts, the catalyst is reuseable. The desireable properties of phase transfer catalysts that must be maintained include their ability to facilitate certain organic syntheses, behave as ionophores, solubilize metal salts and act as complexing agents. Polymer bound phase transfer catalysts, both onium salt1,2,3,4 and crown ether5,6 have been reported. The polymer bound phase transfer catalysts appear to require two special conditions for optimum product turnover: a relatively long \"spacer\" group between the polymer and the catalytic center and a swollen polymer substrate. It has been recently reported that the use of silica gel for immobilization of onium salts reduces the importance of \"spacer groups\" for catalytic activity although they do modify the adsorptive capacity of the silica.7 Crown ethers have also been recently immobilized on"
},
{
"article_title": "Living Polymerization Routes to Siloxane Macromers and Higher Order Silicone Structures",
"year": "2013",
"date": "1357016400",
"link": "https://pubs.acs.org/doi/abs/10.1021/bk-2013-1154.ch005",
"volume": "1154",
"pages": " 59-78",
"is_gelest": true,
"journal_id": 38,
"author_ids": [1, 42, 3],
"category_ids": [1],
"abstract": "This report describes the synthesis, characterization and physical properties of symmetric silicone macromers, as well as new dual functional macromers, with both asymmetric and symmetric structures. Higher order silicone structures are introduced as convergent-branched silicones synthesized using hydride functional silicone macromer building blocks linked to a cyclic siloxane core. Silicone chain length, endgroup functionality and number of chains attached to the core have been studied to elucidate the physical properties of these higher order silicone structures."
},
{
"article_title": "Facile Surface Modification of Hydroxylated Silicon Nanostructures using Heterocyclic Silanes",
"year": "2016",
"date": "1451624400",
"link": "https://pubs.acs.org/doi/abs/10.1021/jacs.6b08614",
"volume": "138 ",
"pages": " 15106-15109",
"is_gelest": true,
"journal_id": 19,
"author_ids": [22, 23, 24, 9, 25, 26, 3, 27],
"category_ids": [1],
"abstract": "Heterocyclic silanes containing Si–N or Si–S bonds in the ring undergo a ring opening reaction with −OH groups at the surface of porous Si nanostructures to generate −SH or −NH functional surfaces, grafted via O–Si bonds. The reaction is substantially faster (0.5–2 h at 25 °C) and more efficient than hydrolytic condensation of trialkoxysilanes on similar hydroxy-terminated surfaces, and the reaction retains the open pore structure and photoluminescence of the quantum-confined silicon nanostructures. The chemistry is sufficiently mild to allow trapping of the test protein lysozyme, which retains its enzymatic activity upon release from the modified porous nanostructure."
},
{
"article_title": "Understanding ALD, MLD and SAMs as they enter the fab",
"year": "2018",
"date": "1514782800",
"link": "https://sst.semiconductor-digest.com/issue/?id=28534&url=/articles/sst/print/volume-1/issue-61/features/deposition/understanding-ald-mld-and-sams-as-they-enter-the-fab",
"volume": "61 ",
"pages": " 22-24",
"is_gelest": true,
"journal_id": 13,
"author_ids": [3, 1, 8],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Barbecuing - A Scientific Technological Effort",
"year": "1978",
"date": "252478800",
"link": "https://www.academia.edu/12158607/Barbecuing_A_Scientific_Technological_Effort",
"volume": "8 ",
"pages": " IBC",
"is_gelest": false,
"journal_id": 103,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Dehydrogenative Silane Coupling on Porous Silicon",
"year": "2016",
"date": "1451624400",
"link": "https://www.academia.edu/23414872/Dehydrogenative_Silane_Coupling_on_Porous_Silicon",
"volume": "1",
"pages": "1",
"is_gelest": true,
"journal_id": 25,
"author_ids": [22, 28, 9, 3, 27],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Elevated Temperature Performance of Thermoplastic Composites",
"year": "1975",
"date": "157784400",
"link": "https://www.academia.edu/29914531/Elevated_Temperature_Performance_of_Thermoplastic_Composites",
"volume": "1",
"pages": "17-E 1-16",
"is_gelest": false,
"journal_id": 133,
"author_ids": [166, 3, 174, 176],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "How Time and Heat Affect Properties of Plastics",
"year": "1975",
"date": "157784400",
"link": "https://www.academia.edu/30469169/How_Time_and_Heat_Affect_the_Properties_of_Plastics",
"volume": "47 ",
"pages": " 79-81",
"is_gelest": false,
"journal_id": 91,
"author_ids": [166, 3, 174],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Hydrolysis in Stages: A New Polymer Route to Modified Silica Materials",
"year": "1996",
"date": "820472400",
"link": "https://www.academia.edu/49265293/Hydrolysis_in_Stages_A_New_Polymer_Route_to_Modified_Silica_Materials",
"volume": "1",
"pages": "B-21",
"is_gelest": true,
"journal_id": 80,
"author_ids": [89, 62, 3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Organoalkoxysilane Hydrolysis, Deposition and Interface Behavior",
"year": "1991",
"date": "662706000",
"link": "https://www.academia.edu/49274385/Organoalkoxysilane_Hydrolysis_Deposition_and_Interface_Behavior",
"volume": "1",
"pages": "9",
"is_gelest": true,
"journal_id": 87,
"author_ids": [3, 147, 61],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Cyclic azasilanes: Efficient monolayer deposition and their applications",
"year": "2014",
"date": "1388552400",
"link": "https://www.academia.edu/49466861/Cyclic_Azasilanes_Efficient_Monolayer_Deposition_and_Their_Applications",
"volume": "1",
"pages": "1",
"is_gelest": true,
"journal_id": 35,
"author_ids": [34, 20, 38, 35, 9, 36, 3],
"category_ids": [1],
"abstract": "yes"
},
{
"article_title": "Dipodal Silanes",
"year": "2008",
"date": "1199163600",
"link": "https://www.adhesivesmag.com/articles/87627-dipodal-silanes",
"volume": "15 ",
"pages": " 33-35",
"is_gelest": false,
"journal_id": 49,
"author_ids": [3, 36],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "High Density Silicon Dioxide Coatings by UV and Thermal Processing",
"year": "2000",
"date": "946702800",
"link": "https://www.gelest.com/wp-content/uploads/ConfText.pdf",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 62,
"author_ids": [3, 84, 62, 67, 85],
"category_ids": [1],
"abstract": "Silsesquioxanes containing b electronegative groups are processible resins that can be applied as thin film precursors of dielectric and abrasion resistant coatings. Both UV (<215nm) and thermally driven (>280°C) cures convert the silsesquioxanes to silicon dioxide. The cure mechanism is dependent on the extrusion of ethylene with concomitant transfer of the electronegative group to silicon which then undergoes facile hydrolysis. A minor pathway involving elimination of the protonated electronegative group can be utilized to modify the resins by organic group incorporation. The introduction of fluoride ion catalysts greatly accelerates the major pathway, lowering conversion temperatures to less than 200°C. A review of the chemistry, processing and film properties is presented."
