Software architecture encompasses the set of significant decisions about the organization of a software system including the selection of the structural elements and their interfaces by which the system is composed; behavior as specified in collaboration among those elements; composition of these structural and behavioral elements into larger subsystems; and an architectural style that guides this organization. Software architecture also involves functionality, usability, resilience, performance, reuse, comprehensibility, economic and technology constraints, tradeoffs and aesthetic concerns.
Philippe Kruchten, Grady Booch, Kurt Bittner, and Rich Reitman
The highest-level breakdown of a system into its parts; the decisions that are hard to change; there are multiple architectures in a system; what is architecturally significant can change over a system's lifetime; and, in the end, architecture boils down to whatever the important stuff is.
Patterns of Enterprise Application Architecture, Martin Fowler