No matter how well organized or spec'ed out a PSD is, there's always that point where you have to manually bring colors from design to code. Here are a few tools that have helped me get a seamless 360° workflow for dealing with colors in OS X.
Alfred 2 Colors Workflow
Amazing workflow by Tyler Eich that allows you to preview, modify and convert colors in a bunch of different color spaces and formats (rgb, hsl, hex, ...). Great if you want to convert those hex values to RGB for CSS.