},
{
"article_title": "Silicone Elastomers with Exceptional Elongation",
"year": "2015",
"date": "1420088400",
"link": "https://www.gelest.com/wp-content/uploads/Silicone_Elastomers_with_Exceptional_Elongation_ACS_Rubber.pdf",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 27,
"author_ids": [3, 1, 2],
"category_ids": [1],
"abstract": "Polysiloxanes elastomers formed by the step-growth of heterobifunctional macromers achieve high molecular weights and show elastomeric behavior. There is no apparent mechanism for crosslinking and advanced NMR and DSC techniques as well as rheological studies support the fact that, within the limits of detection, the step-growth elastomers are linear. When formed into nanocomposites by the incorporation of surface passivated fumed silica, they exhibit elongations exceeding 5000%. At extensions comparable to conventional silicone elastomers, they show similar elastic recovery. At greater extensions, recovery is reduced marginally. These materials are readily manufacturable and can be compounded and processed similar to conventional two-component platinum cure silicone RTVs. We have adopted the designation of xPDMS for these materials, a modified acronym for “high eXtension PolyDiMethylSiloxanes”. The synthesis, characterization, and mechanical properties of the first example of of an xPDMS suitable for commercial production is presented."
},
{
"article_title": "Silicone elastomers by step-growth polymerization of monodisperse dual functional silicones",
"year": "2012",
"date": "1325394000",
"link": "https://www.gelest.com/wp-content/uploads/technical_library/Jonathan-ACSPreprint.pdf",
"volume": "53 ",
"pages": " 486-487",
"is_gelest": true,
"journal_id": 43,
"author_ids": [1, 3, 45, 42],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Positive Tactile Interaction Coatings",
"year": "2017",
"date": "1483246800",
"link": "https://www.pcimag.com/articles/103634-positive-tactile-interaction-coatings",
"volume": "33 ",
"pages": " 30-36",
"is_gelest": true,
"journal_id": 17,
"author_ids": [3, 1],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Grignard reagents and silanes",
"year": "1996",
"date": "820472400",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/237700950_Grignard_Reagents_and_Silanes/links/54e612980cf2bff5a4f27602/Grignard-Reagents-and-Silanes.pdf",
"volume": "1",
"pages": "667-676",
"is_gelest": true,
"journal_id": 81,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Silicon Compounds: Ethers and Esters",
"year": "1997",
"date": "852094800",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/272494142_Silicon_Compounds_Silicon_Esters/links/5a8591030f7e9b1a95472a53/Silicon-Compounds-Silicon-Esters.pdf",
"volume": "1",
"pages": "4th edition",
"is_gelest": true,
"journal_id": 78,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Stable, Water-Borne Silane Coupling Agents",
"year": "1991",
"date": "662706000",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/272744934_Stable_Water-Borne_Silane_Coupling_Agents/links/54ecd6fb0cf28f3e6534e261/Stable-Water-Borne-Silane-Coupling-Agents.pdf",
"volume": "1",
"pages": "2-D",
"is_gelest": true,
"journal_id": 88,
"author_ids": [3, 147, 36, 148],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Future Developments in Silicon Chemistry - An Industrial Perspective",
"year": "1995",
"date": "788936400",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/273141840_Future_Developments_in_Silicon_Chemistry-_An_Industrial_Perspective/links/54f9e73f0cf29a9fbd7c57e8/Future-Developments-in-Silicon-Chemistry-An-Industrial-Perspective.pdf",
"volume": "1",
"pages": "571-579",
"is_gelest": true,
"journal_id": 83,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Low Cost Glass-Fortified Thermoplastic Resins for Automotive Applications",
"year": "1972",
"date": "63090000",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/274071705_Low_Cost_Glass-Fortified_Thermoplastic_Resins/links/551432780cf283ee0834c92f/Low-Cost-Glass-Fortified-Thermoplastic-Resins.pdf",
"volume": "27",
"pages": " 14-C1-12",
"is_gelest": true,
"journal_id": 144,
"author_ids": [166, 3, 174],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Polysiloxanes Having Increased Moisturization Potential",
"year": "2006",
"date": "1136091600",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/274195153_Polysiloxanes_Having_Increased_Moisturization_Potential/links/55188ecc0cf29ab36bc4d46a/Polysiloxanes-Having-Increased-Moisturization-Potential.pdf",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 51,
"author_ids": [50, 3, 59, 44, 60],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Silicone IPN Modified Thermoplastics",
"year": "1984",
"date": "441781200",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/275583742_Silicone_IPN_Modified_Thermoplastics/links/554259d00cf24107d3946cee/Silicone-IPN-Modified-Thermoplastics.pdf",
"volume": "1",
"pages": "486-487",
"is_gelest": true,
"journal_id": 100,
"author_ids": [3, 161],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Environmental, Thermal and Flammability Resistance of Glass Fortified Thermoplastics for Business Machine, Appliance and Tool Housings",
"year": "1971",
"date": "31554000",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/275642141_Environmental_Thermal_and_Flammability_Resistance_of_Glass_Fortified_Thermoplastics/links/554131d10cf23222273154b6/Environmental-Thermal-and-Flammability-Resistance-of-Glass-Fortified-Thermoplastics.pdf",
