How to use a PS3 controller on Mac OS X 10.7 (Lion)
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Open Apple menu -> System Preferences -> Bluetooth and disable Bluetooth on Mac as well as any other nearby Macs or devices which will try to pair with and confuse the controller.
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Reset PS3 controller by inserting paperclip into pinhole near L2 button.
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Connect PS3 controller to Mac with USB cable.
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Enable Bluetooth.