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PODCASTS:
http://rubyrogues.com/ - about programming in general, not always Ruby-specific (below a list of some episodes I found good, among many others)
- http://rubyrogues.com/131-rr-how-to-learn/ - episode about learning
- http://rubyrogues.com/023-rr-book-club-smalltalk-best-practice-patterns-with-kent-beck/ - episode with Kent Beck
- http://rubyrogues.com/068-rr-book-club-growing-object-oriented-software-guided-by-tests/ - episode about the GOOS book

http://pragprog.com/podcasts - about programming in general
- includes interviews with UncleBob, Kent Beck, Ward Cunningham, etc...

http://www.functionalgeekery.com/ - about functional programming

SCREENCASTS:
https://www.destroyallsoftware.com/screencasts - Gary Bernhardt's screencasts (I consider them my favourite screencasts)
http://cleancoders.com/ - Uncle Bob's stuff (as far as I remember, you already watch them)

CONFERENCE VIDEOS:
http://www.confreaks.com/ (grouped by conferences or speakers)

TALKS:
https://skillsmatter.com - requires you to log in (with Twitter if you like) to get access to many (hundreds?) of talks which happen pretty much every day in London