"volume": "26",
"pages": " 1-22",
"is_gelest": false,
"journal_id": 147,
"author_ids": [166, 3, 174],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Low Friction and Wear Thermoplastic Composites",
"year": "1973",
"date": "94712400",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/276847571_Low_Friction_and_Wear_Thermoplastic_Composites/links/555a3ddd08aeaaff3bfabc4a/Low-Friction-and-Wear-Thermoplastic-Composites.pdf",
"volume": "33 ",
"pages": " 188-194",
"is_gelest": true,
"journal_id": 141,
"author_ids": [166, 3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Silicones in Biomedical Applications",
"year": "1983",
"date": "410245200",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/280559052_Silicones_in_Biomedical_Applications/links/55b9293308ae9289a08ffa9f/Silicones-in-Biomedical-Applications.pdf",
"volume": "1",
"pages": "749-768",
"is_gelest": false,
"journal_id": 106,
"author_ids": [3, 164],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "A Reactive Processing Method for IPN Thermoplastics",
"year": "1983",
"date": "410245200",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/281866081_A_Reactive_Processing_Method_for_IPN_Thermoplastics/links/55fc67f608ae07629e0cf4cc/A-Reactive-Processing-Method-for-IPN-Thermoplastics.pdf",
"volume": "49",
"pages": " 6-9",
"is_gelest": true,
"journal_id": 104,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "High-Performance Functional Powder Coatings",
"year": "1975",
"date": "157784400",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/310457697_High_Performance_Functional_Powder_Coatings/links/582dcf4f08ae004f74bcd95e/High-Performance-Functional-Powder-Coatings.pdf",
"volume": "40 ",
"pages": " 74-82",
"is_gelest": false,
"journal_id": 129,
"author_ids": [3, 175, 176],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Soft Tissue Compliant Silicones for Medical Devices",
"year": "2018",
"date": "1514782800",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/325858337_Soft_Tissue_Compliant_Silicones_for_Medical_Devices/links/5b2989b34585150c630a52c6/Soft-Tissue-Compliant-Silicones-for-Medical-Devices.pdf",
"volume": "258 ",
"pages": " 22-26",
"is_gelest": false,
"journal_id": 11,
"author_ids": [1, 2, 13, 14, 3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Integration of CVD W-and Ta-based Liners for Copper Metallization",
"year": "1999",
"date": "915166800",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/325995678_Integration_of_CVD_W-_and_Ta-based_Liners_for_Copper_Metallization/links/5b3247f70f7e9b0df5cc9772/Integration-of-CVD-W-and-Ta-based-Liners-for-Copper-Metallization.pdf",
"volume": "1",
"pages": "1",
"is_gelest": true,
"journal_id": 68,
"author_ids": [47, 97, 81, 98, 99, 100, 82, 8, 3, 73],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Mechanical and physical properties of ultra-high elongation silicone elastomers",
"year": "2016",
"date": "1451624400",
"link": "https://www.researchgate.net/profile/Barry-Arkles/publication/345139171_Mechanical_and_physical_properties_of_ultra-high_elongation_silicone_elastomers/links/5fa03fed458515b7cfb3504a/Mechanical-and-physical-properties-of-ultra-high-elongation-silicone-elastomers.pdf",
"volume": "1",
"pages": "1",
"is_gelest": true,
"journal_id": 20,
"author_ids": [2, 1, 3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Chemical aspects of electronic ceramic processing",
"year": "1998",
"date": "883630800",
"link": "https://www.researchgate.net/publication/235017419_Chemical_Aspects_of_Electronic_Ceramics_Processing",
"volume": "495",
"pages": " 1-469",
"is_gelest": false,
"journal_id": 72,
"author_ids": [113, 114, 115, 3, 73],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Synthesizing Low-k Materials for Fab Use",
"year": "2000",
"date": "946702800",
"link": "https://www.researchgate.net/publication/272482062_Synthesizing_Low-k_CVD_Materials_for_Fab_Use",
"volume": "23 ",
"pages": " 95-102",
"is_gelest": false,
"journal_id": 60,
"author_ids": [74, 75, 3, 76],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Living polymerization routes to siloxane macromers",
"year": "2015",
"date": "1420088400",
"link": "https://www.researchgate.net/publication/272494061_Living_Polymerization_Routes_to_Siloxane_Macromers_and_Higher_Order_Silicone_Structures",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 29,
"author_ids": [1, 3],
"category_ids": [1],
"abstract": "yes"
},
{
"article_title": "Hydrophobicity, Hydrophilicity and Silanes",
"year": "2006",
"date": "1136091600",
"link": "https://www.researchgate.net/publication/272494216_Hydrophobicity_Hydrophilicity_and_Silanes",
"volume": "22 ",
"pages": " 114-135",
"is_gelest": true,
"journal_id": 17,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Novel Organosilanes for Separation Science",
"year": "2001",
"date": "978325200",
"link": "https://www.researchgate.net/publication/272746649_Novel_Organosilanes_for_Separation_Science",
"volume": "1",
"pages": "PS1-31",
"is_gelest": true,
"journal_id": 57,
"author_ids": [33, 3, 9, 66],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Comparing High-Temperature Plastics",
"year": "1975",
"date": "157784400",
"link": "https://www.researchgate.net/publication/272786797_Comparing_High-Temperature_Plastics",
"volume": "47 ",
"pages": " 73-77",
"is_gelest": true,
"journal_id": 91,
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"abstract": "This book embodies the proceedings of the Second International Symposium on Silanes and other Adhesion Promoters held in Newark, New Jersey, October 21--23, 1998. Silanes are the most popular and widely used coupling agents (or adhesion promoters) to promote adhesion between dissimilar materials in a variety of situations, e.g. coating technology, adhesive bonding, reinforced composites, etc. Since the first symposium on this topic in 1991, there had been a tremendous R&D activity in developing new and more effective adhesion promoters and in understanding and optimising the performance of available coupling agents. The technical program for the symposium contained 36 papers and reflected both overviews and original research contributors and the presenters hailed from academia, industry and other research laboratories. Many different aspects of coupling agents were discussed, and both fundamental and applied aspects were accorded due coverage. In addition to formal presentations, there were brisk and lively discussions throughout the symposium, and this event provided an opportunity for cross-pollination of ideas in the broad arena of adhesion promoters. This present volume contains 18 papers by experts from academia, industry and other research laboratories. All manuscripts were subjected to rigorous peer review and were suitably revised before inclusion in this volume. The book is divided into two parts as follows: Part 1. Silane Coupling Agents; and Part 2: Non-silane Coupling Agents/Adhesion Promotors. The topics covered include: silane adhesion prompters for hydrosilylation cure systems; sterically hindered silanes; study of silanes hydrolysis; adsorption of silanes on different substrates; interaction of water with silane films studied by neutron reflection; characterization of glass fiber sizings; silanes as dispersion promoters; corrosion protection of metals by silanes; surface 'Intelligraft' as a new class of adhesion promoters; hydroxymethylated resorcinol, sol-gels, and -diketone functionalised polymers as adhesion promoters; and plasma deposition of silanes"
},
{
"article_title": "Silicone Elastomers with Intrinsic Control of Surface Hydrophilicity",
"year": "2013",
"date": "1357016400",
"link": "http://biomaterials-org.securec7.ezhostingserver.com/abstracts/data/papers/2013/0243-000796.pdf",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 39,
"author_ids": [1, 3],
"category_ids": [1],
"abstract": "Addition-cure, platinum catalyzed silicone RTVs undergo a crosslinking reaction yielding silicone elastomers.1 Silicone elastomers have myriad uses in medical applications due to their biocompatiblity. The hydrophobic surface of silicone elastomers is a well documented disadvantage in many applications. Longterm surface modification of silicones to improve wettability and reduce protein adsorption is desirable. Oxidative surface treatment of silicone elastomers to improve surface wettability has been reported, however, the surface recovers hydrophobic character over time.2 As a result, oxidative surface treatments need to be continually reapplied to the silicone elastomer to retain hydrophilic surface performance. Addition of a hydrophilic additive such as polyethylene glycol (PEG) to silicone RTV formulations is another approach to modifying the surface of silicone elastomers. These unbound hydrophilic additives in silicone elastomers lead to loss of optical clarity, increased presence of undesirable extractables and degradation of mechanical properties. This paper reports the development of silicone elastomer comonomers containing surface active pendants with discrete discrete polyether or tetrahydrofurfuryl (THF) substitution and a central vinyl functionality that can react into RTV formulations. Copolymerization leads to optically clear silicone elastomers with good mechanical properties and no increase in extractables. The pendant hydrophilic groups orient on the surface of the bulk silicone elastomer, providing long-term improvement of surface wettability and reduced protein adsorption."
},
{
"article_title": "Quaternary functional silsesquioxanes for use in personal care: polysilsesquioxane steardimonium chloride",
"year": "2012",
"date": "1325394000",
"link": "http://www.gelest.com/wp-content/uploads/pdf-04.pdf",
"volume": "1",
"pages": "1",
"is_gelest": false,
"journal_id": 41,
"author_ids": [42, 3, 36, 44],
"category_ids": [1],
"abstract": "Quaternary amine functional silsesquioxane particles are a universal conditioning and anti-static additive for personal care and cosmetics formulations. This solid powder can be dispersed easily into water based formulations, dry powders or plastic packaging. The highly charged surface provides beneficial effects at low loading levels. The particles are non-toxic, non-leaching, non-irritating, biocompatible, environmentally friendly and thermally stable"
},
{
"article_title": "Cyclic azasilanes: Volatile coupling agents for nanotechnology",
"year": "2004",
"date": "1072933200",
"link": "https://books.google.com/books?hl=en&lr=&id=TKbSBQAAQBAJ&oi=fnd&pg=PA179&ots=9H6Rma78Yq&sig=tFa6j9Hzo9U802nQ4sYcxygQISY#v=onepage&q&f=false",
"volume": "3",
"pages": " 179-191",
"is_gelest": false,
"journal_id": 54,
"author_ids": [3, 9, 33, 62],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Silicon nitride from organosilazane cyclic and linear prepolymers",
"year": "1986",
"date": "504939600",
"link": "https://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.923.702&rep=rep1&type=pdf",
"volume": "1",
"pages": "233-234",
"is_gelest": false,
"journal_id": 97,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Migratory Internal Lubrication of Thermoplastic Resins",
"year": "1973",
"date": "94712400",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37375365/Migratory_Internal_Lubrication_of_Thermoplastic_Resins.pdf?1429623595=&response-content-disposition=inline%3B+filename%3DMigratory_Internal_Lubrication_of_Thermo.pdf&Expires=1634074331&Signature=ePUcA8M4phy77N0b10AewIqP7Oga2Us7Sp3RIX486uu2sQtPyOncDUHgnb5xLF~W0HdmjBaRaj74QPPOHrClq1Th9gypAmwviYXzL5RFEsIMOLOEnsqUoq3dHAWLKYTHfelwVm5fktF1Tvhm8lhrwum33fQzEm8Ax-wzj9G2TOiuyeSgyLyqHwDXA6xfIbNWrc2e3dZ-WIQvBMbiyF4hRowEHWkgTcByg0sXH2BxZYdN1j1179-zbdekvPhLqV-tS0HNVr97DgmH5Fx-wIDHhL4hk5UaQeSovxND5siZyGtEpzsm2Z0dp58iqvlMGiXVcWbIqS2ehsSOkZdJbgDCtw__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "29 ",
"pages": " 552-555",
"is_gelest": false,
"journal_id": 118,
"author_ids": [3, 166],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Tailoring surfaces with silanes",
"year": "1977",
"date": "220942800",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37375696/Arkles__B.__Tailoring_Surfaces_with_Silanes__Chemtech__7__766-778__1977-with-cover-page-v2.pdf?Expires=1634063497&Signature=CXTSM-b~rDJqAmzeLCWOHgbGJ-cUMaRglMl1CMuHGd7LAiHbc1Dwq8ujjD5YjiipDMuNLgbBZywiVX4Lx53IS3qCihZW~uXR4k9DAXzceOzEdH3VI-5N1ISqtJH5yWdzkx~vRN1QVHfeO9BC~6ROlDGe59H6SfuV9s1B1~V0PVPTpCWvwHLLr~Fz1-HQbFptdgSbl9UnsULaDre58BxwfzWV5LmGN~H-s3gQzy1HyRxSIX81INxGOr~PyLWCRud-6wmDJDmInaEaKdj5K-JF-kgZMfA7EZ62MhsdsfPX29gaorLPa9qBtvHHG4w2I9cZDN-O~koATz4A0XbWuit7ow__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "7 ",
"pages": " 766-778",
"is_gelest": false,
"journal_id": 103,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Look what you can make out of silicones (Biomedical applications of silicones)",
"year": "1983",
"date": "410245200",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37376162/Look_what_you_can_make_out_of_silicones.pdf?1429627172=&response-content-disposition=inline%3B+filename%3DLook_what_you_can_make_out_of_silicones.pdf&Expires=1634059656&Signature=FzIPg3lHj89qRmnX-Gn83UcPhgd9vzSQKiH7kb7mNUpYM6UiU4e5BrvGZbcx9EC7xPrlX-CDdDN4QK5ygFonRuAL5GeqtGFiGGvnLYlDa1Xlwm0odBCFEEBsyPf-zV-~hXWQ468HIgO-BKIo5a50zkqUbKDytN3T22NkgpDXAlSZD9w~R3-OOWuilrIsynE3XKyPJP8if-3InF~21gsGiSdw~kpFBy4Z-He5mjMfQmPOPUQ0ipYc~AO~Arp9eh2bq9C-CuLAMKioAudV3v0pXVA3pwcrEwK-b89-MobvpoC7dbkSQevoWGBJex3oFHyBUtIN7nXxbzbSCqgttO69Wg__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "13 ",
"pages": " 542-555",
"is_gelest": false,
"journal_id": 103,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Polysiloxane-thermoplastic interpenetrating polymer networks",
"year": "1990",
"date": "631170000",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37383062/Polysiloxane-Thermoplastic_Interpenetrating_Polymer_Networks.pdf?1429665559=&response-content-disposition=inline%3B+filename%3DPolysiloxane_Thermoplastic_Interpenetrat.pdf&Expires=1634056569&Signature=Npn2MP~65Upuij7y9ADi1VwgqXZHuFncOYSH-WnTkUCPmdeGTBByuuEOjuUDgan5Q-ikRY69jfAeQiVTPlbS34jBI76yK6SXNdcvx35y~oKGcRglrSrrvFiPzje7~JZmxynBPMf55-~FjbbwAUen5At-9pJlgd-ygH5vLCdikRqcI5ZDYdtXm8EIFRmd~idQhVnymgswqnOAATBgpgg4MTccQp0VgACTDOBeD6eIHagKys4yYmC8N6ngkGBJciE84HBbag~DskTikLT7D-wmn8EGHTrf8CWmKnFe64WwYxGh7FEaJnJqtig8t3XldGPhz-CQIMKkqVPYTu2V9a4tXA__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "224",
"pages": " 181-199",
"is_gelest": false,
"journal_id": 89,
"author_ids": [3, 149],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Polymeric Silane Coupling Agents Enhance Strength of Composites",
"year": "1987",
"date": "536475600",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37414615/Polymeric_silane_coupling_agents_enhance_strength_of_composites.pdf?1429922551=&response-content-disposition=inline%3B+filename%3DPolymeric_Silane_Coupling_Agents_Enhance.pdf&Expires=1634058188&Signature=GHC7IahJvNFoxuVPDsRzq8NBATbMFZa-u5NbLhU68O-BgDbvXECvxWLR6xMUak14JN3323rHiTBIi~Ui9-GUcoatJ8b7vBGTUTBJBUeBGcqkjQsbbdI7Jx2c4JwvxnrXgM3HJdWjdQBf3MERxK5KID44owNmNoqmc8RrZ2qQsRgyUzYBY4~BF5TQPWvTv0eWz5vlBbAtMz-dluXyve-gaC56HumaktToFj8fZ38TmMT01sO63NZsgKTPq0iFor9LBdPVuJgk-wbo8GbbxtL6gd8OnYeokSXTt0M0hvEFm8VvqeIM2ursqZgKqqZWMApdR3CdsMcy3ObDKGWctS2Lug__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "64 ",
"pages": " 143",
"is_gelest": true,
"journal_id": 95,
"author_ids": [3, 147, 151],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Symmetric silicone macromers",
"year": "2009",
"date": "1230786000",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37471597/symmetric_macromers_poly_preprint-with-cover-page-v2.PDF?Expires=1633988933&Signature=Kis9tIjwHNIfgeQGrACa64kZAZ7K5d7ji~JPod0eI-LvSyK9WNJPxzOddyK3hV-gruH7pAwkwfGuHXzu4rUvWHgXTpf9nppr-EEwxxXTh~P2gtUU~Yi50RA2fZc-NKIheplFxBG~-MGti5878YtmGpeT7bxUhE3KoG9l3Ctw8PUeC48C-AJq6PcbKTpmwfqYYSZER23xReFYeiXXUaUEtzHCfQdcmDhc6az9-tNUebBS6L8Wj-PblArcxr-3mkGp3xnS5LZpPO0ot-rqW98pl7NmVCpr1O0gxquvBHRi04ULgxl43fO8yMWq8L56WmM9WMLRHf3cRsD6cIowrQQmBw__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "50 ",
"pages": " 859",
"is_gelest": false,
"journal_id": 43,
"author_ids": [42, 3, 46],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Designing with Fiber Reinforced and Internally Lubricated Thermoplastic Elastomers",
"year": "1976",
"date": "189320400",
"link": "https://d1wqtxts1xzle7.cloudfront.net/37583826/Designing_with_fiber_reinforced_and_internally_lubricated_thermoplastic_elastomers.pdf?1431118521=&response-content-disposition=inline%3B+filename%3DDesigning_with_fiber_reinforced_and_inte.pdf&Expires=1634064221&Signature=F7UZspCLXmQoUcYBOZPzAL5wRc4QhfoJoyy8XTrkyWrkBwI011cIMbhJ6C19yFQogLleHynCN-q82ZtTWokB6V4XzBovZ6sbYuO41WG8QixcBe~CO4fLBqJX7~voZvPzjGWyF2zwPvI1-gieHMWvqLyKK3qe7C3yT1XvHywZL2vMlzsZONyxP-SR59OAAgUMcL8iTq8jreeBhKgljMKuBTsy0JUZXdTLWm4CzUYYqKKLTaYyudrX-65Zu-6Ppihs3BlkFEtj-1ZwcBKn5vi8XV1z2Tn8qE8r5xx30Xut-4m1pdr6RW7Yr41cC1uHaBfvXTl1e6IUQhrl1E1OG~CYAw__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "13-E",
"pages": " 12pp",
"is_gelest": false,
"journal_id": 123,
"author_ids": [166, 3, 172],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "The effect of silanes on adhesion of size-free glass fibers in thermoplastic composites",
"year": "1979",
"date": "284014800",
"link": "https://d1wqtxts1xzle7.cloudfront.net/38801757/The_Effect_of_Silanes_on_Adhesion_of_Size_Free_Glass_Fibers_in_Thermoplastic_Composites.pdf?1442506325=&response-content-disposition=inline%3B+filename%3DThe_Effect_of_Silanes_on_Adhesion_of_Siz.pdf&Expires=1634062870&Signature=JvBWTXoXMVglm2fJtse49dgKRjKYhUo5FvVckKSQXRgRcxXjDyc0b0p08jnzTXrBSHo2tAcwqQK4dTJjr96dZIJJO7Bubu-2-CqRq~guoXIy4HVUepqqXrsoLcraGjgYIVvxfCuoErGmv-lPzMMfB~AiagjIZRIDsJu-J8nFr8rA5mTLzqKAUHsWujV9261wwh3Uu18fcoofCfjnciIZ21pySkze35MIqBz~CU0uSP0YQpKat4Jf8AqFzONsCYRrMz3yRPzEwT7mpIjZPlTBn59dR2aV30JSZk55xIXisGWRx9cH9AgKeuoVgI5X8u2GLcL-ulDT5P5F1Pu4FZvddw__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "40",
"pages": " 538-541",
"is_gelest": true,
"journal_id": 114,
"author_ids": [3, 163],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Ultra-High Elongation Silicone Elastomers",
"year": "2016",
"date": "1451624400",
"link": "https://d1wqtxts1xzle7.cloudfront.net/46582485/Ultra-high_Elongation_Silicone_Elastomers-with-cover-page-v2.pdf?Expires=1633988094&Signature=H795V8OdSlTmtlCJLmZZR7tISLfWgyEF3jQYyV31BaGBj0Rsz0PrkISZIL7zzpOZGKLS0bQEtXyLB9hMUdnz8nLjfcc0xnk501bb4tX~8vED~hK0esLq-NbW4CVKOLvMwp1WVWLbYOivcwKqSXhQYWqS1D1lK4FjlSsfr~ANDCEEY-Q3CXjx6zksfk~SXYWr7-LPmPxxQL1fYWj4tUkwAXdBgPRbu3sX3Oi8GQx4EdMvDjvtM4yE2zi9YWDWQGdD5OhDMEiEqit9gcexKcZ0dk7kuGcpVn7Kmj8tDuwar4cywLpXBq2LFCS5At9tEq81V2JZ5FQw0PjU4-gKQP7g0A__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "254 ",
"pages": " 29-34",
"is_gelest": true,
"journal_id": 11,
"author_ids": [3, 1, 2, 16],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Sivate enhanced aminofunctional silane",
"year": "2018",
"date": "1514782800",
"link": "https://d1wqtxts1xzle7.cloudfront.net/56420499/Sivate_enhanced_amino_functional_silane.pdf?1524703920=&response-content-disposition=inline%3B+filename%3DSivate_enhanced_amino_functional_silane.pdf&Expires=1633987817&Signature=cZFoAv9tH0aNVl-yQny9wCYtwanbBfmLytJ6lqVZgpazPx170X654B3vR~FO1Hwmlqki-nCSZhTqsUkGrCRSiJNBYFLMbiU7PH9NiFbbfDDPw3pFsgAghLrw4KrsBfZ4aDm-NfvOxdp8~CIyvRT2y-NKnlokGYts6kxsP9Hhguc5UyDqy6Ew-B6h7FGitZ4UZTmVNAQgfCcC9~Duim0LKmp1UIebouvd~F1QzdS8u98Phb5qHeEN~-VyyE0Rgxjj4e-IXdytwM~SLW1rEmKwh9aKAbTzcadi7I2gq2VxcHHQzZNF1sZDXzJ2yGjWvSgA~pB4cw7vyyogZ0x9rq2kcw__&Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA",
"volume": "208",
"pages": " 26-27",
"is_gelest": false,
"journal_id": 12,
"author_ids": [15, 3, 1],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Commercial Hybrid Organic‐Inorganic Polymers",
"year": "2000",
"date": "946702800",
"link": "https://doi.org/10.1002/9783527620777.ch100c",
"volume": "1",
"pages": "592-612",
"is_gelest": false,
"journal_id": 63,
"author_ids": [3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Thermally Induced Silane Dehydrocoupling on Silicon Nanostructures",
"year": "2016",
"date": "1451624400",
"link": "https://doi.org/10.1002/anie.201601010",
"volume": "55 ",
"pages": " 6533-6537",
"is_gelest": false,
"journal_id": 22,
"author_ids": [22, 28, 9, 29, 30, 31, 3, 27],
"category_ids": [1],
"abstract": "Organic trihydridosilanes can be grafted to hydrogen-terminated porous Si nanostructures with no catalyst. The reaction proceeds efficiently at 80 °C, and it shows little sensitivity to air or water impurities. The modified surfaces are stable to corrosive aqueous solutions and common organic solvents. Octadecylsilane H3Si(CH2)17CH3, and functional silanes H3Si(CH2)11Br, H3Si(CH2)9CH=CH2, and H3Si(CH2)2(CF2)5CF3 are readily grafted. When performed on a mesoporous Si wafer, the perfluoro reagent yields a superhydrophobic surface (contact angle 151°). The bromo-derivative is converted to azide, amine, or alkyne functional surfaces via standard transformations, and the utility of the method is demonstrated by loading of the antibiotic ciprofloxaxin (35 % by mass). When intrinsically photoluminescent porous Si films or nanoparticles are used, photoluminescence is retained in the grafted products, indicating that the chemistry does not introduce substantial nonradiative surface traps."
},
{
"article_title": "Surface Triggered Tandem Coupling Reactions of Cyclic Azasilanes",
"year": "2017",
"date": "1483246800",
"link": "https://doi.org/10.1002/asia.201700137",
"volume": "12 ",
"pages": " 1198-1203",
"is_gelest": false,
"journal_id": 18,
"author_ids": [9, 20, 10, 21, 1, 3],
"category_ids": [1],
"abstract": "Cyclic azasilanes have been synthesized for the purpose of developing coupling agents appropriate for a variety of nanotechnologies including surface modification of nanoparticles, nanocrystals, mesoporous materials and substrates. N-Methyl-aza-2,2,4-trimethylsilacyclopentane is representative of this class of compounds. Preliminary data for the treatment of inorganic surfaces, including nanoparticles and oxidized silicon wafers, with cyclic azasilanes suggest high-density monolayer deposition by a ring-opening reaction. Cyclic azasilanes contain a cryptic amine functionality that can perform a subsequent tandem coupling reaction with functional molecules after the surface-triggered ring-opening reaction, allowing for a one-pot self-assembly route on nanostructures. Tandem coupling reactions are demonstrated via addition reactions of the cryptic amine with epoxy and acrylate systems."
},
{
"article_title": "Enhanced Hydrolytic Stability of Siliceous Surfaces Modified with Pendant Dipodal Silanes",
"year": "2014",
"date": "1388552400",
"link": "https://doi.org/10.1002/chem.201402757",
"volume": "20 ",
"pages": " 9442-9450",
"is_gelest": true,
"journal_id": 34,
"author_ids": [3, 9, 33, 35],
"category_ids": [1],
"abstract": "Dipodal silanes possess two silicon atoms that can covalently bond to a surface. They offer a distinct advantage over conventional silanes commonly used for surface modification in terms of maintaining the integrity of surface coatings, adhesive primers, and composites in aqueous environments. New nonfunctional and functional dipodal silanes with structures containing “pendant” rather than “bridged” organofunctionality are introduced. The stability of surfaces in aqueous environments prepared from dipodal silanes with hydrophobic alkyl functionality is compared to the stability of similar surfaces prepared from the conventional silanes. In strongly acidic and brine environments, surfaces modified with dipodal silanes demonstrate markedly improved resistance to hydrolysis compared to surfaces prepared from conventional silanes. Pendant dipodal silanes exhibit greater stability than bridged dipodal silanes. The apparent equilibrium constant for the formation of silanol species by the hydrolysis of a disiloxane bond was determined as Kc=[SiOH]2/[Si-O-Si][H2O]=6±1×10−5 and is helpful in understanding the enhanced hydrolytic stability of surfaces modified with dipodal silanes."
},
{
"article_title": "Recycling Poly(Tetragluoroethylene)",
"year": "1973",
"date": "94712400",
"link": "https://doi.org/10.1007/978-1-4684-0871-3_8",
"volume": "1",
"pages": "121-137",
"is_gelest": false,
"journal_id": 142,
"author_ids": [3],
"category_ids": [1],
"abstract": "Poly(tetrafluoroethylene) (PTFE) is unique among polymers in its ecological position. Although there has been considerable discussion on recycling waste polymers such as poly(ethylene) (PE), poly(styrene) (PS), and poly(vinyl chloride) (PVC), only poly(tetrafluoroethylene) has been recycled in quantities significant compared to production. Over fifty times more PE is consumed in the form of trash bags for waste disposal than PTFE manufactured. Further, the growth rate of PE, PVC, and PS is continuing at 5–10%o per year while PTFE growth has plateaued. On a tonnage basis, then, the recycling of PTFE appears anomalous. The discrepancy disappears when the economic reward of reprocessing a $2.75/1b material is contrasted with that of a $0.14/1b material. The high scrap value of PTFE provides an incentive for both fabricators and end-users to accumulate waste in reasonably concentrated bulk. Further, freight cost to reprocessing installations is not a significant portion of the polymer cost. Due to the economic incentive a wide variety of methods for up-grading waste PTFE to reprocessable grades have been evaluated. The techniques employed may be transferable to other polymers of greater ecological impact."
},
{
"article_title": "Staged development of modified silicon dioxide films",
"year": "1997",
"date": "852094800",
"link": "https://doi.org/10.1007/BF02436883",
"volume": "8 ",
"pages": " 465-469",
"is_gelest": false,
"journal_id": 77,
"author_ids": [3, 62, 89, 68, 127, 128, 94],
"category_ids": [1],
"abstract": "The hydrolytic generation of SiO2 films from chlorosilanes or alkoxysilanes is interrupted by incorporating labile organic groups which stop SiO2 formation at a processable prepolymer stage. The monomers for the prepolymer have electron withdrawing substituents in the β-position. The organic groups are removed from the prepolymer at low temperature, extruding ethylene. The formation of SiO2 proceeds by intramolecular condensation of the electronegative substituents which are now in a hydrolytically unstable bond with silicon and hydroxyl groups or ambient moisture. Films of the prepolymer spun onto silicon wafers are converted into uniform SiO2-rich films at temperatures between 150–400°C."
},
{
"article_title": "Hydroxymethylsilanetriol – a simple analog of silicic acid",
"year": "2013",
"date": "1357016400",
"link": "https://doi.org/10.1007/s12633-013-9146-2",
"volume": "5 ",
"pages": " 187-197",
"is_gelest": false,
"journal_id": 37,
"author_ids": [3, 40, 41],
"category_ids": [1],
"abstract": "Hydroxymethyltriethoxysilane and hydroxymethyltrimethoxysilane, precursors by hydrolysis to a simple analog of silicic acid, hydroxymethylsilanetriol, were prepared. Hydroxymethyltrialkoxysilanes undergo condensation to form silmethyleneoxide oligomers and dimeric 2,2,5,5-tetraalkoxy-2,5-disila-1,4-dioxanes. Hydroxymethylsilanetriol undergoes condensation reactions similar to silicic acid and readily forms organosilicate structures by sol–gel processing techniques which may be converted at relatively low temperatures to silicon dioxide. Hydroxmethylsilanetriol derived gels were subject to less stress-cracking during drying than conventional tetraethoxysilane derived gels, suggesting that Si-O-C bond equilibration during drying provides a mechanism for stress-relief. In screening experiments, hydroxymethylsilanetriol appears to be a competitive inhibitor of the growth of the diatom C. fusiformis, a silicate dependent species, which produces silicate structures."
},
{
"article_title": "The molecular weight of PTFE wear debris",
"year": "1976",
"date": "189320400",
"link": "https://doi.org/10.1016/0043-1648(76)90235-0",
"volume": "39 ",
"pages": " 177-180",
"is_gelest": false,
"journal_id": 120,
"author_ids": [3, 169],
"category_ids": [1],
"abstract": "A preliminary investigation of the molecular weight of polytetrafluoroethylene (PTFE) wear debris was undertaken. It was found that the molecular weight of PTFE wear debris generated from thrust washers was drastically reduced compared with that of the thrust washer. A consistent difference in the molecular weight of the wear debris was observed in samples obtained at high and at low pressure velocities. A fluorocarbon composite material yielded wear debris of molecular weight even lower than that of unfilled PTFE wearing below its limiting pressure-velocity."
},
{
"article_title": "Functional properties of rat liver mitochondria immobilized on an alkylsilylated surface",
"year": "1979",
"date": "284014800",
"link": "https://doi.org/10.1016/0076-6879(79)56053-4",
"volume": "56",
"pages": " 550-557",
"is_gelest": true,
"journal_id": 116,
"author_ids": [158, 3],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Concerning the relative non-toxicity of silacrown ionophores",
"year": "1985",
"date": "473403600",
"link": "https://doi.org/10.1016/0091-3057(84)90167-9",
"volume": "21 ",
"pages": " 77-80",
"is_gelest": false,
"journal_id": 98,
"author_ids": [152, 160, 153, 3],
"category_ids": [1],
"abstract": "Silacrowns, ionophoric materials in which an ethylene bridge of a normal crown ether has been replaced by a R2Si group, facilitate ion transport across liquid membranes. A major aspect of their properties is their nontoxicity when compared to these crown ethers. This is probably due to their ready hydrolysis to the corresponding polyethylene glycols. The glycols also exhibit ion transport properties, even with an efficiency close to the silacrowns but the silacrowns stay intact long enough to partition into the hydrophobic phase of a liquid membrane whereas their hydrolysis products preferentially partition into the aqueous phases. Ready removal from the hydrophobic phase of a membrane will reduce the long term transporting effectiveness of the glycols. Thus, in vivo hydrolysis of the silacrowns will result in the loss of transmembrane carriers. Similar removal will not occur for normal crown ionophores which are both hydrolytically stable and partition into the hydrophobic phase, and remain there for long time periods."
},
{
"article_title": "The Low-Temperature Remote-Plasma-Activated Pulsed Chemical Vapor Deposition Route to SiNx from 1,3,5-tri(isopropyl)cyclotrisilazane",
"year": "2020",
"date": "1577854800",
"link": "https://doi.org/10.1016/j.tsf.2020.138299",
"volume": "711",
"pages": " 138299",
"is_gelest": true,
"journal_id": 4,
"author_ids": [3, 7, 1, 8],
"category_ids": [1],
"abstract": "High-quality silicon nitride (SiNx) thin films were grown by remote-plasma-activated pulsed chemical vapor deposition (P-CVD) from the source precursor 1,3,5-tri(isopropyl)cyclotrisilazane (TICZ, C9H27N3Si3) and remote ammonia (NH3) plasma on silicon oxide (SiO2) substrates within an optimized substrate temperature window ranging from 200 to 350 °C. TICZ was selected because of its chemical stability, non-pyrophoric nature, good vapor pressure (~127 Pa at 70 °C), and its chemical structure that incorporates alkyl groups with three C atoms on each N atom, which provides a clean elimination mechanism for low temperature SiNx deposition. P-CVD consisted of a four-step process: TICZ pulse with no plasma, N2 purge, NH3 plasma pulse, and N2 purge. The as-deposited films were analyzed using spectroscopic ellipsometry and x-ray photoelectron spectroscopy (XPS). Wet etch rates were determined using a standard solution consisting of 0.5% hydrofluoric acid in deionized water. XPS analysis revealed a Si:N ratio of ~1:1 within the entire substrate temperature range and validated the formation of the SiNx phase. In situ, real-time ellipsometry measurements confirmed that SiNx growth exhibited a non-self-limiting P-CVD behavior. They also yielded an as-grown SiNx average refractive index of ~1.8 for the films grown at substrate temperatures above 200 °C."
},
{
"article_title": "Respiratory properties of rat liver mitochondria immobilized on an alkylsilylated glass surface",
"year": "1975",
"date": "157784400",
"link": "https://doi.org/10.1016/S0021-9258(19)40752-7",
"volume": "250 ",
"pages": " 8856-8862",
"is_gelest": false,
"journal_id": 127,
"author_ids": [3, 158],
"category_ids": [1],
"abstract": ""
},
{
"article_title": "Reaction of Trimethylsilyl Azide with Bridged Bicyclic Olefins",
"year": "1976",
"date": "189320400",
"link": "https://doi.org/10.1016/S0022-328X(00)85082-2",
"volume": "121 ",
"pages": " 285-291",
"is_gelest": false,
"journal_id": 125,
"author_ids": [163, 3, 173],
"category_ids": [1],
"abstract": "Bridged bicyclic olefins were found to undergo facile 1,3-cycloaddition reaction with trimethylsilyl azide. Norbornene produced cis,exo-1-trimethylsilyl-4,7-methano-3a,4,5,6,7,7a-hexahydrobenzotriazole, while norbornadiene formed a diadduct with cis,exo-stereochemistry, together with 2-trimethylsilyl-1,2,3-triazole produced by a retro-Diels—Alder reaction of an intermediate mono-adduct. Dicyclopentadiene reacted only at the norbornene position while α-pinene did not react with trimethylsilyl azide. In contrast to aryl- and sulfonyl-azide adducts of norbornene derivatives, which decompose upon heating the present adducts were recovered unchanged after prolonged treatment at 205°C."
}
]
}
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"article_title": "Ultra-High Elongation Silicone Elastomers",
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"journal": "Angewandte Chemie International Edition",
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